05. Le-Chatelier Principle and It's Application
Chemical Equilibrium

229163 The chemical reaction of a gas phase is given below.
$\mathbf{2 A}(\mathrm{g})+\mathbf{B}(\mathrm{g}) \rightleftharpoons \mathbf{C}(\mathrm{g})+\mathrm{D}(\mathrm{g})$
Which one of the following changes will affect the value of $K_{c}$ ?

1 Addition of inert gas
2 Increasing in temperature
3 Addition of reactants
4 Addition of catalyst
Chemical Equilibrium

229165 Which one of the following is correct?

1 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ is independent of temperature
2 The value of $K_{c}$ is independent of initial concentrations of reactants and products
3 At equilibrium, the rate of the forward reaction is twice the rate of the backward reaction
4 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ for the reaction
$\mathrm{Ni}(\mathrm{s})+4 \mathrm{CO}(\mathrm{g}) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(\mathrm{~g}) \text { is, } \frac{\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]}{[\mathrm{CO}]}$
Chemical Equilibrium

229169 Consider the following reaction $\mathrm{CaCO}_{3}(\mathrm{~s})$
$\mathrm{CaO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})$ in closed container at equilibrium. What would be the effect of addition of $\mathrm{CaCO}_{3}$ on the equilibrium concentration of $\mathrm{CO}_{2}$ ?

1 Increases
2 Decreases
3 Data is insufficient
4 Remains unaffected
Chemical Equilibrium

229171 In a reaction, $A+B \rightleftharpoons C+D, 40 \%$ of $B$ has reacted at equilibrium, when 1 mole of $A$ was heated with 1 mole of $B$ in a $10 \mathrm{~L}$ closed vessel. The value of $K_{c}$ is

1 0.44
2 0.18
3 0.22
4 0.36
Chemical Equilibrium

229180 The value of $\Delta H$ for the reaction
$\mathbf{X}_{2}(\mathrm{~g})+\mathbf{4} \mathbf{Y}_{2}(\mathrm{~g}) \rightleftharpoons \mathbf{2} \mathbf{X Y}_{4}(\mathrm{~g})$ is less than zero formation of $\mathrm{XY}_{4}(\mathrm{~g})$ will favoured at

1 high temperature and high pressure
2 low pressure and low temperature
3 high temperature and low pressure
4 high pressure and low temperature
Chemical Equilibrium

229163 The chemical reaction of a gas phase is given below.
$\mathbf{2 A}(\mathrm{g})+\mathbf{B}(\mathrm{g}) \rightleftharpoons \mathbf{C}(\mathrm{g})+\mathrm{D}(\mathrm{g})$
Which one of the following changes will affect the value of $K_{c}$ ?

1 Addition of inert gas
2 Increasing in temperature
3 Addition of reactants
4 Addition of catalyst
Chemical Equilibrium

229165 Which one of the following is correct?

1 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ is independent of temperature
2 The value of $K_{c}$ is independent of initial concentrations of reactants and products
3 At equilibrium, the rate of the forward reaction is twice the rate of the backward reaction
4 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ for the reaction
$\mathrm{Ni}(\mathrm{s})+4 \mathrm{CO}(\mathrm{g}) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(\mathrm{~g}) \text { is, } \frac{\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]}{[\mathrm{CO}]}$
Chemical Equilibrium

229169 Consider the following reaction $\mathrm{CaCO}_{3}(\mathrm{~s})$
$\mathrm{CaO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})$ in closed container at equilibrium. What would be the effect of addition of $\mathrm{CaCO}_{3}$ on the equilibrium concentration of $\mathrm{CO}_{2}$ ?

1 Increases
2 Decreases
3 Data is insufficient
4 Remains unaffected
Chemical Equilibrium

229171 In a reaction, $A+B \rightleftharpoons C+D, 40 \%$ of $B$ has reacted at equilibrium, when 1 mole of $A$ was heated with 1 mole of $B$ in a $10 \mathrm{~L}$ closed vessel. The value of $K_{c}$ is

1 0.44
2 0.18
3 0.22
4 0.36
Chemical Equilibrium

229180 The value of $\Delta H$ for the reaction
$\mathbf{X}_{2}(\mathrm{~g})+\mathbf{4} \mathbf{Y}_{2}(\mathrm{~g}) \rightleftharpoons \mathbf{2} \mathbf{X Y}_{4}(\mathrm{~g})$ is less than zero formation of $\mathrm{XY}_{4}(\mathrm{~g})$ will favoured at

1 high temperature and high pressure
2 low pressure and low temperature
3 high temperature and low pressure
4 high pressure and low temperature
Chemical Equilibrium

229163 The chemical reaction of a gas phase is given below.
$\mathbf{2 A}(\mathrm{g})+\mathbf{B}(\mathrm{g}) \rightleftharpoons \mathbf{C}(\mathrm{g})+\mathrm{D}(\mathrm{g})$
Which one of the following changes will affect the value of $K_{c}$ ?

1 Addition of inert gas
2 Increasing in temperature
3 Addition of reactants
4 Addition of catalyst
Chemical Equilibrium

229165 Which one of the following is correct?

1 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ is independent of temperature
2 The value of $K_{c}$ is independent of initial concentrations of reactants and products
3 At equilibrium, the rate of the forward reaction is twice the rate of the backward reaction
4 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ for the reaction
$\mathrm{Ni}(\mathrm{s})+4 \mathrm{CO}(\mathrm{g}) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(\mathrm{~g}) \text { is, } \frac{\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]}{[\mathrm{CO}]}$
Chemical Equilibrium

229169 Consider the following reaction $\mathrm{CaCO}_{3}(\mathrm{~s})$
$\mathrm{CaO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})$ in closed container at equilibrium. What would be the effect of addition of $\mathrm{CaCO}_{3}$ on the equilibrium concentration of $\mathrm{CO}_{2}$ ?

1 Increases
2 Decreases
3 Data is insufficient
4 Remains unaffected
Chemical Equilibrium

229171 In a reaction, $A+B \rightleftharpoons C+D, 40 \%$ of $B$ has reacted at equilibrium, when 1 mole of $A$ was heated with 1 mole of $B$ in a $10 \mathrm{~L}$ closed vessel. The value of $K_{c}$ is

1 0.44
2 0.18
3 0.22
4 0.36
Chemical Equilibrium

229180 The value of $\Delta H$ for the reaction
$\mathbf{X}_{2}(\mathrm{~g})+\mathbf{4} \mathbf{Y}_{2}(\mathrm{~g}) \rightleftharpoons \mathbf{2} \mathbf{X Y}_{4}(\mathrm{~g})$ is less than zero formation of $\mathrm{XY}_{4}(\mathrm{~g})$ will favoured at

1 high temperature and high pressure
2 low pressure and low temperature
3 high temperature and low pressure
4 high pressure and low temperature
Chemical Equilibrium

229163 The chemical reaction of a gas phase is given below.
$\mathbf{2 A}(\mathrm{g})+\mathbf{B}(\mathrm{g}) \rightleftharpoons \mathbf{C}(\mathrm{g})+\mathrm{D}(\mathrm{g})$
Which one of the following changes will affect the value of $K_{c}$ ?

1 Addition of inert gas
2 Increasing in temperature
3 Addition of reactants
4 Addition of catalyst
Chemical Equilibrium

229165 Which one of the following is correct?

1 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ is independent of temperature
2 The value of $K_{c}$ is independent of initial concentrations of reactants and products
3 At equilibrium, the rate of the forward reaction is twice the rate of the backward reaction
4 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ for the reaction
$\mathrm{Ni}(\mathrm{s})+4 \mathrm{CO}(\mathrm{g}) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(\mathrm{~g}) \text { is, } \frac{\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]}{[\mathrm{CO}]}$
Chemical Equilibrium

229169 Consider the following reaction $\mathrm{CaCO}_{3}(\mathrm{~s})$
$\mathrm{CaO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})$ in closed container at equilibrium. What would be the effect of addition of $\mathrm{CaCO}_{3}$ on the equilibrium concentration of $\mathrm{CO}_{2}$ ?

1 Increases
2 Decreases
3 Data is insufficient
4 Remains unaffected
Chemical Equilibrium

229171 In a reaction, $A+B \rightleftharpoons C+D, 40 \%$ of $B$ has reacted at equilibrium, when 1 mole of $A$ was heated with 1 mole of $B$ in a $10 \mathrm{~L}$ closed vessel. The value of $K_{c}$ is

1 0.44
2 0.18
3 0.22
4 0.36
Chemical Equilibrium

229180 The value of $\Delta H$ for the reaction
$\mathbf{X}_{2}(\mathrm{~g})+\mathbf{4} \mathbf{Y}_{2}(\mathrm{~g}) \rightleftharpoons \mathbf{2} \mathbf{X Y}_{4}(\mathrm{~g})$ is less than zero formation of $\mathrm{XY}_{4}(\mathrm{~g})$ will favoured at

1 high temperature and high pressure
2 low pressure and low temperature
3 high temperature and low pressure
4 high pressure and low temperature
Chemical Equilibrium

229163 The chemical reaction of a gas phase is given below.
$\mathbf{2 A}(\mathrm{g})+\mathbf{B}(\mathrm{g}) \rightleftharpoons \mathbf{C}(\mathrm{g})+\mathrm{D}(\mathrm{g})$
Which one of the following changes will affect the value of $K_{c}$ ?

1 Addition of inert gas
2 Increasing in temperature
3 Addition of reactants
4 Addition of catalyst
Chemical Equilibrium

229165 Which one of the following is correct?

1 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ is independent of temperature
2 The value of $K_{c}$ is independent of initial concentrations of reactants and products
3 At equilibrium, the rate of the forward reaction is twice the rate of the backward reaction
4 The equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ for the reaction
$\mathrm{Ni}(\mathrm{s})+4 \mathrm{CO}(\mathrm{g}) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(\mathrm{~g}) \text { is, } \frac{\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]}{[\mathrm{CO}]}$
Chemical Equilibrium

229169 Consider the following reaction $\mathrm{CaCO}_{3}(\mathrm{~s})$
$\mathrm{CaO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})$ in closed container at equilibrium. What would be the effect of addition of $\mathrm{CaCO}_{3}$ on the equilibrium concentration of $\mathrm{CO}_{2}$ ?

1 Increases
2 Decreases
3 Data is insufficient
4 Remains unaffected
Chemical Equilibrium

229171 In a reaction, $A+B \rightleftharpoons C+D, 40 \%$ of $B$ has reacted at equilibrium, when 1 mole of $A$ was heated with 1 mole of $B$ in a $10 \mathrm{~L}$ closed vessel. The value of $K_{c}$ is

1 0.44
2 0.18
3 0.22
4 0.36
Chemical Equilibrium

229180 The value of $\Delta H$ for the reaction
$\mathbf{X}_{2}(\mathrm{~g})+\mathbf{4} \mathbf{Y}_{2}(\mathrm{~g}) \rightleftharpoons \mathbf{2} \mathbf{X Y}_{4}(\mathrm{~g})$ is less than zero formation of $\mathrm{XY}_{4}(\mathrm{~g})$ will favoured at

1 high temperature and high pressure
2 low pressure and low temperature
3 high temperature and low pressure
4 high pressure and low temperature