Diazonium Salts
CHXII13:AMINES

324265 During the preparation of arene diazonium salts, the excess of nitrous acid, if any, is destroyed by adding

1 aq. \(\mathrm{Na}_{2} \mathrm{CO}_{3}\)
2 aq. \(\mathrm{NaOH}\)
3 aq. \(\mathrm{NH}_{2} \mathrm{CONH}_{2}\)
4 aq. KI
CHXII13:AMINES

324266 \({\text{Ca}}{{\text{C}}_{\text{2}}}\xrightarrow[{{\text{ - Ca(OH}}{{\text{)}}_{\text{2}}}}]{{{\text{Hydrolysis}}}}{\text{A}}\xrightarrow[{{\text{Fe tube}}}]{{{\text{Red}}\,\,{\text{hot}}}}{\text{B}}\)
\(\xrightarrow[{{\text{50 - 6}}{{\text{0}}^{\text{o}}}\,{\text{C}}}]{{{\text{HN}}{{\text{O}}_{\text{3}}}{\text{ + }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}{\text{C}}\)
\(\xrightarrow{{{\text{Fe + HCl}}}}{\text{D}}\xrightarrow{{{\text{NaN}}{{\text{O}}_{\text{2}}}{\text{ + HCl,}}{{\text{O}}^{\text{o}}}{\text{C}}}}{\text{E}}\)
Then \(\mathrm{E}\) is

1 Aniline black
2 Benzene diazonium chloride
3 Phenyl osazone
4 Benzoyl chloride
CHXII13:AMINES

324267 The product ' \({\text{D}}\) ' in the following sequence of reactions is:
supporting img

1 2, 4, 6-Tribromofluorobenzene
2 Fluorobenzene
3 p-Bromofluorobenzene
4 Tribromobenzene
CHXII13:AMINES

324268 Complete reduction of benzene diazonium chloride with \(\mathrm{Zn} / \mathrm{HCl}\) gives :

1 Phenylhydrazine
2 Azobenzene
3 Aniline
4 Hydrazombenzene
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CHXII13:AMINES

324265 During the preparation of arene diazonium salts, the excess of nitrous acid, if any, is destroyed by adding

1 aq. \(\mathrm{Na}_{2} \mathrm{CO}_{3}\)
2 aq. \(\mathrm{NaOH}\)
3 aq. \(\mathrm{NH}_{2} \mathrm{CONH}_{2}\)
4 aq. KI
CHXII13:AMINES

324266 \({\text{Ca}}{{\text{C}}_{\text{2}}}\xrightarrow[{{\text{ - Ca(OH}}{{\text{)}}_{\text{2}}}}]{{{\text{Hydrolysis}}}}{\text{A}}\xrightarrow[{{\text{Fe tube}}}]{{{\text{Red}}\,\,{\text{hot}}}}{\text{B}}\)
\(\xrightarrow[{{\text{50 - 6}}{{\text{0}}^{\text{o}}}\,{\text{C}}}]{{{\text{HN}}{{\text{O}}_{\text{3}}}{\text{ + }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}{\text{C}}\)
\(\xrightarrow{{{\text{Fe + HCl}}}}{\text{D}}\xrightarrow{{{\text{NaN}}{{\text{O}}_{\text{2}}}{\text{ + HCl,}}{{\text{O}}^{\text{o}}}{\text{C}}}}{\text{E}}\)
Then \(\mathrm{E}\) is

1 Aniline black
2 Benzene diazonium chloride
3 Phenyl osazone
4 Benzoyl chloride
CHXII13:AMINES

324267 The product ' \({\text{D}}\) ' in the following sequence of reactions is:
supporting img

1 2, 4, 6-Tribromofluorobenzene
2 Fluorobenzene
3 p-Bromofluorobenzene
4 Tribromobenzene
CHXII13:AMINES

324268 Complete reduction of benzene diazonium chloride with \(\mathrm{Zn} / \mathrm{HCl}\) gives :

1 Phenylhydrazine
2 Azobenzene
3 Aniline
4 Hydrazombenzene
CHXII13:AMINES

324265 During the preparation of arene diazonium salts, the excess of nitrous acid, if any, is destroyed by adding

1 aq. \(\mathrm{Na}_{2} \mathrm{CO}_{3}\)
2 aq. \(\mathrm{NaOH}\)
3 aq. \(\mathrm{NH}_{2} \mathrm{CONH}_{2}\)
4 aq. KI
CHXII13:AMINES

324266 \({\text{Ca}}{{\text{C}}_{\text{2}}}\xrightarrow[{{\text{ - Ca(OH}}{{\text{)}}_{\text{2}}}}]{{{\text{Hydrolysis}}}}{\text{A}}\xrightarrow[{{\text{Fe tube}}}]{{{\text{Red}}\,\,{\text{hot}}}}{\text{B}}\)
\(\xrightarrow[{{\text{50 - 6}}{{\text{0}}^{\text{o}}}\,{\text{C}}}]{{{\text{HN}}{{\text{O}}_{\text{3}}}{\text{ + }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}{\text{C}}\)
\(\xrightarrow{{{\text{Fe + HCl}}}}{\text{D}}\xrightarrow{{{\text{NaN}}{{\text{O}}_{\text{2}}}{\text{ + HCl,}}{{\text{O}}^{\text{o}}}{\text{C}}}}{\text{E}}\)
Then \(\mathrm{E}\) is

1 Aniline black
2 Benzene diazonium chloride
3 Phenyl osazone
4 Benzoyl chloride
CHXII13:AMINES

324267 The product ' \({\text{D}}\) ' in the following sequence of reactions is:
supporting img

1 2, 4, 6-Tribromofluorobenzene
2 Fluorobenzene
3 p-Bromofluorobenzene
4 Tribromobenzene
CHXII13:AMINES

324268 Complete reduction of benzene diazonium chloride with \(\mathrm{Zn} / \mathrm{HCl}\) gives :

1 Phenylhydrazine
2 Azobenzene
3 Aniline
4 Hydrazombenzene
CHXII13:AMINES

324265 During the preparation of arene diazonium salts, the excess of nitrous acid, if any, is destroyed by adding

1 aq. \(\mathrm{Na}_{2} \mathrm{CO}_{3}\)
2 aq. \(\mathrm{NaOH}\)
3 aq. \(\mathrm{NH}_{2} \mathrm{CONH}_{2}\)
4 aq. KI
CHXII13:AMINES

324266 \({\text{Ca}}{{\text{C}}_{\text{2}}}\xrightarrow[{{\text{ - Ca(OH}}{{\text{)}}_{\text{2}}}}]{{{\text{Hydrolysis}}}}{\text{A}}\xrightarrow[{{\text{Fe tube}}}]{{{\text{Red}}\,\,{\text{hot}}}}{\text{B}}\)
\(\xrightarrow[{{\text{50 - 6}}{{\text{0}}^{\text{o}}}\,{\text{C}}}]{{{\text{HN}}{{\text{O}}_{\text{3}}}{\text{ + }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}{\text{C}}\)
\(\xrightarrow{{{\text{Fe + HCl}}}}{\text{D}}\xrightarrow{{{\text{NaN}}{{\text{O}}_{\text{2}}}{\text{ + HCl,}}{{\text{O}}^{\text{o}}}{\text{C}}}}{\text{E}}\)
Then \(\mathrm{E}\) is

1 Aniline black
2 Benzene diazonium chloride
3 Phenyl osazone
4 Benzoyl chloride
CHXII13:AMINES

324267 The product ' \({\text{D}}\) ' in the following sequence of reactions is:
supporting img

1 2, 4, 6-Tribromofluorobenzene
2 Fluorobenzene
3 p-Bromofluorobenzene
4 Tribromobenzene
CHXII13:AMINES

324268 Complete reduction of benzene diazonium chloride with \(\mathrm{Zn} / \mathrm{HCl}\) gives :

1 Phenylhydrazine
2 Azobenzene
3 Aniline
4 Hydrazombenzene