00. Electrode Potential
ELECTROCHEMISTRY

275892 The emf of a galvanic cell constituted with the electrodes $\mathrm{Zn}^{2+} \mid \mathrm{Zn}(-0.76 \mathrm{~V})$ and $\mathrm{Fe}^{2+} \mid \mathrm{Fe}(-0.41$ $\mathrm{V})$ is

1 $-0.35 \mathrm{~V}$
2 $+1.17 \mathrm{~V}$
3 $+0.35 \mathrm{~V}$
4 $-1.17 \mathrm{~V}$
ELECTROCHEMISTRY

275895 Given that the standard reduction potentials for $\mathrm{M}^{+} / \mathrm{M}$ and $\mathrm{N}^{+} / \mathrm{N}$ electrodes at $298 \mathrm{~K}$ are 0.52 $\mathrm{V}$ and $0.25 \mathrm{~V}$ respectively. Which of the following is correct in respect of the following electrochemical cell?
$\mathbf{M}\left \vert\mathbf{M}^{+} \ \vert \mathbf{N}^{+}\right \vert \mathbf{N}$

1 The overall cell reaction is a spontaneous reaction
2 The standard EMF of the cell is $-0.27 \mathrm{~V}$
3 The standard EMF of the cell is $0.77 \mathrm{~V}$
4 The standard EMF of the cell is $-0.77 \mathrm{~V}$
5 The standard EMF of the cell is $0.27 \mathrm{~V}$
ELECTROCHEMISTRY

275898 In a cell that utilizes the reaction
$\mathbf{Z n}(\mathrm{s})+2 \mathrm{H}^{+}(\mathrm{aq}) \longrightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})$
addition of $\mathrm{H}_{2} \mathrm{SO}_{4}$ to cathode compartment will.

1 lower the $\mathrm{E}$ and shift equilibrium to the left
2 lower the $\mathrm{E}$ and shift the equilibrium to the right
3 increase the $\mathrm{E}$ and shift the equilibrium to the right
4 increase the $\mathrm{E}$ and shift the equilibrium to the left.
ELECTROCHEMISTRY

275900 $\mathrm{Zn}(\mathrm{s})+\mathrm{Cl}_{2}(1 \mathrm{~atm}) \rightarrow \mathrm{Zn}^{2+}+2 \mathrm{Cl}^{-} ; \mathrm{E}^{\circ}=2.0 \mathrm{~V}$.
To increase the e.m.f. of the above cell

1 $\left[\mathrm{Zn}^{2+}\right]$ should be increased
2 $\left[\mathrm{Zn}^{2+}\right]$ should be decreased
3 $\left[\mathrm{Cl}^{-}\right]$should be increased
4 partial pressure of $\mathrm{Cl}_{2}$ should be decreased.
ELECTROCHEMISTRY

275901 The reduction potential of an electrode can be increased by

1 Increasing the area of electrode
2 Decreasing the temperature
3 Increasing the temperature
4 Decreasing the concentration of metal ions.
ELECTROCHEMISTRY

275892 The emf of a galvanic cell constituted with the electrodes $\mathrm{Zn}^{2+} \mid \mathrm{Zn}(-0.76 \mathrm{~V})$ and $\mathrm{Fe}^{2+} \mid \mathrm{Fe}(-0.41$ $\mathrm{V})$ is

1 $-0.35 \mathrm{~V}$
2 $+1.17 \mathrm{~V}$
3 $+0.35 \mathrm{~V}$
4 $-1.17 \mathrm{~V}$
ELECTROCHEMISTRY

275895 Given that the standard reduction potentials for $\mathrm{M}^{+} / \mathrm{M}$ and $\mathrm{N}^{+} / \mathrm{N}$ electrodes at $298 \mathrm{~K}$ are 0.52 $\mathrm{V}$ and $0.25 \mathrm{~V}$ respectively. Which of the following is correct in respect of the following electrochemical cell?
$\mathbf{M}\left \vert\mathbf{M}^{+} \ \vert \mathbf{N}^{+}\right \vert \mathbf{N}$

1 The overall cell reaction is a spontaneous reaction
2 The standard EMF of the cell is $-0.27 \mathrm{~V}$
3 The standard EMF of the cell is $0.77 \mathrm{~V}$
4 The standard EMF of the cell is $-0.77 \mathrm{~V}$
5 The standard EMF of the cell is $0.27 \mathrm{~V}$
ELECTROCHEMISTRY

275898 In a cell that utilizes the reaction
$\mathbf{Z n}(\mathrm{s})+2 \mathrm{H}^{+}(\mathrm{aq}) \longrightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})$
addition of $\mathrm{H}_{2} \mathrm{SO}_{4}$ to cathode compartment will.

1 lower the $\mathrm{E}$ and shift equilibrium to the left
2 lower the $\mathrm{E}$ and shift the equilibrium to the right
3 increase the $\mathrm{E}$ and shift the equilibrium to the right
4 increase the $\mathrm{E}$ and shift the equilibrium to the left.
ELECTROCHEMISTRY

275900 $\mathrm{Zn}(\mathrm{s})+\mathrm{Cl}_{2}(1 \mathrm{~atm}) \rightarrow \mathrm{Zn}^{2+}+2 \mathrm{Cl}^{-} ; \mathrm{E}^{\circ}=2.0 \mathrm{~V}$.
To increase the e.m.f. of the above cell

1 $\left[\mathrm{Zn}^{2+}\right]$ should be increased
2 $\left[\mathrm{Zn}^{2+}\right]$ should be decreased
3 $\left[\mathrm{Cl}^{-}\right]$should be increased
4 partial pressure of $\mathrm{Cl}_{2}$ should be decreased.
ELECTROCHEMISTRY

275901 The reduction potential of an electrode can be increased by

1 Increasing the area of electrode
2 Decreasing the temperature
3 Increasing the temperature
4 Decreasing the concentration of metal ions.
ELECTROCHEMISTRY

275892 The emf of a galvanic cell constituted with the electrodes $\mathrm{Zn}^{2+} \mid \mathrm{Zn}(-0.76 \mathrm{~V})$ and $\mathrm{Fe}^{2+} \mid \mathrm{Fe}(-0.41$ $\mathrm{V})$ is

1 $-0.35 \mathrm{~V}$
2 $+1.17 \mathrm{~V}$
3 $+0.35 \mathrm{~V}$
4 $-1.17 \mathrm{~V}$
ELECTROCHEMISTRY

275895 Given that the standard reduction potentials for $\mathrm{M}^{+} / \mathrm{M}$ and $\mathrm{N}^{+} / \mathrm{N}$ electrodes at $298 \mathrm{~K}$ are 0.52 $\mathrm{V}$ and $0.25 \mathrm{~V}$ respectively. Which of the following is correct in respect of the following electrochemical cell?
$\mathbf{M}\left \vert\mathbf{M}^{+} \ \vert \mathbf{N}^{+}\right \vert \mathbf{N}$

1 The overall cell reaction is a spontaneous reaction
2 The standard EMF of the cell is $-0.27 \mathrm{~V}$
3 The standard EMF of the cell is $0.77 \mathrm{~V}$
4 The standard EMF of the cell is $-0.77 \mathrm{~V}$
5 The standard EMF of the cell is $0.27 \mathrm{~V}$
ELECTROCHEMISTRY

275898 In a cell that utilizes the reaction
$\mathbf{Z n}(\mathrm{s})+2 \mathrm{H}^{+}(\mathrm{aq}) \longrightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})$
addition of $\mathrm{H}_{2} \mathrm{SO}_{4}$ to cathode compartment will.

1 lower the $\mathrm{E}$ and shift equilibrium to the left
2 lower the $\mathrm{E}$ and shift the equilibrium to the right
3 increase the $\mathrm{E}$ and shift the equilibrium to the right
4 increase the $\mathrm{E}$ and shift the equilibrium to the left.
ELECTROCHEMISTRY

275900 $\mathrm{Zn}(\mathrm{s})+\mathrm{Cl}_{2}(1 \mathrm{~atm}) \rightarrow \mathrm{Zn}^{2+}+2 \mathrm{Cl}^{-} ; \mathrm{E}^{\circ}=2.0 \mathrm{~V}$.
To increase the e.m.f. of the above cell

1 $\left[\mathrm{Zn}^{2+}\right]$ should be increased
2 $\left[\mathrm{Zn}^{2+}\right]$ should be decreased
3 $\left[\mathrm{Cl}^{-}\right]$should be increased
4 partial pressure of $\mathrm{Cl}_{2}$ should be decreased.
ELECTROCHEMISTRY

275901 The reduction potential of an electrode can be increased by

1 Increasing the area of electrode
2 Decreasing the temperature
3 Increasing the temperature
4 Decreasing the concentration of metal ions.
ELECTROCHEMISTRY

275892 The emf of a galvanic cell constituted with the electrodes $\mathrm{Zn}^{2+} \mid \mathrm{Zn}(-0.76 \mathrm{~V})$ and $\mathrm{Fe}^{2+} \mid \mathrm{Fe}(-0.41$ $\mathrm{V})$ is

1 $-0.35 \mathrm{~V}$
2 $+1.17 \mathrm{~V}$
3 $+0.35 \mathrm{~V}$
4 $-1.17 \mathrm{~V}$
ELECTROCHEMISTRY

275895 Given that the standard reduction potentials for $\mathrm{M}^{+} / \mathrm{M}$ and $\mathrm{N}^{+} / \mathrm{N}$ electrodes at $298 \mathrm{~K}$ are 0.52 $\mathrm{V}$ and $0.25 \mathrm{~V}$ respectively. Which of the following is correct in respect of the following electrochemical cell?
$\mathbf{M}\left \vert\mathbf{M}^{+} \ \vert \mathbf{N}^{+}\right \vert \mathbf{N}$

1 The overall cell reaction is a spontaneous reaction
2 The standard EMF of the cell is $-0.27 \mathrm{~V}$
3 The standard EMF of the cell is $0.77 \mathrm{~V}$
4 The standard EMF of the cell is $-0.77 \mathrm{~V}$
5 The standard EMF of the cell is $0.27 \mathrm{~V}$
ELECTROCHEMISTRY

275898 In a cell that utilizes the reaction
$\mathbf{Z n}(\mathrm{s})+2 \mathrm{H}^{+}(\mathrm{aq}) \longrightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})$
addition of $\mathrm{H}_{2} \mathrm{SO}_{4}$ to cathode compartment will.

1 lower the $\mathrm{E}$ and shift equilibrium to the left
2 lower the $\mathrm{E}$ and shift the equilibrium to the right
3 increase the $\mathrm{E}$ and shift the equilibrium to the right
4 increase the $\mathrm{E}$ and shift the equilibrium to the left.
ELECTROCHEMISTRY

275900 $\mathrm{Zn}(\mathrm{s})+\mathrm{Cl}_{2}(1 \mathrm{~atm}) \rightarrow \mathrm{Zn}^{2+}+2 \mathrm{Cl}^{-} ; \mathrm{E}^{\circ}=2.0 \mathrm{~V}$.
To increase the e.m.f. of the above cell

1 $\left[\mathrm{Zn}^{2+}\right]$ should be increased
2 $\left[\mathrm{Zn}^{2+}\right]$ should be decreased
3 $\left[\mathrm{Cl}^{-}\right]$should be increased
4 partial pressure of $\mathrm{Cl}_{2}$ should be decreased.
ELECTROCHEMISTRY

275901 The reduction potential of an electrode can be increased by

1 Increasing the area of electrode
2 Decreasing the temperature
3 Increasing the temperature
4 Decreasing the concentration of metal ions.
ELECTROCHEMISTRY

275892 The emf of a galvanic cell constituted with the electrodes $\mathrm{Zn}^{2+} \mid \mathrm{Zn}(-0.76 \mathrm{~V})$ and $\mathrm{Fe}^{2+} \mid \mathrm{Fe}(-0.41$ $\mathrm{V})$ is

1 $-0.35 \mathrm{~V}$
2 $+1.17 \mathrm{~V}$
3 $+0.35 \mathrm{~V}$
4 $-1.17 \mathrm{~V}$
ELECTROCHEMISTRY

275895 Given that the standard reduction potentials for $\mathrm{M}^{+} / \mathrm{M}$ and $\mathrm{N}^{+} / \mathrm{N}$ electrodes at $298 \mathrm{~K}$ are 0.52 $\mathrm{V}$ and $0.25 \mathrm{~V}$ respectively. Which of the following is correct in respect of the following electrochemical cell?
$\mathbf{M}\left \vert\mathbf{M}^{+} \ \vert \mathbf{N}^{+}\right \vert \mathbf{N}$

1 The overall cell reaction is a spontaneous reaction
2 The standard EMF of the cell is $-0.27 \mathrm{~V}$
3 The standard EMF of the cell is $0.77 \mathrm{~V}$
4 The standard EMF of the cell is $-0.77 \mathrm{~V}$
5 The standard EMF of the cell is $0.27 \mathrm{~V}$
ELECTROCHEMISTRY

275898 In a cell that utilizes the reaction
$\mathbf{Z n}(\mathrm{s})+2 \mathrm{H}^{+}(\mathrm{aq}) \longrightarrow \mathrm{Zn}^{2+}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})$
addition of $\mathrm{H}_{2} \mathrm{SO}_{4}$ to cathode compartment will.

1 lower the $\mathrm{E}$ and shift equilibrium to the left
2 lower the $\mathrm{E}$ and shift the equilibrium to the right
3 increase the $\mathrm{E}$ and shift the equilibrium to the right
4 increase the $\mathrm{E}$ and shift the equilibrium to the left.
ELECTROCHEMISTRY

275900 $\mathrm{Zn}(\mathrm{s})+\mathrm{Cl}_{2}(1 \mathrm{~atm}) \rightarrow \mathrm{Zn}^{2+}+2 \mathrm{Cl}^{-} ; \mathrm{E}^{\circ}=2.0 \mathrm{~V}$.
To increase the e.m.f. of the above cell

1 $\left[\mathrm{Zn}^{2+}\right]$ should be increased
2 $\left[\mathrm{Zn}^{2+}\right]$ should be decreased
3 $\left[\mathrm{Cl}^{-}\right]$should be increased
4 partial pressure of $\mathrm{Cl}_{2}$ should be decreased.
ELECTROCHEMISTRY

275901 The reduction potential of an electrode can be increased by

1 Increasing the area of electrode
2 Decreasing the temperature
3 Increasing the temperature
4 Decreasing the concentration of metal ions.