11. ALCOHOLS, PHENOLS AND ETHERS
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ALCOHOLS, PHENOLS AND ETHER

15513 Ether on carbonylation gives

1 Alkanoic acid
2 Alkanone
3 Alkyl alkanoate
4 Alkanal
ALCOHOLS, PHENOLS AND ETHER

15514 $\begin{array}{*{20}{c}}
  {IR - \mathop {\mathop O\limits^{ \bullet  \bullet } }\limits^ \oplus   - R'} \\ 
  | \\ 
  H 
\end{array} \to RI + R'OH$true about this mechanism

1 \({S_{{N^1}}}\) in gas phase
2 \({S_{{N^2}}}\) in aqueous phase
3 both of the above
4 none
ALCOHOLS, PHENOLS AND ETHER

15515 Phenol with Hinsberg’s reagent gives

1 Sulphone
2 Sulphanilic acid
3 Sulphonic ester
4 Sulphonal
ALCOHOLS, PHENOLS AND ETHER

15516 Select the odd structure out

1 \(CH_3-CH(OH)-CH_2-CH_3\)
2 \(CH_3-CH(OH)-CH_2-CH_2-CH_3\)
3 \(CH_3-CH(OH)-CH_3\)
4 \(CH_3-CH_2-CH(OH)-C_2H_5\)
ALCOHOLS, PHENOLS AND ETHER

15517 Glycerol \(\xrightarrow{{KHS{O_4}}}A\xrightarrow{{LiAl{H_4}}}B\)\(A\) and \(B\) are :

1 Acrolein, allyl alcohol
2 Glyceryl sulphate, acrylic acid
3 Allyl alcohol, acrolein
4 Only acrolein (\(B\) is not formed)
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ALCOHOLS, PHENOLS AND ETHER

15513 Ether on carbonylation gives

1 Alkanoic acid
2 Alkanone
3 Alkyl alkanoate
4 Alkanal
ALCOHOLS, PHENOLS AND ETHER

15514 $\begin{array}{*{20}{c}}
  {IR - \mathop {\mathop O\limits^{ \bullet  \bullet } }\limits^ \oplus   - R'} \\ 
  | \\ 
  H 
\end{array} \to RI + R'OH$true about this mechanism

1 \({S_{{N^1}}}\) in gas phase
2 \({S_{{N^2}}}\) in aqueous phase
3 both of the above
4 none
ALCOHOLS, PHENOLS AND ETHER

15515 Phenol with Hinsberg’s reagent gives

1 Sulphone
2 Sulphanilic acid
3 Sulphonic ester
4 Sulphonal
ALCOHOLS, PHENOLS AND ETHER

15516 Select the odd structure out

1 \(CH_3-CH(OH)-CH_2-CH_3\)
2 \(CH_3-CH(OH)-CH_2-CH_2-CH_3\)
3 \(CH_3-CH(OH)-CH_3\)
4 \(CH_3-CH_2-CH(OH)-C_2H_5\)
ALCOHOLS, PHENOLS AND ETHER

15517 Glycerol \(\xrightarrow{{KHS{O_4}}}A\xrightarrow{{LiAl{H_4}}}B\)\(A\) and \(B\) are :

1 Acrolein, allyl alcohol
2 Glyceryl sulphate, acrylic acid
3 Allyl alcohol, acrolein
4 Only acrolein (\(B\) is not formed)
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ALCOHOLS, PHENOLS AND ETHER

15513 Ether on carbonylation gives

1 Alkanoic acid
2 Alkanone
3 Alkyl alkanoate
4 Alkanal
ALCOHOLS, PHENOLS AND ETHER

15514 $\begin{array}{*{20}{c}}
  {IR - \mathop {\mathop O\limits^{ \bullet  \bullet } }\limits^ \oplus   - R'} \\ 
  | \\ 
  H 
\end{array} \to RI + R'OH$true about this mechanism

1 \({S_{{N^1}}}\) in gas phase
2 \({S_{{N^2}}}\) in aqueous phase
3 both of the above
4 none
ALCOHOLS, PHENOLS AND ETHER

15515 Phenol with Hinsberg’s reagent gives

1 Sulphone
2 Sulphanilic acid
3 Sulphonic ester
4 Sulphonal
ALCOHOLS, PHENOLS AND ETHER

15516 Select the odd structure out

1 \(CH_3-CH(OH)-CH_2-CH_3\)
2 \(CH_3-CH(OH)-CH_2-CH_2-CH_3\)
3 \(CH_3-CH(OH)-CH_3\)
4 \(CH_3-CH_2-CH(OH)-C_2H_5\)
ALCOHOLS, PHENOLS AND ETHER

15517 Glycerol \(\xrightarrow{{KHS{O_4}}}A\xrightarrow{{LiAl{H_4}}}B\)\(A\) and \(B\) are :

1 Acrolein, allyl alcohol
2 Glyceryl sulphate, acrylic acid
3 Allyl alcohol, acrolein
4 Only acrolein (\(B\) is not formed)
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ALCOHOLS, PHENOLS AND ETHER

15513 Ether on carbonylation gives

1 Alkanoic acid
2 Alkanone
3 Alkyl alkanoate
4 Alkanal
ALCOHOLS, PHENOLS AND ETHER

15514 $\begin{array}{*{20}{c}}
  {IR - \mathop {\mathop O\limits^{ \bullet  \bullet } }\limits^ \oplus   - R'} \\ 
  | \\ 
  H 
\end{array} \to RI + R'OH$true about this mechanism

1 \({S_{{N^1}}}\) in gas phase
2 \({S_{{N^2}}}\) in aqueous phase
3 both of the above
4 none
ALCOHOLS, PHENOLS AND ETHER

15515 Phenol with Hinsberg’s reagent gives

1 Sulphone
2 Sulphanilic acid
3 Sulphonic ester
4 Sulphonal
ALCOHOLS, PHENOLS AND ETHER

15516 Select the odd structure out

1 \(CH_3-CH(OH)-CH_2-CH_3\)
2 \(CH_3-CH(OH)-CH_2-CH_2-CH_3\)
3 \(CH_3-CH(OH)-CH_3\)
4 \(CH_3-CH_2-CH(OH)-C_2H_5\)
ALCOHOLS, PHENOLS AND ETHER

15517 Glycerol \(\xrightarrow{{KHS{O_4}}}A\xrightarrow{{LiAl{H_4}}}B\)\(A\) and \(B\) are :

1 Acrolein, allyl alcohol
2 Glyceryl sulphate, acrylic acid
3 Allyl alcohol, acrolein
4 Only acrolein (\(B\) is not formed)
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ALCOHOLS, PHENOLS AND ETHER

15513 Ether on carbonylation gives

1 Alkanoic acid
2 Alkanone
3 Alkyl alkanoate
4 Alkanal
ALCOHOLS, PHENOLS AND ETHER

15514 $\begin{array}{*{20}{c}}
  {IR - \mathop {\mathop O\limits^{ \bullet  \bullet } }\limits^ \oplus   - R'} \\ 
  | \\ 
  H 
\end{array} \to RI + R'OH$true about this mechanism

1 \({S_{{N^1}}}\) in gas phase
2 \({S_{{N^2}}}\) in aqueous phase
3 both of the above
4 none
ALCOHOLS, PHENOLS AND ETHER

15515 Phenol with Hinsberg’s reagent gives

1 Sulphone
2 Sulphanilic acid
3 Sulphonic ester
4 Sulphonal
ALCOHOLS, PHENOLS AND ETHER

15516 Select the odd structure out

1 \(CH_3-CH(OH)-CH_2-CH_3\)
2 \(CH_3-CH(OH)-CH_2-CH_2-CH_3\)
3 \(CH_3-CH(OH)-CH_3\)
4 \(CH_3-CH_2-CH(OH)-C_2H_5\)
ALCOHOLS, PHENOLS AND ETHER

15517 Glycerol \(\xrightarrow{{KHS{O_4}}}A\xrightarrow{{LiAl{H_4}}}B\)\(A\) and \(B\) are :

1 Acrolein, allyl alcohol
2 Glyceryl sulphate, acrylic acid
3 Allyl alcohol, acrolein
4 Only acrolein (\(B\) is not formed)