03. Buffer Solution
Ionic Equilibrium

229720 The Henderson's equation for a basic buffer is

1 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Salt }]}{[\text { Base }]}$
2 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}-\log \frac{[\text { Salt }]}{[\text { Base }]}$
3 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Base }]}{[\text { Salt }]}$
4 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\frac{[\text { Salt }]}{[\text { Base }]}$
Ionic Equilibrium

229721 Which of the following is a buffer solution?

1 $\mathrm{K}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{SO}_4$
2 $\mathrm{NaOH}+\mathrm{Na}_2 \mathrm{SO}_4$
3 $\mathrm{NaOH}+\mathrm{CH}_3 \mathrm{COONa}$
4 $\mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}$
Ionic Equilibrium

229712 Which of the following solutions cannot act as a buffer?

1 $\mathrm{NaH}_2 \mathrm{PO}_4+\mathrm{H}_3 \mathrm{PO}_4$
2 $\mathrm{CH}_3 \mathrm{COOH}+\mathrm{CH}_3 \mathrm{COONa}$
3 $\mathrm{HCl}+\mathrm{NH}_4 \mathrm{Cl}$
4 $\mathrm{H}_3 \mathrm{PO}_4+\mathrm{Na}_2 \mathrm{HPO}_4$
Ionic Equilibrium

229719 Which among the following pairs constitute a buffer?

1 $\mathrm{LiOH} \& \mathrm{LiCl}$
2 $\mathrm{HNO}_3 \& \mathrm{NH}_4 \mathrm{NO}_3$
3 $\mathrm{HNO}_2 \& \mathrm{NaNO}_2$
4 $\mathrm{HBr} \& \mathrm{KBr}$
Ionic Equilibrium

229729 Which one of the following statements is not correct?

1 The $\mathrm{pH}$ of $1.0 \times 10^{-8} \mathrm{M} \mathrm{HCl}$ is less than 7
2 The ionic product of water at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-14} \mathrm{~mol}^2 \mathrm{~L}^{-2}$
3 $\mathrm{Cl}^{-}$is a Lewis acid
4 Bronsted Lowry theory cannot explain the acidic character of $\mathrm{AlCl}_3$
Ionic Equilibrium

229720 The Henderson's equation for a basic buffer is

1 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Salt }]}{[\text { Base }]}$
2 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}-\log \frac{[\text { Salt }]}{[\text { Base }]}$
3 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Base }]}{[\text { Salt }]}$
4 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\frac{[\text { Salt }]}{[\text { Base }]}$
Ionic Equilibrium

229721 Which of the following is a buffer solution?

1 $\mathrm{K}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{SO}_4$
2 $\mathrm{NaOH}+\mathrm{Na}_2 \mathrm{SO}_4$
3 $\mathrm{NaOH}+\mathrm{CH}_3 \mathrm{COONa}$
4 $\mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}$
Ionic Equilibrium

229712 Which of the following solutions cannot act as a buffer?

1 $\mathrm{NaH}_2 \mathrm{PO}_4+\mathrm{H}_3 \mathrm{PO}_4$
2 $\mathrm{CH}_3 \mathrm{COOH}+\mathrm{CH}_3 \mathrm{COONa}$
3 $\mathrm{HCl}+\mathrm{NH}_4 \mathrm{Cl}$
4 $\mathrm{H}_3 \mathrm{PO}_4+\mathrm{Na}_2 \mathrm{HPO}_4$
Ionic Equilibrium

229719 Which among the following pairs constitute a buffer?

1 $\mathrm{LiOH} \& \mathrm{LiCl}$
2 $\mathrm{HNO}_3 \& \mathrm{NH}_4 \mathrm{NO}_3$
3 $\mathrm{HNO}_2 \& \mathrm{NaNO}_2$
4 $\mathrm{HBr} \& \mathrm{KBr}$
Ionic Equilibrium

229729 Which one of the following statements is not correct?

1 The $\mathrm{pH}$ of $1.0 \times 10^{-8} \mathrm{M} \mathrm{HCl}$ is less than 7
2 The ionic product of water at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-14} \mathrm{~mol}^2 \mathrm{~L}^{-2}$
3 $\mathrm{Cl}^{-}$is a Lewis acid
4 Bronsted Lowry theory cannot explain the acidic character of $\mathrm{AlCl}_3$
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Ionic Equilibrium

229720 The Henderson's equation for a basic buffer is

1 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Salt }]}{[\text { Base }]}$
2 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}-\log \frac{[\text { Salt }]}{[\text { Base }]}$
3 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Base }]}{[\text { Salt }]}$
4 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\frac{[\text { Salt }]}{[\text { Base }]}$
Ionic Equilibrium

229721 Which of the following is a buffer solution?

1 $\mathrm{K}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{SO}_4$
2 $\mathrm{NaOH}+\mathrm{Na}_2 \mathrm{SO}_4$
3 $\mathrm{NaOH}+\mathrm{CH}_3 \mathrm{COONa}$
4 $\mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}$
Ionic Equilibrium

229712 Which of the following solutions cannot act as a buffer?

1 $\mathrm{NaH}_2 \mathrm{PO}_4+\mathrm{H}_3 \mathrm{PO}_4$
2 $\mathrm{CH}_3 \mathrm{COOH}+\mathrm{CH}_3 \mathrm{COONa}$
3 $\mathrm{HCl}+\mathrm{NH}_4 \mathrm{Cl}$
4 $\mathrm{H}_3 \mathrm{PO}_4+\mathrm{Na}_2 \mathrm{HPO}_4$
Ionic Equilibrium

229719 Which among the following pairs constitute a buffer?

1 $\mathrm{LiOH} \& \mathrm{LiCl}$
2 $\mathrm{HNO}_3 \& \mathrm{NH}_4 \mathrm{NO}_3$
3 $\mathrm{HNO}_2 \& \mathrm{NaNO}_2$
4 $\mathrm{HBr} \& \mathrm{KBr}$
Ionic Equilibrium

229729 Which one of the following statements is not correct?

1 The $\mathrm{pH}$ of $1.0 \times 10^{-8} \mathrm{M} \mathrm{HCl}$ is less than 7
2 The ionic product of water at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-14} \mathrm{~mol}^2 \mathrm{~L}^{-2}$
3 $\mathrm{Cl}^{-}$is a Lewis acid
4 Bronsted Lowry theory cannot explain the acidic character of $\mathrm{AlCl}_3$
Ionic Equilibrium

229720 The Henderson's equation for a basic buffer is

1 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Salt }]}{[\text { Base }]}$
2 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}-\log \frac{[\text { Salt }]}{[\text { Base }]}$
3 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Base }]}{[\text { Salt }]}$
4 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\frac{[\text { Salt }]}{[\text { Base }]}$
Ionic Equilibrium

229721 Which of the following is a buffer solution?

1 $\mathrm{K}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{SO}_4$
2 $\mathrm{NaOH}+\mathrm{Na}_2 \mathrm{SO}_4$
3 $\mathrm{NaOH}+\mathrm{CH}_3 \mathrm{COONa}$
4 $\mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}$
Ionic Equilibrium

229712 Which of the following solutions cannot act as a buffer?

1 $\mathrm{NaH}_2 \mathrm{PO}_4+\mathrm{H}_3 \mathrm{PO}_4$
2 $\mathrm{CH}_3 \mathrm{COOH}+\mathrm{CH}_3 \mathrm{COONa}$
3 $\mathrm{HCl}+\mathrm{NH}_4 \mathrm{Cl}$
4 $\mathrm{H}_3 \mathrm{PO}_4+\mathrm{Na}_2 \mathrm{HPO}_4$
Ionic Equilibrium

229719 Which among the following pairs constitute a buffer?

1 $\mathrm{LiOH} \& \mathrm{LiCl}$
2 $\mathrm{HNO}_3 \& \mathrm{NH}_4 \mathrm{NO}_3$
3 $\mathrm{HNO}_2 \& \mathrm{NaNO}_2$
4 $\mathrm{HBr} \& \mathrm{KBr}$
Ionic Equilibrium

229729 Which one of the following statements is not correct?

1 The $\mathrm{pH}$ of $1.0 \times 10^{-8} \mathrm{M} \mathrm{HCl}$ is less than 7
2 The ionic product of water at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-14} \mathrm{~mol}^2 \mathrm{~L}^{-2}$
3 $\mathrm{Cl}^{-}$is a Lewis acid
4 Bronsted Lowry theory cannot explain the acidic character of $\mathrm{AlCl}_3$
Ionic Equilibrium

229720 The Henderson's equation for a basic buffer is

1 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Salt }]}{[\text { Base }]}$
2 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}-\log \frac{[\text { Salt }]}{[\text { Base }]}$
3 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\log \frac{[\text { Base }]}{[\text { Salt }]}$
4 $\mathrm{pOH}=\mathrm{pK}_{\mathrm{b}}+\frac{[\text { Salt }]}{[\text { Base }]}$
Ionic Equilibrium

229721 Which of the following is a buffer solution?

1 $\mathrm{K}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{SO}_4$
2 $\mathrm{NaOH}+\mathrm{Na}_2 \mathrm{SO}_4$
3 $\mathrm{NaOH}+\mathrm{CH}_3 \mathrm{COONa}$
4 $\mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}$
Ionic Equilibrium

229712 Which of the following solutions cannot act as a buffer?

1 $\mathrm{NaH}_2 \mathrm{PO}_4+\mathrm{H}_3 \mathrm{PO}_4$
2 $\mathrm{CH}_3 \mathrm{COOH}+\mathrm{CH}_3 \mathrm{COONa}$
3 $\mathrm{HCl}+\mathrm{NH}_4 \mathrm{Cl}$
4 $\mathrm{H}_3 \mathrm{PO}_4+\mathrm{Na}_2 \mathrm{HPO}_4$
Ionic Equilibrium

229719 Which among the following pairs constitute a buffer?

1 $\mathrm{LiOH} \& \mathrm{LiCl}$
2 $\mathrm{HNO}_3 \& \mathrm{NH}_4 \mathrm{NO}_3$
3 $\mathrm{HNO}_2 \& \mathrm{NaNO}_2$
4 $\mathrm{HBr} \& \mathrm{KBr}$
Ionic Equilibrium

229729 Which one of the following statements is not correct?

1 The $\mathrm{pH}$ of $1.0 \times 10^{-8} \mathrm{M} \mathrm{HCl}$ is less than 7
2 The ionic product of water at $25^{\circ} \mathrm{C}$ is $1.0 \times 10^{-14} \mathrm{~mol}^2 \mathrm{~L}^{-2}$
3 $\mathrm{Cl}^{-}$is a Lewis acid
4 Bronsted Lowry theory cannot explain the acidic character of $\mathrm{AlCl}_3$