Explanation:
: Sodium and Cesium chlorides are solid with high melting and boiling points because of the large amount of heat which is needed to break the strong ionic attractions. Copper chlorides are liquids and low melting points solids. Boiling Points $\propto \frac{1}{\text { Covalent character }}$
Since, the anion that is chlorides is the same in all four compounds, compare the covalent character based on the polarizing power of the cations
In $\mathrm{NaCl}$ has +1 charge on catian
$\mathrm{CuCl}$ has +1 charge on catian
$\mathrm{CuCl}_2$ has +2 charge on catian
$\mathrm{C}_5 \mathrm{Cl}$ has +1 charge on catian
Hence, the covalent character is maximum in $\mathrm{CuCl}_2$ So, $\mathrm{Cucl}_2$ has the minimum boiling point.