00. Properties of Alkyl Halides
HALOALKANES AND HALOARENES

90854 Excess of isobutane on reaction with $\mathrm{Br}_{2}$ in presence of light at $125^{\circ} \mathrm{C}$ gives which one of the following, as the major product?

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2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90855 Reaction of Grignard reagent, $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{MgBr}$ with $\mathrm{C}_{8} \mathrm{H}_{8} \mathrm{O}$ followed by hydrolysis gives compound ' $A$ ', which reacts instantly with Lucas reagent to give compound $\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{13} \mathrm{Cl}$.
The compound $B$ is:

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90860 When $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{Br}$ reacts with sodium acetylide, the main product is

1 1-butane
2 1-butyne
3 1-butene
4 3-butane
HALOALKANES AND HALOARENES

90861 The boiling point of alkyl halide are higher than those of corresponding alkanes because of

1 dipole-dipole interaction
2 dipole-induced dipole interaction
3 H-bonding
4 None of the above
HALOALKANES AND HALOARENES

90945 Among the choices of alkyl bromide, the least reactive bromide in a $S_{N} 2$ reaction is

1 1-bromopentane
2 2-bromo-2-methylbutane
3 1-bromo-3methylbutane
4 1-bromo-2-methylbutane.
HALOALKANES AND HALOARENES

90854 Excess of isobutane on reaction with $\mathrm{Br}_{2}$ in presence of light at $125^{\circ} \mathrm{C}$ gives which one of the following, as the major product?

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90855 Reaction of Grignard reagent, $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{MgBr}$ with $\mathrm{C}_{8} \mathrm{H}_{8} \mathrm{O}$ followed by hydrolysis gives compound ' $A$ ', which reacts instantly with Lucas reagent to give compound $\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{13} \mathrm{Cl}$.
The compound $B$ is:

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90860 When $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{Br}$ reacts with sodium acetylide, the main product is

1 1-butane
2 1-butyne
3 1-butene
4 3-butane
HALOALKANES AND HALOARENES

90861 The boiling point of alkyl halide are higher than those of corresponding alkanes because of

1 dipole-dipole interaction
2 dipole-induced dipole interaction
3 H-bonding
4 None of the above
HALOALKANES AND HALOARENES

90945 Among the choices of alkyl bromide, the least reactive bromide in a $S_{N} 2$ reaction is

1 1-bromopentane
2 2-bromo-2-methylbutane
3 1-bromo-3methylbutane
4 1-bromo-2-methylbutane.
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HALOALKANES AND HALOARENES

90854 Excess of isobutane on reaction with $\mathrm{Br}_{2}$ in presence of light at $125^{\circ} \mathrm{C}$ gives which one of the following, as the major product?

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90855 Reaction of Grignard reagent, $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{MgBr}$ with $\mathrm{C}_{8} \mathrm{H}_{8} \mathrm{O}$ followed by hydrolysis gives compound ' $A$ ', which reacts instantly with Lucas reagent to give compound $\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{13} \mathrm{Cl}$.
The compound $B$ is:

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90860 When $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{Br}$ reacts with sodium acetylide, the main product is

1 1-butane
2 1-butyne
3 1-butene
4 3-butane
HALOALKANES AND HALOARENES

90861 The boiling point of alkyl halide are higher than those of corresponding alkanes because of

1 dipole-dipole interaction
2 dipole-induced dipole interaction
3 H-bonding
4 None of the above
HALOALKANES AND HALOARENES

90945 Among the choices of alkyl bromide, the least reactive bromide in a $S_{N} 2$ reaction is

1 1-bromopentane
2 2-bromo-2-methylbutane
3 1-bromo-3methylbutane
4 1-bromo-2-methylbutane.
HALOALKANES AND HALOARENES

90854 Excess of isobutane on reaction with $\mathrm{Br}_{2}$ in presence of light at $125^{\circ} \mathrm{C}$ gives which one of the following, as the major product?

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90855 Reaction of Grignard reagent, $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{MgBr}$ with $\mathrm{C}_{8} \mathrm{H}_{8} \mathrm{O}$ followed by hydrolysis gives compound ' $A$ ', which reacts instantly with Lucas reagent to give compound $\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{13} \mathrm{Cl}$.
The compound $B$ is:

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90860 When $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{Br}$ reacts with sodium acetylide, the main product is

1 1-butane
2 1-butyne
3 1-butene
4 3-butane
HALOALKANES AND HALOARENES

90861 The boiling point of alkyl halide are higher than those of corresponding alkanes because of

1 dipole-dipole interaction
2 dipole-induced dipole interaction
3 H-bonding
4 None of the above
HALOALKANES AND HALOARENES

90945 Among the choices of alkyl bromide, the least reactive bromide in a $S_{N} 2$ reaction is

1 1-bromopentane
2 2-bromo-2-methylbutane
3 1-bromo-3methylbutane
4 1-bromo-2-methylbutane.
HALOALKANES AND HALOARENES

90854 Excess of isobutane on reaction with $\mathrm{Br}_{2}$ in presence of light at $125^{\circ} \mathrm{C}$ gives which one of the following, as the major product?

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90855 Reaction of Grignard reagent, $\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{MgBr}$ with $\mathrm{C}_{8} \mathrm{H}_{8} \mathrm{O}$ followed by hydrolysis gives compound ' $A$ ', which reacts instantly with Lucas reagent to give compound $\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{13} \mathrm{Cl}$.
The compound $B$ is:

1 original image
2 original image
3 original image
4 original image
HALOALKANES AND HALOARENES

90860 When $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{Br}$ reacts with sodium acetylide, the main product is

1 1-butane
2 1-butyne
3 1-butene
4 3-butane
HALOALKANES AND HALOARENES

90861 The boiling point of alkyl halide are higher than those of corresponding alkanes because of

1 dipole-dipole interaction
2 dipole-induced dipole interaction
3 H-bonding
4 None of the above
HALOALKANES AND HALOARENES

90945 Among the choices of alkyl bromide, the least reactive bromide in a $S_{N} 2$ reaction is

1 1-bromopentane
2 2-bromo-2-methylbutane
3 1-bromo-3methylbutane
4 1-bromo-2-methylbutane.