02. Lowering of Vapour Pressure
SOLUTIONS

277321 The vapour pressure of pure $\mathrm{CHCl}_{3}$ and
$\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are 200 and $41.5 \mathrm{~atm}$ respectively. The weight of $\mathrm{CHCl}_{3}$ and $\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are respectively $11.9 \mathrm{~g}$ and $17 \mathrm{~g}$. The vapour pressure of solution will be?

1 80.5
2 79.5
3 94.3
4 105.5
SOLUTIONS

277322 At room temperature, a dilute solution of urea is prepared by dissolving $0.60 \mathrm{~g}$ of urea in $360 \mathrm{~g}$ of water. If the vapour pressure of pure water at this temperature is $35 \mathrm{~mm} \mathrm{Hg}$, lowering of vapour pressure will be (Molar mass of urea $=$ $60 \mathrm{~g} \mathrm{~mol}^{-1}$ )

1 $0.027 \mathrm{mmHg}$
2 $0.031 \mathrm{mmHg}$
3 $0.017 \mathrm{mmHg}$
4 $0.028 \mathrm{mmHg}$
SOLUTIONS

277323 Acetic acid dimerizes when dissolved in benzene. As a result boiling point of the solution rises by $0.36^{\circ} \mathrm{C}$, when $100 \mathrm{~g}$ of benzene is mixed with " $\mathrm{X}$ " $\mathrm{g}$ of acetic acid. In this solution, if experimentally measured molecular weight of acetic acid is $\mathbf{1 1 7 . 8}$ and molar elevation constant of benzene is $2.57 \mathrm{~K} \mathrm{kgmol}^{-1}$, what is the weight \% and degree of dissociation (in \%) of acetic acid in benzene?

1 1.62 and 98.3
2 0.81 and 98.3
3 0.5 and 8.6
4 1 and 98.3
5 1.4 and 99
SOLUTIONS

277324 Calculate Van't Hoff-factor for $0.2 \mathrm{~m}$ aqueous solution of $\mathrm{KCl}$ which freezes at $-0.680^{\circ} \mathrm{C}$.
$\left(K_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

1 3.72
2 1.83
3 6.8
4 1.86
SOLUTIONS

277321 The vapour pressure of pure $\mathrm{CHCl}_{3}$ and
$\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are 200 and $41.5 \mathrm{~atm}$ respectively. The weight of $\mathrm{CHCl}_{3}$ and $\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are respectively $11.9 \mathrm{~g}$ and $17 \mathrm{~g}$. The vapour pressure of solution will be?

1 80.5
2 79.5
3 94.3
4 105.5
SOLUTIONS

277322 At room temperature, a dilute solution of urea is prepared by dissolving $0.60 \mathrm{~g}$ of urea in $360 \mathrm{~g}$ of water. If the vapour pressure of pure water at this temperature is $35 \mathrm{~mm} \mathrm{Hg}$, lowering of vapour pressure will be (Molar mass of urea $=$ $60 \mathrm{~g} \mathrm{~mol}^{-1}$ )

1 $0.027 \mathrm{mmHg}$
2 $0.031 \mathrm{mmHg}$
3 $0.017 \mathrm{mmHg}$
4 $0.028 \mathrm{mmHg}$
SOLUTIONS

277323 Acetic acid dimerizes when dissolved in benzene. As a result boiling point of the solution rises by $0.36^{\circ} \mathrm{C}$, when $100 \mathrm{~g}$ of benzene is mixed with " $\mathrm{X}$ " $\mathrm{g}$ of acetic acid. In this solution, if experimentally measured molecular weight of acetic acid is $\mathbf{1 1 7 . 8}$ and molar elevation constant of benzene is $2.57 \mathrm{~K} \mathrm{kgmol}^{-1}$, what is the weight \% and degree of dissociation (in \%) of acetic acid in benzene?

1 1.62 and 98.3
2 0.81 and 98.3
3 0.5 and 8.6
4 1 and 98.3
5 1.4 and 99
SOLUTIONS

277324 Calculate Van't Hoff-factor for $0.2 \mathrm{~m}$ aqueous solution of $\mathrm{KCl}$ which freezes at $-0.680^{\circ} \mathrm{C}$.
$\left(K_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

1 3.72
2 1.83
3 6.8
4 1.86
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
SOLUTIONS

277321 The vapour pressure of pure $\mathrm{CHCl}_{3}$ and
$\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are 200 and $41.5 \mathrm{~atm}$ respectively. The weight of $\mathrm{CHCl}_{3}$ and $\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are respectively $11.9 \mathrm{~g}$ and $17 \mathrm{~g}$. The vapour pressure of solution will be?

1 80.5
2 79.5
3 94.3
4 105.5
SOLUTIONS

277322 At room temperature, a dilute solution of urea is prepared by dissolving $0.60 \mathrm{~g}$ of urea in $360 \mathrm{~g}$ of water. If the vapour pressure of pure water at this temperature is $35 \mathrm{~mm} \mathrm{Hg}$, lowering of vapour pressure will be (Molar mass of urea $=$ $60 \mathrm{~g} \mathrm{~mol}^{-1}$ )

1 $0.027 \mathrm{mmHg}$
2 $0.031 \mathrm{mmHg}$
3 $0.017 \mathrm{mmHg}$
4 $0.028 \mathrm{mmHg}$
SOLUTIONS

277323 Acetic acid dimerizes when dissolved in benzene. As a result boiling point of the solution rises by $0.36^{\circ} \mathrm{C}$, when $100 \mathrm{~g}$ of benzene is mixed with " $\mathrm{X}$ " $\mathrm{g}$ of acetic acid. In this solution, if experimentally measured molecular weight of acetic acid is $\mathbf{1 1 7 . 8}$ and molar elevation constant of benzene is $2.57 \mathrm{~K} \mathrm{kgmol}^{-1}$, what is the weight \% and degree of dissociation (in \%) of acetic acid in benzene?

1 1.62 and 98.3
2 0.81 and 98.3
3 0.5 and 8.6
4 1 and 98.3
5 1.4 and 99
SOLUTIONS

277324 Calculate Van't Hoff-factor for $0.2 \mathrm{~m}$ aqueous solution of $\mathrm{KCl}$ which freezes at $-0.680^{\circ} \mathrm{C}$.
$\left(K_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

1 3.72
2 1.83
3 6.8
4 1.86
SOLUTIONS

277321 The vapour pressure of pure $\mathrm{CHCl}_{3}$ and
$\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are 200 and $41.5 \mathrm{~atm}$ respectively. The weight of $\mathrm{CHCl}_{3}$ and $\mathrm{CH}_{2} \mathrm{Cl}_{2}$ are respectively $11.9 \mathrm{~g}$ and $17 \mathrm{~g}$. The vapour pressure of solution will be?

1 80.5
2 79.5
3 94.3
4 105.5
SOLUTIONS

277322 At room temperature, a dilute solution of urea is prepared by dissolving $0.60 \mathrm{~g}$ of urea in $360 \mathrm{~g}$ of water. If the vapour pressure of pure water at this temperature is $35 \mathrm{~mm} \mathrm{Hg}$, lowering of vapour pressure will be (Molar mass of urea $=$ $60 \mathrm{~g} \mathrm{~mol}^{-1}$ )

1 $0.027 \mathrm{mmHg}$
2 $0.031 \mathrm{mmHg}$
3 $0.017 \mathrm{mmHg}$
4 $0.028 \mathrm{mmHg}$
SOLUTIONS

277323 Acetic acid dimerizes when dissolved in benzene. As a result boiling point of the solution rises by $0.36^{\circ} \mathrm{C}$, when $100 \mathrm{~g}$ of benzene is mixed with " $\mathrm{X}$ " $\mathrm{g}$ of acetic acid. In this solution, if experimentally measured molecular weight of acetic acid is $\mathbf{1 1 7 . 8}$ and molar elevation constant of benzene is $2.57 \mathrm{~K} \mathrm{kgmol}^{-1}$, what is the weight \% and degree of dissociation (in \%) of acetic acid in benzene?

1 1.62 and 98.3
2 0.81 and 98.3
3 0.5 and 8.6
4 1 and 98.3
5 1.4 and 99
SOLUTIONS

277324 Calculate Van't Hoff-factor for $0.2 \mathrm{~m}$ aqueous solution of $\mathrm{KCl}$ which freezes at $-0.680^{\circ} \mathrm{C}$.
$\left(K_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

1 3.72
2 1.83
3 6.8
4 1.86