11. ALCOHOLS, PHENOLS AND ETHERS
ALCOHOLS, PHENOLS AND ETHER

15524 Oxalic acid \(+ A\) \(\rightarrow\)  \([Figure]\)hence \(A\) \(\xrightarrow{{conc.\,{H_2}S{O_4}}}\) \(B,\) \(B\) is :

1 355-a351
2 355-b351
3 $\begin{array}{*{20}{c}}
  {C{H_2} - O - C{H_2}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,} 
\end{array}$
4 None
ALCOHOLS, PHENOLS AND ETHER

15501 When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of

1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
ALCOHOLS, PHENOLS AND ETHER

15502 In the following reaction, final product is

1 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}O{C_2}{H_5}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}$
2 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}ONa} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {O{C_2}{H_5}} 
\end{array}$
3 355-c328
4 355-d328
ALCOHOLS, PHENOLS AND ETHER

15503 Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?

1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
ALCOHOLS, PHENOLS AND ETHER

15504 Ethanol on reaction with acetic anhydride gives

1 Acetic ester
2 Formic ester
3 Ethanoic acid
4 Acetic ester and Ethanoic acid both
ALCOHOLS, PHENOLS AND ETHER

15524 Oxalic acid \(+ A\) \(\rightarrow\)  \([Figure]\)hence \(A\) \(\xrightarrow{{conc.\,{H_2}S{O_4}}}\) \(B,\) \(B\) is :

1 355-a351
2 355-b351
3 $\begin{array}{*{20}{c}}
  {C{H_2} - O - C{H_2}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,} 
\end{array}$
4 None
ALCOHOLS, PHENOLS AND ETHER

15501 When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of

1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
ALCOHOLS, PHENOLS AND ETHER

15502 In the following reaction, final product is

1 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}O{C_2}{H_5}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}$
2 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}ONa} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {O{C_2}{H_5}} 
\end{array}$
3 355-c328
4 355-d328
ALCOHOLS, PHENOLS AND ETHER

15503 Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?

1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
ALCOHOLS, PHENOLS AND ETHER

15504 Ethanol on reaction with acetic anhydride gives

1 Acetic ester
2 Formic ester
3 Ethanoic acid
4 Acetic ester and Ethanoic acid both
ALCOHOLS, PHENOLS AND ETHER

15524 Oxalic acid \(+ A\) \(\rightarrow\)  \([Figure]\)hence \(A\) \(\xrightarrow{{conc.\,{H_2}S{O_4}}}\) \(B,\) \(B\) is :

1 355-a351
2 355-b351
3 $\begin{array}{*{20}{c}}
  {C{H_2} - O - C{H_2}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,} 
\end{array}$
4 None
ALCOHOLS, PHENOLS AND ETHER

15501 When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of

1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
ALCOHOLS, PHENOLS AND ETHER

15502 In the following reaction, final product is

1 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}O{C_2}{H_5}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}$
2 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}ONa} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {O{C_2}{H_5}} 
\end{array}$
3 355-c328
4 355-d328
ALCOHOLS, PHENOLS AND ETHER

15503 Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?

1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
ALCOHOLS, PHENOLS AND ETHER

15504 Ethanol on reaction with acetic anhydride gives

1 Acetic ester
2 Formic ester
3 Ethanoic acid
4 Acetic ester and Ethanoic acid both
ALCOHOLS, PHENOLS AND ETHER

15524 Oxalic acid \(+ A\) \(\rightarrow\)  \([Figure]\)hence \(A\) \(\xrightarrow{{conc.\,{H_2}S{O_4}}}\) \(B,\) \(B\) is :

1 355-a351
2 355-b351
3 $\begin{array}{*{20}{c}}
  {C{H_2} - O - C{H_2}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,} 
\end{array}$
4 None
ALCOHOLS, PHENOLS AND ETHER

15501 When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of

1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
ALCOHOLS, PHENOLS AND ETHER

15502 In the following reaction, final product is

1 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}O{C_2}{H_5}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}$
2 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}ONa} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {O{C_2}{H_5}} 
\end{array}$
3 355-c328
4 355-d328
ALCOHOLS, PHENOLS AND ETHER

15503 Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?

1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
ALCOHOLS, PHENOLS AND ETHER

15504 Ethanol on reaction with acetic anhydride gives

1 Acetic ester
2 Formic ester
3 Ethanoic acid
4 Acetic ester and Ethanoic acid both
ALCOHOLS, PHENOLS AND ETHER

15524 Oxalic acid \(+ A\) \(\rightarrow\)  \([Figure]\)hence \(A\) \(\xrightarrow{{conc.\,{H_2}S{O_4}}}\) \(B,\) \(B\) is :

1 355-a351
2 355-b351
3 $\begin{array}{*{20}{c}}
  {C{H_2} - O - C{H_2}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,\,\,} 
\end{array}$
4 None
ALCOHOLS, PHENOLS AND ETHER

15501 When phenol is treated with \(PCl_5,\) the yield of chlorobenzene is generally poor because of the formation of

1 Benzoyl chloride
2 \(p\,-\) chorophenol
3 \(o\,-\) chlorophenol
4 Triphenyl phosphate
ALCOHOLS, PHENOLS AND ETHER

15502 In the following reaction, final product is

1 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}O{C_2}{H_5}} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}$
2 $\begin{array}{*{20}{c}}
  {ClC{H_2}CH\mathop C\limits^{14} {H_2}ONa} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {O{C_2}{H_5}} 
\end{array}$
3 355-c328
4 355-d328
ALCOHOLS, PHENOLS AND ETHER

15503 Consider the reaction of \(HI\) with the following :Which forms di-iodide on reaction with \(HI \) (excess) ?

1 \(I\) and \(II\) both
2 \(II\) only
3 \(I\) only
4 none
ALCOHOLS, PHENOLS AND ETHER

15504 Ethanol on reaction with acetic anhydride gives

1 Acetic ester
2 Formic ester
3 Ethanoic acid
4 Acetic ester and Ethanoic acid both