CARBOXYLIC ACIDS
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28435 In the anion \(HCOO^-\), the two carbon oxygen bonds are found to be equal length. What is the reason

1 The \(C=O\) are weaker than the \(C-O\) bond
2 The anion is obtained by removal of proton from acid molecules
3 The anion has two equal contributing resonating structure
4 Carbon is present in \(sp^2\) state of hybridisation
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28436 In following reaction$\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$ $\xrightarrow{{S{OCl_2}}}$ ProductThe structure of Main Product is

1 $\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$
2 $\begin{array}{*{20}{c}}
\,\,\,{\,O}\\
\,\,\,{\,||}\\
{C{H_3} - C - Cl}
\end{array}$
3 \(CH_3-Cl\)
4 816-d1430
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28437 Arrange the following in order of their reactivity toward decarboxylation reaction$\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{CH \equiv C - C - OH}
\end{array}}\limits_{\rm{I}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_2} = CH - C - OH}
\end{array}}\limits_{{\rm{II}}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - C{H_2} - C - OH}
\end{array}}\limits_{{\rm{III}}} $$\mathop {\begin{array}{*{20}{c}}
\,\,\,{C{H_3}\,\,\,\,\,\,O}\\
\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - CH - C - OH}
\end{array}}\limits_{{\rm{IV}}} $

1 \(IV > III > II > I\)
2 \(I > II > III > IV\)
3 \(III > II > I > IV\)
4 \(III > IV > II > I\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28438 Kolbe's electrolysis of sodium acetate at anode gives

1 Ethane only
2 Only \(CO_2\)
3 Ethane $+$ \(CO_2\)
4 \(CO_2 + H_2\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28435 In the anion \(HCOO^-\), the two carbon oxygen bonds are found to be equal length. What is the reason

1 The \(C=O\) are weaker than the \(C-O\) bond
2 The anion is obtained by removal of proton from acid molecules
3 The anion has two equal contributing resonating structure
4 Carbon is present in \(sp^2\) state of hybridisation
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28436 In following reaction$\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$ $\xrightarrow{{S{OCl_2}}}$ ProductThe structure of Main Product is

1 $\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$
2 $\begin{array}{*{20}{c}}
\,\,\,{\,O}\\
\,\,\,{\,||}\\
{C{H_3} - C - Cl}
\end{array}$
3 \(CH_3-Cl\)
4 816-d1430
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28437 Arrange the following in order of their reactivity toward decarboxylation reaction$\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{CH \equiv C - C - OH}
\end{array}}\limits_{\rm{I}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_2} = CH - C - OH}
\end{array}}\limits_{{\rm{II}}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - C{H_2} - C - OH}
\end{array}}\limits_{{\rm{III}}} $$\mathop {\begin{array}{*{20}{c}}
\,\,\,{C{H_3}\,\,\,\,\,\,O}\\
\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - CH - C - OH}
\end{array}}\limits_{{\rm{IV}}} $

1 \(IV > III > II > I\)
2 \(I > II > III > IV\)
3 \(III > II > I > IV\)
4 \(III > IV > II > I\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28438 Kolbe's electrolysis of sodium acetate at anode gives

1 Ethane only
2 Only \(CO_2\)
3 Ethane $+$ \(CO_2\)
4 \(CO_2 + H_2\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28435 In the anion \(HCOO^-\), the two carbon oxygen bonds are found to be equal length. What is the reason

1 The \(C=O\) are weaker than the \(C-O\) bond
2 The anion is obtained by removal of proton from acid molecules
3 The anion has two equal contributing resonating structure
4 Carbon is present in \(sp^2\) state of hybridisation
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28436 In following reaction$\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$ $\xrightarrow{{S{OCl_2}}}$ ProductThe structure of Main Product is

1 $\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$
2 $\begin{array}{*{20}{c}}
\,\,\,{\,O}\\
\,\,\,{\,||}\\
{C{H_3} - C - Cl}
\end{array}$
3 \(CH_3-Cl\)
4 816-d1430
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28437 Arrange the following in order of their reactivity toward decarboxylation reaction$\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{CH \equiv C - C - OH}
\end{array}}\limits_{\rm{I}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_2} = CH - C - OH}
\end{array}}\limits_{{\rm{II}}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - C{H_2} - C - OH}
\end{array}}\limits_{{\rm{III}}} $$\mathop {\begin{array}{*{20}{c}}
\,\,\,{C{H_3}\,\,\,\,\,\,O}\\
\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - CH - C - OH}
\end{array}}\limits_{{\rm{IV}}} $

1 \(IV > III > II > I\)
2 \(I > II > III > IV\)
3 \(III > II > I > IV\)
4 \(III > IV > II > I\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28438 Kolbe's electrolysis of sodium acetate at anode gives

1 Ethane only
2 Only \(CO_2\)
3 Ethane $+$ \(CO_2\)
4 \(CO_2 + H_2\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28435 In the anion \(HCOO^-\), the two carbon oxygen bonds are found to be equal length. What is the reason

1 The \(C=O\) are weaker than the \(C-O\) bond
2 The anion is obtained by removal of proton from acid molecules
3 The anion has two equal contributing resonating structure
4 Carbon is present in \(sp^2\) state of hybridisation
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28436 In following reaction$\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$ $\xrightarrow{{S{OCl_2}}}$ ProductThe structure of Main Product is

1 $\begin{array}{*{20}{c}}
\,\,\,O\\
\,\,\,{||}\\
{C{H_3} - C - OH}
\end{array}$
2 $\begin{array}{*{20}{c}}
\,\,\,{\,O}\\
\,\,\,{\,||}\\
{C{H_3} - C - Cl}
\end{array}$
3 \(CH_3-Cl\)
4 816-d1430
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28437 Arrange the following in order of their reactivity toward decarboxylation reaction$\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{CH \equiv C - C - OH}
\end{array}}\limits_{\rm{I}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_2} = CH - C - OH}
\end{array}}\limits_{{\rm{II}}} $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - C{H_2} - C - OH}
\end{array}}\limits_{{\rm{III}}} $$\mathop {\begin{array}{*{20}{c}}
\,\,\,{C{H_3}\,\,\,\,\,\,O}\\
\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||}\\
{C{H_3} - CH - C - OH}
\end{array}}\limits_{{\rm{IV}}} $

1 \(IV > III > II > I\)
2 \(I > II > III > IV\)
3 \(III > II > I > IV\)
4 \(III > IV > II > I\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28438 Kolbe's electrolysis of sodium acetate at anode gives

1 Ethane only
2 Only \(CO_2\)
3 Ethane $+$ \(CO_2\)
4 \(CO_2 + H_2\)