274258
Finely divided iron combines with $\mathrm{CO}$ to give:
1 $\mathrm{Fe}(\mathrm{CO})_{5}$
2 $\mathrm{Fe}_{2}(\mathrm{CO})_{9}$
3 $\mathrm{Fe}_{3}(\mathrm{CO})_{12}$
4 $\mathrm{Fe}(\mathrm{CO})_{6}$
Explanation:
(A) : Finely divided iron combines with CO ligand and forms $\mathrm{Fe}(\mathrm{CO})_{5}$. $\mathrm{Fe}+5 \mathrm{CO} \longrightarrow \mathrm{Fe}(\mathrm{CO})_{5}$
JCECE - 2006
COORDINATION COMPOUNDS
274259
Which does not give a precipitate with $\mathbf{A g N O}_{3}$ solution?
(D) : When $\mathrm{Cl}^{-}$is present outside the complex then it reacts with $\mathrm{AgNO}_{3}$ and give precipitate of $\mathrm{AgCl}$. $\left[\mathrm{CO}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]+\mathrm{AgNO}_{3} \rightarrow \mathrm{NO}$ ppt.
JCECE - 2007
COORDINATION COMPOUNDS
274261
The $\pi$-bonded organometallic compound which has ethene as one of its component is
1 Zeise's salt
2 ferrocene
3 dibenzene chromium
4 tetraethyltin
Explanation:
(A) : Zeise's salt $\mathrm{K}\left[\mathrm{PtCl}_{3}\left(\mathrm{C}_{2} \mathrm{H}_{4}\right)\right]$ is a $\pi$-bonded organometallic compound. Its structure is
JCECE - 2012
COORDINATION COMPOUNDS
274203
Colour of $\mathrm{V}^{4+}$ ion is
1 green
2 violet
3 pink
4 blue
Explanation:
(D) : Colour of $\mathrm{V}^{4+}$ ion is blue. The colour observed corresponds to the complementary colour of the light absorbed. The frequency of light absorbed is determined by the nature of the ligand. Thus, most of the compounds of transition metals are coloured due to d-d transition.
274258
Finely divided iron combines with $\mathrm{CO}$ to give:
1 $\mathrm{Fe}(\mathrm{CO})_{5}$
2 $\mathrm{Fe}_{2}(\mathrm{CO})_{9}$
3 $\mathrm{Fe}_{3}(\mathrm{CO})_{12}$
4 $\mathrm{Fe}(\mathrm{CO})_{6}$
Explanation:
(A) : Finely divided iron combines with CO ligand and forms $\mathrm{Fe}(\mathrm{CO})_{5}$. $\mathrm{Fe}+5 \mathrm{CO} \longrightarrow \mathrm{Fe}(\mathrm{CO})_{5}$
JCECE - 2006
COORDINATION COMPOUNDS
274259
Which does not give a precipitate with $\mathbf{A g N O}_{3}$ solution?
(D) : When $\mathrm{Cl}^{-}$is present outside the complex then it reacts with $\mathrm{AgNO}_{3}$ and give precipitate of $\mathrm{AgCl}$. $\left[\mathrm{CO}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]+\mathrm{AgNO}_{3} \rightarrow \mathrm{NO}$ ppt.
JCECE - 2007
COORDINATION COMPOUNDS
274261
The $\pi$-bonded organometallic compound which has ethene as one of its component is
1 Zeise's salt
2 ferrocene
3 dibenzene chromium
4 tetraethyltin
Explanation:
(A) : Zeise's salt $\mathrm{K}\left[\mathrm{PtCl}_{3}\left(\mathrm{C}_{2} \mathrm{H}_{4}\right)\right]$ is a $\pi$-bonded organometallic compound. Its structure is
JCECE - 2012
COORDINATION COMPOUNDS
274203
Colour of $\mathrm{V}^{4+}$ ion is
1 green
2 violet
3 pink
4 blue
Explanation:
(D) : Colour of $\mathrm{V}^{4+}$ ion is blue. The colour observed corresponds to the complementary colour of the light absorbed. The frequency of light absorbed is determined by the nature of the ligand. Thus, most of the compounds of transition metals are coloured due to d-d transition.
274258
Finely divided iron combines with $\mathrm{CO}$ to give:
1 $\mathrm{Fe}(\mathrm{CO})_{5}$
2 $\mathrm{Fe}_{2}(\mathrm{CO})_{9}$
3 $\mathrm{Fe}_{3}(\mathrm{CO})_{12}$
4 $\mathrm{Fe}(\mathrm{CO})_{6}$
Explanation:
(A) : Finely divided iron combines with CO ligand and forms $\mathrm{Fe}(\mathrm{CO})_{5}$. $\mathrm{Fe}+5 \mathrm{CO} \longrightarrow \mathrm{Fe}(\mathrm{CO})_{5}$
JCECE - 2006
COORDINATION COMPOUNDS
274259
Which does not give a precipitate with $\mathbf{A g N O}_{3}$ solution?
(D) : When $\mathrm{Cl}^{-}$is present outside the complex then it reacts with $\mathrm{AgNO}_{3}$ and give precipitate of $\mathrm{AgCl}$. $\left[\mathrm{CO}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]+\mathrm{AgNO}_{3} \rightarrow \mathrm{NO}$ ppt.
JCECE - 2007
COORDINATION COMPOUNDS
274261
The $\pi$-bonded organometallic compound which has ethene as one of its component is
1 Zeise's salt
2 ferrocene
3 dibenzene chromium
4 tetraethyltin
Explanation:
(A) : Zeise's salt $\mathrm{K}\left[\mathrm{PtCl}_{3}\left(\mathrm{C}_{2} \mathrm{H}_{4}\right)\right]$ is a $\pi$-bonded organometallic compound. Its structure is
JCECE - 2012
COORDINATION COMPOUNDS
274203
Colour of $\mathrm{V}^{4+}$ ion is
1 green
2 violet
3 pink
4 blue
Explanation:
(D) : Colour of $\mathrm{V}^{4+}$ ion is blue. The colour observed corresponds to the complementary colour of the light absorbed. The frequency of light absorbed is determined by the nature of the ligand. Thus, most of the compounds of transition metals are coloured due to d-d transition.
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COORDINATION COMPOUNDS
274258
Finely divided iron combines with $\mathrm{CO}$ to give:
1 $\mathrm{Fe}(\mathrm{CO})_{5}$
2 $\mathrm{Fe}_{2}(\mathrm{CO})_{9}$
3 $\mathrm{Fe}_{3}(\mathrm{CO})_{12}$
4 $\mathrm{Fe}(\mathrm{CO})_{6}$
Explanation:
(A) : Finely divided iron combines with CO ligand and forms $\mathrm{Fe}(\mathrm{CO})_{5}$. $\mathrm{Fe}+5 \mathrm{CO} \longrightarrow \mathrm{Fe}(\mathrm{CO})_{5}$
JCECE - 2006
COORDINATION COMPOUNDS
274259
Which does not give a precipitate with $\mathbf{A g N O}_{3}$ solution?
(D) : When $\mathrm{Cl}^{-}$is present outside the complex then it reacts with $\mathrm{AgNO}_{3}$ and give precipitate of $\mathrm{AgCl}$. $\left[\mathrm{CO}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]+\mathrm{AgNO}_{3} \rightarrow \mathrm{NO}$ ppt.
JCECE - 2007
COORDINATION COMPOUNDS
274261
The $\pi$-bonded organometallic compound which has ethene as one of its component is
1 Zeise's salt
2 ferrocene
3 dibenzene chromium
4 tetraethyltin
Explanation:
(A) : Zeise's salt $\mathrm{K}\left[\mathrm{PtCl}_{3}\left(\mathrm{C}_{2} \mathrm{H}_{4}\right)\right]$ is a $\pi$-bonded organometallic compound. Its structure is
JCECE - 2012
COORDINATION COMPOUNDS
274203
Colour of $\mathrm{V}^{4+}$ ion is
1 green
2 violet
3 pink
4 blue
Explanation:
(D) : Colour of $\mathrm{V}^{4+}$ ion is blue. The colour observed corresponds to the complementary colour of the light absorbed. The frequency of light absorbed is determined by the nature of the ligand. Thus, most of the compounds of transition metals are coloured due to d-d transition.