Ionic Equilibrium, Arrhenius Theory
Ionic Equilibrium

229353 The activation energy for a reaction at the temperature TK was found to be $2.303 \mathrm{RT} J$ $\mathrm{mol}^{-1}$. The ratio of the rate constant to Arrhenius factor is

1 $10^{-1}$
2 $10^{-2}$
3 $2 \times 10^{-3}$
4 $2 \times 10^{-2}$
Ionic Equilibrium

229354 The activation energy of exothermic reaction $A \rightarrow B$ is $80 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The heat of reaction is $-200 \mathrm{kJmol}^{-1}$. The activation energy for the reaction $B \rightarrow A\left(\right.$ in $\mathrm{kJ} \mathrm{mol}^{-1}$ ) will be

1 80
2 120
3 40
4 200
5 280
Ionic Equilibrium

229347 Arrhenius equation is :

1 $\Delta \mathrm{H}=\Delta \mathrm{E}+\Delta \mathrm{n}_{\mathrm{g}} \mathrm{RT}$
2 $\Delta \mathrm{G}=\Delta \mathrm{H}-\mathrm{T} \cdot \Delta \mathrm{S}$
3 $\mathrm{K}=\mathrm{Ae}^{-\mathrm{E}_{\mathrm{a}} / \mathrm{RT}}$
4 none of the above
Ionic Equilibrium

229349 The reactivity order of halogenation of alkanes is $\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{Br}_2>\mathrm{I}_2$. Choose the correct statements.
(I) Lower the activation energy for the chain initiation step, more reactive is the halogen.
(II) Lower the activation energy for the first chain-propagation step, more reactive is the halogen.
(III) Lower the activation energy for the second chain propagation step, more reactive is the halogen.
(IV) More negative is the overall heat of the reaction ( $\Delta \mathrm{H}_{\mathrm{r}}^{\circ}$ of halogenations of alkane) more reactive is the halogen.

1 I and II
2 I, II and III
3 II and IV
4 II, III and IV
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Ionic Equilibrium

229353 The activation energy for a reaction at the temperature TK was found to be $2.303 \mathrm{RT} J$ $\mathrm{mol}^{-1}$. The ratio of the rate constant to Arrhenius factor is

1 $10^{-1}$
2 $10^{-2}$
3 $2 \times 10^{-3}$
4 $2 \times 10^{-2}$
Ionic Equilibrium

229354 The activation energy of exothermic reaction $A \rightarrow B$ is $80 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The heat of reaction is $-200 \mathrm{kJmol}^{-1}$. The activation energy for the reaction $B \rightarrow A\left(\right.$ in $\mathrm{kJ} \mathrm{mol}^{-1}$ ) will be

1 80
2 120
3 40
4 200
5 280
Ionic Equilibrium

229347 Arrhenius equation is :

1 $\Delta \mathrm{H}=\Delta \mathrm{E}+\Delta \mathrm{n}_{\mathrm{g}} \mathrm{RT}$
2 $\Delta \mathrm{G}=\Delta \mathrm{H}-\mathrm{T} \cdot \Delta \mathrm{S}$
3 $\mathrm{K}=\mathrm{Ae}^{-\mathrm{E}_{\mathrm{a}} / \mathrm{RT}}$
4 none of the above
Ionic Equilibrium

229349 The reactivity order of halogenation of alkanes is $\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{Br}_2>\mathrm{I}_2$. Choose the correct statements.
(I) Lower the activation energy for the chain initiation step, more reactive is the halogen.
(II) Lower the activation energy for the first chain-propagation step, more reactive is the halogen.
(III) Lower the activation energy for the second chain propagation step, more reactive is the halogen.
(IV) More negative is the overall heat of the reaction ( $\Delta \mathrm{H}_{\mathrm{r}}^{\circ}$ of halogenations of alkane) more reactive is the halogen.

1 I and II
2 I, II and III
3 II and IV
4 II, III and IV
Ionic Equilibrium

229353 The activation energy for a reaction at the temperature TK was found to be $2.303 \mathrm{RT} J$ $\mathrm{mol}^{-1}$. The ratio of the rate constant to Arrhenius factor is

1 $10^{-1}$
2 $10^{-2}$
3 $2 \times 10^{-3}$
4 $2 \times 10^{-2}$
Ionic Equilibrium

229354 The activation energy of exothermic reaction $A \rightarrow B$ is $80 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The heat of reaction is $-200 \mathrm{kJmol}^{-1}$. The activation energy for the reaction $B \rightarrow A\left(\right.$ in $\mathrm{kJ} \mathrm{mol}^{-1}$ ) will be

1 80
2 120
3 40
4 200
5 280
Ionic Equilibrium

229347 Arrhenius equation is :

1 $\Delta \mathrm{H}=\Delta \mathrm{E}+\Delta \mathrm{n}_{\mathrm{g}} \mathrm{RT}$
2 $\Delta \mathrm{G}=\Delta \mathrm{H}-\mathrm{T} \cdot \Delta \mathrm{S}$
3 $\mathrm{K}=\mathrm{Ae}^{-\mathrm{E}_{\mathrm{a}} / \mathrm{RT}}$
4 none of the above
Ionic Equilibrium

229349 The reactivity order of halogenation of alkanes is $\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{Br}_2>\mathrm{I}_2$. Choose the correct statements.
(I) Lower the activation energy for the chain initiation step, more reactive is the halogen.
(II) Lower the activation energy for the first chain-propagation step, more reactive is the halogen.
(III) Lower the activation energy for the second chain propagation step, more reactive is the halogen.
(IV) More negative is the overall heat of the reaction ( $\Delta \mathrm{H}_{\mathrm{r}}^{\circ}$ of halogenations of alkane) more reactive is the halogen.

1 I and II
2 I, II and III
3 II and IV
4 II, III and IV
Ionic Equilibrium

229353 The activation energy for a reaction at the temperature TK was found to be $2.303 \mathrm{RT} J$ $\mathrm{mol}^{-1}$. The ratio of the rate constant to Arrhenius factor is

1 $10^{-1}$
2 $10^{-2}$
3 $2 \times 10^{-3}$
4 $2 \times 10^{-2}$
Ionic Equilibrium

229354 The activation energy of exothermic reaction $A \rightarrow B$ is $80 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The heat of reaction is $-200 \mathrm{kJmol}^{-1}$. The activation energy for the reaction $B \rightarrow A\left(\right.$ in $\mathrm{kJ} \mathrm{mol}^{-1}$ ) will be

1 80
2 120
3 40
4 200
5 280
Ionic Equilibrium

229347 Arrhenius equation is :

1 $\Delta \mathrm{H}=\Delta \mathrm{E}+\Delta \mathrm{n}_{\mathrm{g}} \mathrm{RT}$
2 $\Delta \mathrm{G}=\Delta \mathrm{H}-\mathrm{T} \cdot \Delta \mathrm{S}$
3 $\mathrm{K}=\mathrm{Ae}^{-\mathrm{E}_{\mathrm{a}} / \mathrm{RT}}$
4 none of the above
Ionic Equilibrium

229349 The reactivity order of halogenation of alkanes is $\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{Br}_2>\mathrm{I}_2$. Choose the correct statements.
(I) Lower the activation energy for the chain initiation step, more reactive is the halogen.
(II) Lower the activation energy for the first chain-propagation step, more reactive is the halogen.
(III) Lower the activation energy for the second chain propagation step, more reactive is the halogen.
(IV) More negative is the overall heat of the reaction ( $\Delta \mathrm{H}_{\mathrm{r}}^{\circ}$ of halogenations of alkane) more reactive is the halogen.

1 I and II
2 I, II and III
3 II and IV
4 II, III and IV