11. ALCOHOLS, PHENOLS AND ETHERS
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ALCOHOLS, PHENOLS AND ETHER

15609 Suppose the following reaction -The structure of Major Product will be

1 824-a342
2 824-b342
3 824-c342
4 \(CHCl_3\)
ALCOHOLS, PHENOLS AND ETHER

15610 Which of the following is incorrect

1 \(C{H_3} - C{H_2} - C{H_2} - OH\xrightarrow{{PCC}}C{H_3} - C{H_2}COOH\)
2 824-b344
3 \(C{H_3} - C{H_2} - OH\xrightarrow{{{K_2}C{r_2}{O_7}/{H^ \oplus }}}C{H_3} - COOH\)
4 $\begin{matrix}
   C{{H}_{2}}-OH  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{2}}-OH  \\
\end{matrix}$ $\xrightarrow{HI{{O}_{4}}.2{{H}_{2}}O}2HCHO$
ALCOHOLS, PHENOLS AND ETHER

15611 $\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {R - C - OR \to RC{H_2}OH} 
\end{array}$

1 Bauvault blanc reduction
2 Stephen reduction
3 Wolf-kishner reduction
4 Cleamensen reduction
ALCOHOLS, PHENOLS AND ETHER

15612 Suppose the following reactionBenzene \((C_6H_6)\) \(+\,C{{H}_{3}}-CH=C{{H}_{2}}\,\xrightarrow{{{H}^{\oplus }}}A\xrightarrow{{{O}_{2}}}B\) \(\xrightarrow{{{H}^{\oplus }}\,/\,\Delta }C+\)$\begin{matrix}
   O  \\
   ||  \\
   C{{H}_{3}}-C-C{{H}_{3}}  \\
\end{matrix}$The structure of intermediate compound \('B'\) will be

1 824-a356
2 824-b356
3 824-c356
4 824-d356
ALCOHOLS, PHENOLS AND ETHER

15613 In the following reaction$\begin{matrix}
   \begin{matrix}
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\, \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   C{{H}_{3}}-C-CH=C{{H}_{2}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\,\,\, \\
\end{matrix}\,$ $\xrightarrow{{{H}_{2}}O/{{H}^{\oplus }}}$ $\underset{Major\,\,product}{\mathop{A}}\,$ $+$ $\underset{Major\,\,product}{\mathop{B}}\,$The major product is

1 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,C{H_3}\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
2 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - C{H_2} - C{H_2}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
3 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
4 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{{H_2}C - C - C{H_2} - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
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ALCOHOLS, PHENOLS AND ETHER

15609 Suppose the following reaction -The structure of Major Product will be

1 824-a342
2 824-b342
3 824-c342
4 \(CHCl_3\)
ALCOHOLS, PHENOLS AND ETHER

15610 Which of the following is incorrect

1 \(C{H_3} - C{H_2} - C{H_2} - OH\xrightarrow{{PCC}}C{H_3} - C{H_2}COOH\)
2 824-b344
3 \(C{H_3} - C{H_2} - OH\xrightarrow{{{K_2}C{r_2}{O_7}/{H^ \oplus }}}C{H_3} - COOH\)
4 $\begin{matrix}
   C{{H}_{2}}-OH  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{2}}-OH  \\
\end{matrix}$ $\xrightarrow{HI{{O}_{4}}.2{{H}_{2}}O}2HCHO$
ALCOHOLS, PHENOLS AND ETHER

15611 $\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {R - C - OR \to RC{H_2}OH} 
\end{array}$

1 Bauvault blanc reduction
2 Stephen reduction
3 Wolf-kishner reduction
4 Cleamensen reduction
ALCOHOLS, PHENOLS AND ETHER

15612 Suppose the following reactionBenzene \((C_6H_6)\) \(+\,C{{H}_{3}}-CH=C{{H}_{2}}\,\xrightarrow{{{H}^{\oplus }}}A\xrightarrow{{{O}_{2}}}B\) \(\xrightarrow{{{H}^{\oplus }}\,/\,\Delta }C+\)$\begin{matrix}
   O  \\
   ||  \\
   C{{H}_{3}}-C-C{{H}_{3}}  \\
\end{matrix}$The structure of intermediate compound \('B'\) will be

1 824-a356
2 824-b356
3 824-c356
4 824-d356
ALCOHOLS, PHENOLS AND ETHER

15613 In the following reaction$\begin{matrix}
   \begin{matrix}
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\, \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   C{{H}_{3}}-C-CH=C{{H}_{2}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\,\,\, \\
\end{matrix}\,$ $\xrightarrow{{{H}_{2}}O/{{H}^{\oplus }}}$ $\underset{Major\,\,product}{\mathop{A}}\,$ $+$ $\underset{Major\,\,product}{\mathop{B}}\,$The major product is

1 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,C{H_3}\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
2 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - C{H_2} - C{H_2}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
3 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
4 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{{H_2}C - C - C{H_2} - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
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ALCOHOLS, PHENOLS AND ETHER

15609 Suppose the following reaction -The structure of Major Product will be

1 824-a342
2 824-b342
3 824-c342
4 \(CHCl_3\)
ALCOHOLS, PHENOLS AND ETHER

15610 Which of the following is incorrect

1 \(C{H_3} - C{H_2} - C{H_2} - OH\xrightarrow{{PCC}}C{H_3} - C{H_2}COOH\)
2 824-b344
3 \(C{H_3} - C{H_2} - OH\xrightarrow{{{K_2}C{r_2}{O_7}/{H^ \oplus }}}C{H_3} - COOH\)
4 $\begin{matrix}
   C{{H}_{2}}-OH  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{2}}-OH  \\
\end{matrix}$ $\xrightarrow{HI{{O}_{4}}.2{{H}_{2}}O}2HCHO$
ALCOHOLS, PHENOLS AND ETHER

15611 $\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {R - C - OR \to RC{H_2}OH} 
\end{array}$

1 Bauvault blanc reduction
2 Stephen reduction
3 Wolf-kishner reduction
4 Cleamensen reduction
ALCOHOLS, PHENOLS AND ETHER

15612 Suppose the following reactionBenzene \((C_6H_6)\) \(+\,C{{H}_{3}}-CH=C{{H}_{2}}\,\xrightarrow{{{H}^{\oplus }}}A\xrightarrow{{{O}_{2}}}B\) \(\xrightarrow{{{H}^{\oplus }}\,/\,\Delta }C+\)$\begin{matrix}
   O  \\
   ||  \\
   C{{H}_{3}}-C-C{{H}_{3}}  \\
\end{matrix}$The structure of intermediate compound \('B'\) will be

1 824-a356
2 824-b356
3 824-c356
4 824-d356
ALCOHOLS, PHENOLS AND ETHER

15613 In the following reaction$\begin{matrix}
   \begin{matrix}
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\, \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   C{{H}_{3}}-C-CH=C{{H}_{2}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\,\,\, \\
\end{matrix}\,$ $\xrightarrow{{{H}_{2}}O/{{H}^{\oplus }}}$ $\underset{Major\,\,product}{\mathop{A}}\,$ $+$ $\underset{Major\,\,product}{\mathop{B}}\,$The major product is

1 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,C{H_3}\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
2 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - C{H_2} - C{H_2}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
3 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
4 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{{H_2}C - C - C{H_2} - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
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ALCOHOLS, PHENOLS AND ETHER

15609 Suppose the following reaction -The structure of Major Product will be

1 824-a342
2 824-b342
3 824-c342
4 \(CHCl_3\)
ALCOHOLS, PHENOLS AND ETHER

15610 Which of the following is incorrect

1 \(C{H_3} - C{H_2} - C{H_2} - OH\xrightarrow{{PCC}}C{H_3} - C{H_2}COOH\)
2 824-b344
3 \(C{H_3} - C{H_2} - OH\xrightarrow{{{K_2}C{r_2}{O_7}/{H^ \oplus }}}C{H_3} - COOH\)
4 $\begin{matrix}
   C{{H}_{2}}-OH  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{2}}-OH  \\
\end{matrix}$ $\xrightarrow{HI{{O}_{4}}.2{{H}_{2}}O}2HCHO$
ALCOHOLS, PHENOLS AND ETHER

15611 $\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {R - C - OR \to RC{H_2}OH} 
\end{array}$

1 Bauvault blanc reduction
2 Stephen reduction
3 Wolf-kishner reduction
4 Cleamensen reduction
ALCOHOLS, PHENOLS AND ETHER

15612 Suppose the following reactionBenzene \((C_6H_6)\) \(+\,C{{H}_{3}}-CH=C{{H}_{2}}\,\xrightarrow{{{H}^{\oplus }}}A\xrightarrow{{{O}_{2}}}B\) \(\xrightarrow{{{H}^{\oplus }}\,/\,\Delta }C+\)$\begin{matrix}
   O  \\
   ||  \\
   C{{H}_{3}}-C-C{{H}_{3}}  \\
\end{matrix}$The structure of intermediate compound \('B'\) will be

1 824-a356
2 824-b356
3 824-c356
4 824-d356
ALCOHOLS, PHENOLS AND ETHER

15613 In the following reaction$\begin{matrix}
   \begin{matrix}
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\, \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   C{{H}_{3}}-C-CH=C{{H}_{2}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\,\,\, \\
\end{matrix}\,$ $\xrightarrow{{{H}_{2}}O/{{H}^{\oplus }}}$ $\underset{Major\,\,product}{\mathop{A}}\,$ $+$ $\underset{Major\,\,product}{\mathop{B}}\,$The major product is

1 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,C{H_3}\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
2 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - C{H_2} - C{H_2}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
3 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
4 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{{H_2}C - C - C{H_2} - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
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ALCOHOLS, PHENOLS AND ETHER

15609 Suppose the following reaction -The structure of Major Product will be

1 824-a342
2 824-b342
3 824-c342
4 \(CHCl_3\)
ALCOHOLS, PHENOLS AND ETHER

15610 Which of the following is incorrect

1 \(C{H_3} - C{H_2} - C{H_2} - OH\xrightarrow{{PCC}}C{H_3} - C{H_2}COOH\)
2 824-b344
3 \(C{H_3} - C{H_2} - OH\xrightarrow{{{K_2}C{r_2}{O_7}/{H^ \oplus }}}C{H_3} - COOH\)
4 $\begin{matrix}
   C{{H}_{2}}-OH  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{2}}-OH  \\
\end{matrix}$ $\xrightarrow{HI{{O}_{4}}.2{{H}_{2}}O}2HCHO$
ALCOHOLS, PHENOLS AND ETHER

15611 $\begin{array}{*{20}{c}}
  {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {R - C - OR \to RC{H_2}OH} 
\end{array}$

1 Bauvault blanc reduction
2 Stephen reduction
3 Wolf-kishner reduction
4 Cleamensen reduction
ALCOHOLS, PHENOLS AND ETHER

15612 Suppose the following reactionBenzene \((C_6H_6)\) \(+\,C{{H}_{3}}-CH=C{{H}_{2}}\,\xrightarrow{{{H}^{\oplus }}}A\xrightarrow{{{O}_{2}}}B\) \(\xrightarrow{{{H}^{\oplus }}\,/\,\Delta }C+\)$\begin{matrix}
   O  \\
   ||  \\
   C{{H}_{3}}-C-C{{H}_{3}}  \\
\end{matrix}$The structure of intermediate compound \('B'\) will be

1 824-a356
2 824-b356
3 824-c356
4 824-d356
ALCOHOLS, PHENOLS AND ETHER

15613 In the following reaction$\begin{matrix}
   \begin{matrix}
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\, \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
\end{matrix}  \\
   C{{H}_{3}}-C-CH=C{{H}_{2}}  \\
   |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   C{{H}_{3}}\,\,\,\,\,\,\,\, \,\,\,\, \\
\end{matrix}\,$ $\xrightarrow{{{H}_{2}}O/{{H}^{\oplus }}}$ $\underset{Major\,\,product}{\mathop{A}}\,$ $+$ $\underset{Major\,\,product}{\mathop{B}}\,$The major product is

1 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,C{H_3}\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
2 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - C{H_2} - C{H_2}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
3 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{C{H_3} - C - CH - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$
4 $\begin{array}{*{20}{c}}
{C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{{H_2}C - C - C{H_2} - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,C{H_3}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$