04. Spectrochemical Series, Complex Stability
COORDINATION COMPOUNDS

274227 Which of the following represents hexadentate ligand?

1 EDTA
2 DMG
3 Ethylenediamine
4 None of the above
COORDINATION COMPOUNDS

274228 The correct order of the ligands, $\mathrm{OH}^{-}, \mathrm{NO}_{3}^{-}$, $\mathbf{P P h}_{3}$, pyridine, according to their increasing field strength is

1 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
2 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<\mathrm{PPh}_{3}<$ pyridine
3 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
4 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<\mathrm{PPh}_{3}<$ pyridine.
COORDINATION COMPOUNDS

274175 Which one of the following metal complexes is most stable?

1 $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
2 $\left[\mathrm{Co}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}$
3 $\left[\mathrm{Co}(\mathrm{en})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right] \mathrm{Cl}_{2}$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}$
COORDINATION COMPOUNDS

274176 The denticity of an organic ligand, biuret is

1 2
2 4
3 3
4 6
COORDINATION COMPOUNDS

274168 The correct order of decreasing field strength of the below given ligands is
\(I - \mathrm{NCS}^{-} \quad II - \mathrm{S}^{2-}\quad III - en \quad IV - \mathrm{SCN}^{-}\)

1 I $>$ II $>$ IV $>$ III
2 III $>$ II $>$ IV $>$ I
3 III $>$ I $>$ IV $>$ II
4 III $>$ IV $>$ I $>$ II
COORDINATION COMPOUNDS

274227 Which of the following represents hexadentate ligand?

1 EDTA
2 DMG
3 Ethylenediamine
4 None of the above
COORDINATION COMPOUNDS

274228 The correct order of the ligands, $\mathrm{OH}^{-}, \mathrm{NO}_{3}^{-}$, $\mathbf{P P h}_{3}$, pyridine, according to their increasing field strength is

1 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
2 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<\mathrm{PPh}_{3}<$ pyridine
3 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
4 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<\mathrm{PPh}_{3}<$ pyridine.
COORDINATION COMPOUNDS

274175 Which one of the following metal complexes is most stable?

1 $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
2 $\left[\mathrm{Co}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}$
3 $\left[\mathrm{Co}(\mathrm{en})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right] \mathrm{Cl}_{2}$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}$
COORDINATION COMPOUNDS

274176 The denticity of an organic ligand, biuret is

1 2
2 4
3 3
4 6
COORDINATION COMPOUNDS

274168 The correct order of decreasing field strength of the below given ligands is
\(I - \mathrm{NCS}^{-} \quad II - \mathrm{S}^{2-}\quad III - en \quad IV - \mathrm{SCN}^{-}\)

1 I $>$ II $>$ IV $>$ III
2 III $>$ II $>$ IV $>$ I
3 III $>$ I $>$ IV $>$ II
4 III $>$ IV $>$ I $>$ II
COORDINATION COMPOUNDS

274227 Which of the following represents hexadentate ligand?

1 EDTA
2 DMG
3 Ethylenediamine
4 None of the above
COORDINATION COMPOUNDS

274228 The correct order of the ligands, $\mathrm{OH}^{-}, \mathrm{NO}_{3}^{-}$, $\mathbf{P P h}_{3}$, pyridine, according to their increasing field strength is

1 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
2 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<\mathrm{PPh}_{3}<$ pyridine
3 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
4 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<\mathrm{PPh}_{3}<$ pyridine.
COORDINATION COMPOUNDS

274175 Which one of the following metal complexes is most stable?

1 $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
2 $\left[\mathrm{Co}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}$
3 $\left[\mathrm{Co}(\mathrm{en})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right] \mathrm{Cl}_{2}$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}$
COORDINATION COMPOUNDS

274176 The denticity of an organic ligand, biuret is

1 2
2 4
3 3
4 6
COORDINATION COMPOUNDS

274168 The correct order of decreasing field strength of the below given ligands is
\(I - \mathrm{NCS}^{-} \quad II - \mathrm{S}^{2-}\quad III - en \quad IV - \mathrm{SCN}^{-}\)

1 I $>$ II $>$ IV $>$ III
2 III $>$ II $>$ IV $>$ I
3 III $>$ I $>$ IV $>$ II
4 III $>$ IV $>$ I $>$ II
COORDINATION COMPOUNDS

274227 Which of the following represents hexadentate ligand?

1 EDTA
2 DMG
3 Ethylenediamine
4 None of the above
COORDINATION COMPOUNDS

274228 The correct order of the ligands, $\mathrm{OH}^{-}, \mathrm{NO}_{3}^{-}$, $\mathbf{P P h}_{3}$, pyridine, according to their increasing field strength is

1 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
2 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<\mathrm{PPh}_{3}<$ pyridine
3 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
4 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<\mathrm{PPh}_{3}<$ pyridine.
COORDINATION COMPOUNDS

274175 Which one of the following metal complexes is most stable?

1 $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
2 $\left[\mathrm{Co}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}$
3 $\left[\mathrm{Co}(\mathrm{en})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right] \mathrm{Cl}_{2}$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}$
COORDINATION COMPOUNDS

274176 The denticity of an organic ligand, biuret is

1 2
2 4
3 3
4 6
COORDINATION COMPOUNDS

274168 The correct order of decreasing field strength of the below given ligands is
\(I - \mathrm{NCS}^{-} \quad II - \mathrm{S}^{2-}\quad III - en \quad IV - \mathrm{SCN}^{-}\)

1 I $>$ II $>$ IV $>$ III
2 III $>$ II $>$ IV $>$ I
3 III $>$ I $>$ IV $>$ II
4 III $>$ IV $>$ I $>$ II
COORDINATION COMPOUNDS

274227 Which of the following represents hexadentate ligand?

1 EDTA
2 DMG
3 Ethylenediamine
4 None of the above
COORDINATION COMPOUNDS

274228 The correct order of the ligands, $\mathrm{OH}^{-}, \mathrm{NO}_{3}^{-}$, $\mathbf{P P h}_{3}$, pyridine, according to their increasing field strength is

1 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
2 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<\mathrm{PPh}_{3}<$ pyridine
3 $\mathrm{OH}^{-}<\mathrm{NO}_{3}^{-}<$Pyridine $<\mathrm{PPh}_{3}$
4 $\mathrm{NO}_{3}^{-}<\mathrm{OH}^{-}<\mathrm{PPh}_{3}<$ pyridine.
COORDINATION COMPOUNDS

274175 Which one of the following metal complexes is most stable?

1 $\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}$
2 $\left[\mathrm{Co}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}$
3 $\left[\mathrm{Co}(\mathrm{en})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right] \mathrm{Cl}_{2}$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}$
COORDINATION COMPOUNDS

274176 The denticity of an organic ligand, biuret is

1 2
2 4
3 3
4 6
COORDINATION COMPOUNDS

274168 The correct order of decreasing field strength of the below given ligands is
\(I - \mathrm{NCS}^{-} \quad II - \mathrm{S}^{2-}\quad III - en \quad IV - \mathrm{SCN}^{-}\)

1 I $>$ II $>$ IV $>$ III
2 III $>$ II $>$ IV $>$ I
3 III $>$ I $>$ IV $>$ II
4 III $>$ IV $>$ I $>$ II