4 RBTS PAPER
163832
Which one of the following pairs of solutions will be expected to be isotonic under the same temperature?
1 \(0.1 \mathrm{M}\) urea and \(0.1 \mathrm{M} \mathrm{NaCl}\)
2 \(0.1 \mathrm{M}\) urea and \(0.2 \mathrm{M} \mathrm{MgCl}_2\)
3 \(0.1 \mathrm{M} \mathrm{NaCl}\) and \(0.1 \mathrm{M} \mathrm{Na}_2 \mathrm{SO}_4\)
4 \(0.1 \mathrm{M} \mathrm{Ca}\left(\mathrm{NO}_3\right)_2\) and \(0.1 \mathrm{M} \mathrm{Na}_2 \mathrm{SO}_4\)
Explanation:
\( 0.1 \mathrm{M} \mathrm{Ca}\left(\mathrm{NO}_3\right)_2 \)
\( \pi=\mathrm{iCRT} \)
\( \pi=3 \times 0.1 \times \mathrm{RT} \)
\( \pi=0.3 \mathrm{RT} \)
\( 0.1 \mathrm{M} \mathrm{Na}_2 \mathrm{SO}_4 \)
\( \pi=3 \times 0.1 \times \mathrm{RT} \)
\( \pi=0.3 \mathrm{RT} \)