00. Electronic effect and Its Applications
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
GENERAL ORGANIC CHEMISTRY

231292 The correct order for reaction with alcoholic $\mathrm{KOH}$ of the following compounds is
(i)
(ii)
(iii)
(iv)

1 i $>$ ii $>$ iii $>$ iv
2 i $>$ iii $>$ ii $>$ iv
3 iv $>$ ii $>$ iii $>$ i
4 i $>$ iv $>$ ii $>$ iii
GENERAL ORGANIC CHEMISTRY

231293 Correct order of electrophilic substitution reaction is:

1 i $>$ ii $>$ iii $>$ iv
2 iv $>$ ii $>$ i $>$ iii
3 ii $>$ i $>$ iii $>$ iv
4 ii $>$ i $>$ iv $>$ iii
GENERAL ORGANIC CHEMISTRY

231294 Correct order of basic strength is

1 I $>$ II $>$ III $>$ IV
2 II $>$ III $>$ I $>$ IV
3 III $>$ II $>$ I $>$ IV
4 IV $>$ I $>$ II $>$ III
GENERAL ORGANIC CHEMISTRY

231295 Assertion: The carbocation $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$ is less Stable than $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$.
Reason: In case of $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$, the strongly electron-withdrawing $-\mathrm{CF}_{3}$ group intensifies the +ve charge but in case of $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$, the lone pairs of electrons on each of the three $F$-atoms overlap with the empty p-orbita of the carbocation carbon thereby dispersing the $+\mathrm{ve}$ charge.

1 If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
2 If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
3 If the Assertion is correct but Reason is incorrect.
4 If the Assertion is incorrect but the Reason is correct.
GENERAL ORGANIC CHEMISTRY

231292 The correct order for reaction with alcoholic $\mathrm{KOH}$ of the following compounds is
(i)
(ii)
(iii)
(iv)

1 i $>$ ii $>$ iii $>$ iv
2 i $>$ iii $>$ ii $>$ iv
3 iv $>$ ii $>$ iii $>$ i
4 i $>$ iv $>$ ii $>$ iii
GENERAL ORGANIC CHEMISTRY

231293 Correct order of electrophilic substitution reaction is:

1 i $>$ ii $>$ iii $>$ iv
2 iv $>$ ii $>$ i $>$ iii
3 ii $>$ i $>$ iii $>$ iv
4 ii $>$ i $>$ iv $>$ iii
GENERAL ORGANIC CHEMISTRY

231294 Correct order of basic strength is

1 I $>$ II $>$ III $>$ IV
2 II $>$ III $>$ I $>$ IV
3 III $>$ II $>$ I $>$ IV
4 IV $>$ I $>$ II $>$ III
GENERAL ORGANIC CHEMISTRY

231295 Assertion: The carbocation $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$ is less Stable than $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$.
Reason: In case of $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$, the strongly electron-withdrawing $-\mathrm{CF}_{3}$ group intensifies the +ve charge but in case of $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$, the lone pairs of electrons on each of the three $F$-atoms overlap with the empty p-orbita of the carbocation carbon thereby dispersing the $+\mathrm{ve}$ charge.

1 If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
2 If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
3 If the Assertion is correct but Reason is incorrect.
4 If the Assertion is incorrect but the Reason is correct.
GENERAL ORGANIC CHEMISTRY

231292 The correct order for reaction with alcoholic $\mathrm{KOH}$ of the following compounds is
(i)
(ii)
(iii)
(iv)

1 i $>$ ii $>$ iii $>$ iv
2 i $>$ iii $>$ ii $>$ iv
3 iv $>$ ii $>$ iii $>$ i
4 i $>$ iv $>$ ii $>$ iii
GENERAL ORGANIC CHEMISTRY

231293 Correct order of electrophilic substitution reaction is:

1 i $>$ ii $>$ iii $>$ iv
2 iv $>$ ii $>$ i $>$ iii
3 ii $>$ i $>$ iii $>$ iv
4 ii $>$ i $>$ iv $>$ iii
GENERAL ORGANIC CHEMISTRY

231294 Correct order of basic strength is

1 I $>$ II $>$ III $>$ IV
2 II $>$ III $>$ I $>$ IV
3 III $>$ II $>$ I $>$ IV
4 IV $>$ I $>$ II $>$ III
GENERAL ORGANIC CHEMISTRY

231295 Assertion: The carbocation $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$ is less Stable than $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$.
Reason: In case of $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$, the strongly electron-withdrawing $-\mathrm{CF}_{3}$ group intensifies the +ve charge but in case of $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$, the lone pairs of electrons on each of the three $F$-atoms overlap with the empty p-orbita of the carbocation carbon thereby dispersing the $+\mathrm{ve}$ charge.

1 If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
2 If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
3 If the Assertion is correct but Reason is incorrect.
4 If the Assertion is incorrect but the Reason is correct.
GENERAL ORGANIC CHEMISTRY

231292 The correct order for reaction with alcoholic $\mathrm{KOH}$ of the following compounds is
(i)
(ii)
(iii)
(iv)

1 i $>$ ii $>$ iii $>$ iv
2 i $>$ iii $>$ ii $>$ iv
3 iv $>$ ii $>$ iii $>$ i
4 i $>$ iv $>$ ii $>$ iii
GENERAL ORGANIC CHEMISTRY

231293 Correct order of electrophilic substitution reaction is:

1 i $>$ ii $>$ iii $>$ iv
2 iv $>$ ii $>$ i $>$ iii
3 ii $>$ i $>$ iii $>$ iv
4 ii $>$ i $>$ iv $>$ iii
GENERAL ORGANIC CHEMISTRY

231294 Correct order of basic strength is

1 I $>$ II $>$ III $>$ IV
2 II $>$ III $>$ I $>$ IV
3 III $>$ II $>$ I $>$ IV
4 IV $>$ I $>$ II $>$ III
GENERAL ORGANIC CHEMISTRY

231295 Assertion: The carbocation $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$ is less Stable than $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$.
Reason: In case of $\mathrm{CF}_{3}-\stackrel{+}{\mathrm{C}} \mathrm{H}_{2}$, the strongly electron-withdrawing $-\mathrm{CF}_{3}$ group intensifies the +ve charge but in case of $\stackrel{+}{\mathrm{C}} \mathrm{F}_{3}$, the lone pairs of electrons on each of the three $F$-atoms overlap with the empty p-orbita of the carbocation carbon thereby dispersing the $+\mathrm{ve}$ charge.

1 If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
2 If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
3 If the Assertion is correct but Reason is incorrect.
4 If the Assertion is incorrect but the Reason is correct.