231220
Arrange the following in decreasing order of their $\mathbf{p K} \mathbf{K}_{\mathbf{b}}$ values
1 d $>$ a $>$ c $>$ b
2 a $>$ b $>$ d $>$ c
3 d $>$ c $>$ b $>$ a
4 a $>$ c $>$ d $>$ b
Explanation:
$\mathrm{pK}_{\mathrm{b}}$ is defined for base which donates lone pair is called Base. For strong base $\rightarrow$ easily give lone pair and high electron density For strong base $\rightarrow$ value of $K_{b}$ is high. $\mathrm{pK}_{\mathrm{b}}=-\log \mathrm{K}_{\mathrm{b}}$ $\downarrow \mathrm{pK}_{\mathrm{b}}=\log \frac{1}{\mathrm{~K}_{\mathrm{b}} \uparrow}$ For the compounds having greater value of $\mathrm{K}_{\mathrm{b}}$ have lesser $\mathrm{pK}_{\mathrm{b}}$ Hence, correct order is (d) $>$ (c) $>$ (b) $>$ (a)
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231221
The correct order of acidity of the following is
1 III $>$ II $>$ I
2 II $>$ III $>$ I
3 I $>$ II $>$ III
4 III $>$ I $>$ II
Explanation:
The decreasing order of acidity is-
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231219
Identify the ortho and para directing groups towards aromatic electrophilic substitution reactions from the following list
1 I, IV, V
2 II, III, VI
3 I, II, IV
4 IV, V, VI
Explanation:
When electron donating group attach with the benzene ring then the group activate the ortho and para position the electron donating group increases the electron density on ortho and para position that's why aromatic electrophilic substitution reaction take place. Here, $-\mathrm{OH},-\mathrm{OCH}_{3}-\mathrm{NHCOCH}_{3}$ are electron donating group which increases the electron density on ortho and para position.
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231224
The correct order of the stability of the following compounds based on hyper conjugation is
1 IV $>$ III $>$ II $>$ I
2 IV $>$ II $>$ I $>$ III
3 IV $>$ II $>$ III $>$ I
4 IV $>$ I $>$ III $>$ II
Explanation:
The number of 2-h is directly proportional to the stability of alkene The correct order of the stability is-
231220
Arrange the following in decreasing order of their $\mathbf{p K} \mathbf{K}_{\mathbf{b}}$ values
1 d $>$ a $>$ c $>$ b
2 a $>$ b $>$ d $>$ c
3 d $>$ c $>$ b $>$ a
4 a $>$ c $>$ d $>$ b
Explanation:
$\mathrm{pK}_{\mathrm{b}}$ is defined for base which donates lone pair is called Base. For strong base $\rightarrow$ easily give lone pair and high electron density For strong base $\rightarrow$ value of $K_{b}$ is high. $\mathrm{pK}_{\mathrm{b}}=-\log \mathrm{K}_{\mathrm{b}}$ $\downarrow \mathrm{pK}_{\mathrm{b}}=\log \frac{1}{\mathrm{~K}_{\mathrm{b}} \uparrow}$ For the compounds having greater value of $\mathrm{K}_{\mathrm{b}}$ have lesser $\mathrm{pK}_{\mathrm{b}}$ Hence, correct order is (d) $>$ (c) $>$ (b) $>$ (a)
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231221
The correct order of acidity of the following is
1 III $>$ II $>$ I
2 II $>$ III $>$ I
3 I $>$ II $>$ III
4 III $>$ I $>$ II
Explanation:
The decreasing order of acidity is-
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231219
Identify the ortho and para directing groups towards aromatic electrophilic substitution reactions from the following list
1 I, IV, V
2 II, III, VI
3 I, II, IV
4 IV, V, VI
Explanation:
When electron donating group attach with the benzene ring then the group activate the ortho and para position the electron donating group increases the electron density on ortho and para position that's why aromatic electrophilic substitution reaction take place. Here, $-\mathrm{OH},-\mathrm{OCH}_{3}-\mathrm{NHCOCH}_{3}$ are electron donating group which increases the electron density on ortho and para position.
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231224
The correct order of the stability of the following compounds based on hyper conjugation is
1 IV $>$ III $>$ II $>$ I
2 IV $>$ II $>$ I $>$ III
3 IV $>$ II $>$ III $>$ I
4 IV $>$ I $>$ III $>$ II
Explanation:
The number of 2-h is directly proportional to the stability of alkene The correct order of the stability is-
231220
Arrange the following in decreasing order of their $\mathbf{p K} \mathbf{K}_{\mathbf{b}}$ values
1 d $>$ a $>$ c $>$ b
2 a $>$ b $>$ d $>$ c
3 d $>$ c $>$ b $>$ a
4 a $>$ c $>$ d $>$ b
Explanation:
$\mathrm{pK}_{\mathrm{b}}$ is defined for base which donates lone pair is called Base. For strong base $\rightarrow$ easily give lone pair and high electron density For strong base $\rightarrow$ value of $K_{b}$ is high. $\mathrm{pK}_{\mathrm{b}}=-\log \mathrm{K}_{\mathrm{b}}$ $\downarrow \mathrm{pK}_{\mathrm{b}}=\log \frac{1}{\mathrm{~K}_{\mathrm{b}} \uparrow}$ For the compounds having greater value of $\mathrm{K}_{\mathrm{b}}$ have lesser $\mathrm{pK}_{\mathrm{b}}$ Hence, correct order is (d) $>$ (c) $>$ (b) $>$ (a)
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231221
The correct order of acidity of the following is
1 III $>$ II $>$ I
2 II $>$ III $>$ I
3 I $>$ II $>$ III
4 III $>$ I $>$ II
Explanation:
The decreasing order of acidity is-
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231219
Identify the ortho and para directing groups towards aromatic electrophilic substitution reactions from the following list
1 I, IV, V
2 II, III, VI
3 I, II, IV
4 IV, V, VI
Explanation:
When electron donating group attach with the benzene ring then the group activate the ortho and para position the electron donating group increases the electron density on ortho and para position that's why aromatic electrophilic substitution reaction take place. Here, $-\mathrm{OH},-\mathrm{OCH}_{3}-\mathrm{NHCOCH}_{3}$ are electron donating group which increases the electron density on ortho and para position.
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231224
The correct order of the stability of the following compounds based on hyper conjugation is
1 IV $>$ III $>$ II $>$ I
2 IV $>$ II $>$ I $>$ III
3 IV $>$ II $>$ III $>$ I
4 IV $>$ I $>$ III $>$ II
Explanation:
The number of 2-h is directly proportional to the stability of alkene The correct order of the stability is-
231220
Arrange the following in decreasing order of their $\mathbf{p K} \mathbf{K}_{\mathbf{b}}$ values
1 d $>$ a $>$ c $>$ b
2 a $>$ b $>$ d $>$ c
3 d $>$ c $>$ b $>$ a
4 a $>$ c $>$ d $>$ b
Explanation:
$\mathrm{pK}_{\mathrm{b}}$ is defined for base which donates lone pair is called Base. For strong base $\rightarrow$ easily give lone pair and high electron density For strong base $\rightarrow$ value of $K_{b}$ is high. $\mathrm{pK}_{\mathrm{b}}=-\log \mathrm{K}_{\mathrm{b}}$ $\downarrow \mathrm{pK}_{\mathrm{b}}=\log \frac{1}{\mathrm{~K}_{\mathrm{b}} \uparrow}$ For the compounds having greater value of $\mathrm{K}_{\mathrm{b}}$ have lesser $\mathrm{pK}_{\mathrm{b}}$ Hence, correct order is (d) $>$ (c) $>$ (b) $>$ (a)
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231221
The correct order of acidity of the following is
1 III $>$ II $>$ I
2 II $>$ III $>$ I
3 I $>$ II $>$ III
4 III $>$ I $>$ II
Explanation:
The decreasing order of acidity is-
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231219
Identify the ortho and para directing groups towards aromatic electrophilic substitution reactions from the following list
1 I, IV, V
2 II, III, VI
3 I, II, IV
4 IV, V, VI
Explanation:
When electron donating group attach with the benzene ring then the group activate the ortho and para position the electron donating group increases the electron density on ortho and para position that's why aromatic electrophilic substitution reaction take place. Here, $-\mathrm{OH},-\mathrm{OCH}_{3}-\mathrm{NHCOCH}_{3}$ are electron donating group which increases the electron density on ortho and para position.
AP EAMCET-04.07.2022
GENERAL ORGANIC CHEMISTRY
231224
The correct order of the stability of the following compounds based on hyper conjugation is
1 IV $>$ III $>$ II $>$ I
2 IV $>$ II $>$ I $>$ III
3 IV $>$ II $>$ III $>$ I
4 IV $>$ I $>$ III $>$ II
Explanation:
The number of 2-h is directly proportional to the stability of alkene The correct order of the stability is-
