15501
When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of
1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
Explanation:
The \((- OH )\) group on phenol unlike that of alcohol, is difficult to replace by a halogen, e.g., halogen acids have no action, and \(PX _3\) yields only phosphorous esters. Phenol reacts with \(PCl _5\) or \(PBr _5\), when the \((- OH )\) group of phenol is replaced by a halogen atom. The yield of chloro or bromo benzene is small the main product is triphenyl phosphate \(( PhO )_3 P = O\) or \(Ph _3 PO _4\).
Three membered epoxide ring has ring strain. So, on reaction with nucleophile \(\left( C _2 H _5 O ^{\ominus}\right)\) on less hindered carbon. It cleave epoxide ring and then negative oxygen atom attack to substitute chlorine because chlorine is good leaving group.
ALCOHOLS, PHENOLS AND ETHER
15503
Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?
1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
Explanation:
I will form di-iodide on reaction with excess \(HI\). In first step it will form \(OH - CH _2- CH _2- CH _2- CH _2- CH _2 I\) but then again on reaction with \(HI\) it will form \(ICH _2- CH _2- CH _2- CH _2-CH _2 I\)
ALCOHOLS, PHENOLS AND ETHER
15504
Ethanol on reaction with acetic anhydride gives
15501
When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of
1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
Explanation:
The \((- OH )\) group on phenol unlike that of alcohol, is difficult to replace by a halogen, e.g., halogen acids have no action, and \(PX _3\) yields only phosphorous esters. Phenol reacts with \(PCl _5\) or \(PBr _5\), when the \((- OH )\) group of phenol is replaced by a halogen atom. The yield of chloro or bromo benzene is small the main product is triphenyl phosphate \(( PhO )_3 P = O\) or \(Ph _3 PO _4\).
Three membered epoxide ring has ring strain. So, on reaction with nucleophile \(\left( C _2 H _5 O ^{\ominus}\right)\) on less hindered carbon. It cleave epoxide ring and then negative oxygen atom attack to substitute chlorine because chlorine is good leaving group.
ALCOHOLS, PHENOLS AND ETHER
15503
Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?
1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
Explanation:
I will form di-iodide on reaction with excess \(HI\). In first step it will form \(OH - CH _2- CH _2- CH _2- CH _2- CH _2 I\) but then again on reaction with \(HI\) it will form \(ICH _2- CH _2- CH _2- CH _2-CH _2 I\)
ALCOHOLS, PHENOLS AND ETHER
15504
Ethanol on reaction with acetic anhydride gives
15501
When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of
1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
Explanation:
The \((- OH )\) group on phenol unlike that of alcohol, is difficult to replace by a halogen, e.g., halogen acids have no action, and \(PX _3\) yields only phosphorous esters. Phenol reacts with \(PCl _5\) or \(PBr _5\), when the \((- OH )\) group of phenol is replaced by a halogen atom. The yield of chloro or bromo benzene is small the main product is triphenyl phosphate \(( PhO )_3 P = O\) or \(Ph _3 PO _4\).
Three membered epoxide ring has ring strain. So, on reaction with nucleophile \(\left( C _2 H _5 O ^{\ominus}\right)\) on less hindered carbon. It cleave epoxide ring and then negative oxygen atom attack to substitute chlorine because chlorine is good leaving group.
ALCOHOLS, PHENOLS AND ETHER
15503
Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?
1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
Explanation:
I will form di-iodide on reaction with excess \(HI\). In first step it will form \(OH - CH _2- CH _2- CH _2- CH _2- CH _2 I\) but then again on reaction with \(HI\) it will form \(ICH _2- CH _2- CH _2- CH _2-CH _2 I\)
ALCOHOLS, PHENOLS AND ETHER
15504
Ethanol on reaction with acetic anhydride gives
15501
When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of
1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
Explanation:
The \((- OH )\) group on phenol unlike that of alcohol, is difficult to replace by a halogen, e.g., halogen acids have no action, and \(PX _3\) yields only phosphorous esters. Phenol reacts with \(PCl _5\) or \(PBr _5\), when the \((- OH )\) group of phenol is replaced by a halogen atom. The yield of chloro or bromo benzene is small the main product is triphenyl phosphate \(( PhO )_3 P = O\) or \(Ph _3 PO _4\).
Three membered epoxide ring has ring strain. So, on reaction with nucleophile \(\left( C _2 H _5 O ^{\ominus}\right)\) on less hindered carbon. It cleave epoxide ring and then negative oxygen atom attack to substitute chlorine because chlorine is good leaving group.
ALCOHOLS, PHENOLS AND ETHER
15503
Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?
1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
Explanation:
I will form di-iodide on reaction with excess \(HI\). In first step it will form \(OH - CH _2- CH _2- CH _2- CH _2- CH _2 I\) but then again on reaction with \(HI\) it will form \(ICH _2- CH _2- CH _2- CH _2-CH _2 I\)
ALCOHOLS, PHENOLS AND ETHER
15504
Ethanol on reaction with acetic anhydride gives
15501
When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of
1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
Explanation:
The \((- OH )\) group on phenol unlike that of alcohol, is difficult to replace by a halogen, e.g., halogen acids have no action, and \(PX _3\) yields only phosphorous esters. Phenol reacts with \(PCl _5\) or \(PBr _5\), when the \((- OH )\) group of phenol is replaced by a halogen atom. The yield of chloro or bromo benzene is small the main product is triphenyl phosphate \(( PhO )_3 P = O\) or \(Ph _3 PO _4\).
Three membered epoxide ring has ring strain. So, on reaction with nucleophile \(\left( C _2 H _5 O ^{\ominus}\right)\) on less hindered carbon. It cleave epoxide ring and then negative oxygen atom attack to substitute chlorine because chlorine is good leaving group.
ALCOHOLS, PHENOLS AND ETHER
15503
Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?
1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
Explanation:
I will form di-iodide on reaction with excess \(HI\). In first step it will form \(OH - CH _2- CH _2- CH _2- CH _2- CH _2 I\) but then again on reaction with \(HI\) it will form \(ICH _2- CH _2- CH _2- CH _2-CH _2 I\)
ALCOHOLS, PHENOLS AND ETHER
15504
Ethanol on reaction with acetic anhydride gives