Nomenclature, Preparation and Properties of Nitro Compounds
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CHXII13:AMINES

324321 The main product of reduction of nitrobenzene with lithium aluminiumhydride is

1 azoxybenzene
2 aniline
3 azobenzene
4 diazonium salts
CHXII13:AMINES

324322 Nitration of nitrobenzene at \(125^{\circ} \mathrm{C}\) with mixed acids gives

1 meta-dinitrobenzene
2 ortho-dinitrobenzene
3 para-dinitrobenzene
4 1, 3, 5-trinitrobenzene
CHXII13:AMINES

324323 For the electrophilic substitution reaction involving nitration, which of the following sequence regarding the rate of reaction is true?

1 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
2 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
3 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
4 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
CHXII13:AMINES

324324 Assertion :
Nitrobenzene is used as a solvent in Friedel - Craft's reaction
Reason :
Fusion of nitrobenzene with solid \(\mathrm{KOH}\) gives a low yield of a mixture of o- and \(\mathrm{p}\) - nitrophenols.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect.
AIIMS - 2008
CHXII13:AMINES

324325 Assertion :
Nitrating mixture used for carrying out nitration of benzene consists of conc.
\(\mathrm{HNO}_{3}+\) conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
Reason :
In presence of \(\mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{HNO}_{3}\) acts as a base and produces \(\mathrm{NO}_{2}{ }^{+}\)ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
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CHXII13:AMINES

324321 The main product of reduction of nitrobenzene with lithium aluminiumhydride is

1 azoxybenzene
2 aniline
3 azobenzene
4 diazonium salts
CHXII13:AMINES

324322 Nitration of nitrobenzene at \(125^{\circ} \mathrm{C}\) with mixed acids gives

1 meta-dinitrobenzene
2 ortho-dinitrobenzene
3 para-dinitrobenzene
4 1, 3, 5-trinitrobenzene
CHXII13:AMINES

324323 For the electrophilic substitution reaction involving nitration, which of the following sequence regarding the rate of reaction is true?

1 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
2 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
3 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
4 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
CHXII13:AMINES

324324 Assertion :
Nitrobenzene is used as a solvent in Friedel - Craft's reaction
Reason :
Fusion of nitrobenzene with solid \(\mathrm{KOH}\) gives a low yield of a mixture of o- and \(\mathrm{p}\) - nitrophenols.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect.
AIIMS - 2008
CHXII13:AMINES

324325 Assertion :
Nitrating mixture used for carrying out nitration of benzene consists of conc.
\(\mathrm{HNO}_{3}+\) conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
Reason :
In presence of \(\mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{HNO}_{3}\) acts as a base and produces \(\mathrm{NO}_{2}{ }^{+}\)ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
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CHXII13:AMINES

324321 The main product of reduction of nitrobenzene with lithium aluminiumhydride is

1 azoxybenzene
2 aniline
3 azobenzene
4 diazonium salts
CHXII13:AMINES

324322 Nitration of nitrobenzene at \(125^{\circ} \mathrm{C}\) with mixed acids gives

1 meta-dinitrobenzene
2 ortho-dinitrobenzene
3 para-dinitrobenzene
4 1, 3, 5-trinitrobenzene
CHXII13:AMINES

324323 For the electrophilic substitution reaction involving nitration, which of the following sequence regarding the rate of reaction is true?

1 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
2 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
3 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
4 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
CHXII13:AMINES

324324 Assertion :
Nitrobenzene is used as a solvent in Friedel - Craft's reaction
Reason :
Fusion of nitrobenzene with solid \(\mathrm{KOH}\) gives a low yield of a mixture of o- and \(\mathrm{p}\) - nitrophenols.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect.
AIIMS - 2008
CHXII13:AMINES

324325 Assertion :
Nitrating mixture used for carrying out nitration of benzene consists of conc.
\(\mathrm{HNO}_{3}+\) conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
Reason :
In presence of \(\mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{HNO}_{3}\) acts as a base and produces \(\mathrm{NO}_{2}{ }^{+}\)ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
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CHXII13:AMINES

324321 The main product of reduction of nitrobenzene with lithium aluminiumhydride is

1 azoxybenzene
2 aniline
3 azobenzene
4 diazonium salts
CHXII13:AMINES

324322 Nitration of nitrobenzene at \(125^{\circ} \mathrm{C}\) with mixed acids gives

1 meta-dinitrobenzene
2 ortho-dinitrobenzene
3 para-dinitrobenzene
4 1, 3, 5-trinitrobenzene
CHXII13:AMINES

324323 For the electrophilic substitution reaction involving nitration, which of the following sequence regarding the rate of reaction is true?

1 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
2 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
3 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
4 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
CHXII13:AMINES

324324 Assertion :
Nitrobenzene is used as a solvent in Friedel - Craft's reaction
Reason :
Fusion of nitrobenzene with solid \(\mathrm{KOH}\) gives a low yield of a mixture of o- and \(\mathrm{p}\) - nitrophenols.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect.
AIIMS - 2008
CHXII13:AMINES

324325 Assertion :
Nitrating mixture used for carrying out nitration of benzene consists of conc.
\(\mathrm{HNO}_{3}+\) conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
Reason :
In presence of \(\mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{HNO}_{3}\) acts as a base and produces \(\mathrm{NO}_{2}{ }^{+}\)ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Join With Us for More Updates
CHXII13:AMINES

324321 The main product of reduction of nitrobenzene with lithium aluminiumhydride is

1 azoxybenzene
2 aniline
3 azobenzene
4 diazonium salts
CHXII13:AMINES

324322 Nitration of nitrobenzene at \(125^{\circ} \mathrm{C}\) with mixed acids gives

1 meta-dinitrobenzene
2 ortho-dinitrobenzene
3 para-dinitrobenzene
4 1, 3, 5-trinitrobenzene
CHXII13:AMINES

324323 For the electrophilic substitution reaction involving nitration, which of the following sequence regarding the rate of reaction is true?

1 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
2 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
3 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}}=\mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
4 \(\mathrm{k}_{\mathrm{C}_{6} \mathrm{H}_{6}}>\mathrm{k}_{\mathrm{C}_{6} \mathrm{D}_{6}} < \mathrm{k}_{\mathrm{C}_{6} \mathrm{~T}_{6}}\)
CHXII13:AMINES

324324 Assertion :
Nitrobenzene is used as a solvent in Friedel - Craft's reaction
Reason :
Fusion of nitrobenzene with solid \(\mathrm{KOH}\) gives a low yield of a mixture of o- and \(\mathrm{p}\) - nitrophenols.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect.
AIIMS - 2008
CHXII13:AMINES

324325 Assertion :
Nitrating mixture used for carrying out nitration of benzene consists of conc.
\(\mathrm{HNO}_{3}+\) conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
Reason :
In presence of \(\mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{HNO}_{3}\) acts as a base and produces \(\mathrm{NO}_{2}{ }^{+}\)ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.