11. ALCOHOLS, PHENOLS AND ETHERS
ALCOHOLS, PHENOLS AND ETHER

15436 The electrophile involved in the below reaction is

1 trichloromethyl anion \((\mathop C\limits^\circleddash Cl_3 )\)
2 formyl cation \((\mathop C\limits^ \oplus  HO)\)
3 dichloromethyl cation \((\mathop C\limits^ \oplus   HCl_2 )\)
4 dichlorocarbene \((: \,CCl_2)\)
ALCOHOLS, PHENOLS AND ETHER

15439 From amongst the following alcohols the one that would react fastest with conc. \(HCl\) and anhydrous \(ZnCl_2,\) is

1 \(2-\) Butanol
2 \(2-\) Methylpropan\(-2-\)ol
3 \(2-\) Methylpropanol
4 \(1-\) Butanol
ALCOHOLS, PHENOLS AND ETHER

15440 The main product of the following reaction is\({C_6}{H_5}C{H_2}CH(OH)CH{(C{H_3})_2}\xrightarrow{{conc.\,{H_2}S{O_4}}}\,?\)

1 355-a314
2 355-b314
3 355-c314
4 355-d314
ALCOHOLS, PHENOLS AND ETHER

15441 Phenol is heated with a solution of mixture of \(KBr\) and \(KBrO_3.\) The major product obtained in the above reaction is :

1 \(2-\) Bromophenol
2 \(3-\) Bromophenol
3 \(4-\) Bromophenol
4 \(2, 4, 6-\) Tribromophenol
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ALCOHOLS, PHENOLS AND ETHER

15436 The electrophile involved in the below reaction is

1 trichloromethyl anion \((\mathop C\limits^\circleddash Cl_3 )\)
2 formyl cation \((\mathop C\limits^ \oplus  HO)\)
3 dichloromethyl cation \((\mathop C\limits^ \oplus   HCl_2 )\)
4 dichlorocarbene \((: \,CCl_2)\)
ALCOHOLS, PHENOLS AND ETHER

15439 From amongst the following alcohols the one that would react fastest with conc. \(HCl\) and anhydrous \(ZnCl_2,\) is

1 \(2-\) Butanol
2 \(2-\) Methylpropan\(-2-\)ol
3 \(2-\) Methylpropanol
4 \(1-\) Butanol
ALCOHOLS, PHENOLS AND ETHER

15440 The main product of the following reaction is\({C_6}{H_5}C{H_2}CH(OH)CH{(C{H_3})_2}\xrightarrow{{conc.\,{H_2}S{O_4}}}\,?\)

1 355-a314
2 355-b314
3 355-c314
4 355-d314
ALCOHOLS, PHENOLS AND ETHER

15441 Phenol is heated with a solution of mixture of \(KBr\) and \(KBrO_3.\) The major product obtained in the above reaction is :

1 \(2-\) Bromophenol
2 \(3-\) Bromophenol
3 \(4-\) Bromophenol
4 \(2, 4, 6-\) Tribromophenol
ALCOHOLS, PHENOLS AND ETHER

15436 The electrophile involved in the below reaction is

1 trichloromethyl anion \((\mathop C\limits^\circleddash Cl_3 )\)
2 formyl cation \((\mathop C\limits^ \oplus  HO)\)
3 dichloromethyl cation \((\mathop C\limits^ \oplus   HCl_2 )\)
4 dichlorocarbene \((: \,CCl_2)\)
ALCOHOLS, PHENOLS AND ETHER

15439 From amongst the following alcohols the one that would react fastest with conc. \(HCl\) and anhydrous \(ZnCl_2,\) is

1 \(2-\) Butanol
2 \(2-\) Methylpropan\(-2-\)ol
3 \(2-\) Methylpropanol
4 \(1-\) Butanol
ALCOHOLS, PHENOLS AND ETHER

15440 The main product of the following reaction is\({C_6}{H_5}C{H_2}CH(OH)CH{(C{H_3})_2}\xrightarrow{{conc.\,{H_2}S{O_4}}}\,?\)

1 355-a314
2 355-b314
3 355-c314
4 355-d314
ALCOHOLS, PHENOLS AND ETHER

15441 Phenol is heated with a solution of mixture of \(KBr\) and \(KBrO_3.\) The major product obtained in the above reaction is :

1 \(2-\) Bromophenol
2 \(3-\) Bromophenol
3 \(4-\) Bromophenol
4 \(2, 4, 6-\) Tribromophenol
ALCOHOLS, PHENOLS AND ETHER

15436 The electrophile involved in the below reaction is

1 trichloromethyl anion \((\mathop C\limits^\circleddash Cl_3 )\)
2 formyl cation \((\mathop C\limits^ \oplus  HO)\)
3 dichloromethyl cation \((\mathop C\limits^ \oplus   HCl_2 )\)
4 dichlorocarbene \((: \,CCl_2)\)
ALCOHOLS, PHENOLS AND ETHER

15439 From amongst the following alcohols the one that would react fastest with conc. \(HCl\) and anhydrous \(ZnCl_2,\) is

1 \(2-\) Butanol
2 \(2-\) Methylpropan\(-2-\)ol
3 \(2-\) Methylpropanol
4 \(1-\) Butanol
ALCOHOLS, PHENOLS AND ETHER

15440 The main product of the following reaction is\({C_6}{H_5}C{H_2}CH(OH)CH{(C{H_3})_2}\xrightarrow{{conc.\,{H_2}S{O_4}}}\,?\)

1 355-a314
2 355-b314
3 355-c314
4 355-d314
ALCOHOLS, PHENOLS AND ETHER

15441 Phenol is heated with a solution of mixture of \(KBr\) and \(KBrO_3.\) The major product obtained in the above reaction is :

1 \(2-\) Bromophenol
2 \(3-\) Bromophenol
3 \(4-\) Bromophenol
4 \(2, 4, 6-\) Tribromophenol
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