The structure of intermediate acetyl nitrene is \(\mathrm{CH}_{3}-\mathrm{CO}-\mathrm{N}\).
CHXII13:AMINES
324224
Which of the following alkene cannot be prepared by de-amination of \(\mathrm{n}-\mathrm{Bu}-\mathrm{NH}_{2}\) with \(\mathrm{NaNO}_{2} / \mathrm{HCl}\) ?
1 1-butene
2 cis-2-butene
3 trans-2-butene
4 Iso-butene
Explanation:
Formation of isobutene (branched alkene) does not take place by using n\(\mathrm{Bu} \mathrm{NH}_{2}\) (structure chain).
CHXII13:AMINES
324225
Which compound will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution
The compound which will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution is \(\mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}\). The reaction takes place as follows : \(\begin{aligned}& \mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}+\mathrm{NaHCO}_{3} \\& \rightarrow \mathrm{CH}_{3}-\mathrm{NH}_{2}+\mathrm{NaCl}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} \uparrow\end{aligned}\)
The structure of intermediate acetyl nitrene is \(\mathrm{CH}_{3}-\mathrm{CO}-\mathrm{N}\).
CHXII13:AMINES
324224
Which of the following alkene cannot be prepared by de-amination of \(\mathrm{n}-\mathrm{Bu}-\mathrm{NH}_{2}\) with \(\mathrm{NaNO}_{2} / \mathrm{HCl}\) ?
1 1-butene
2 cis-2-butene
3 trans-2-butene
4 Iso-butene
Explanation:
Formation of isobutene (branched alkene) does not take place by using n\(\mathrm{Bu} \mathrm{NH}_{2}\) (structure chain).
CHXII13:AMINES
324225
Which compound will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution
The compound which will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution is \(\mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}\). The reaction takes place as follows : \(\begin{aligned}& \mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}+\mathrm{NaHCO}_{3} \\& \rightarrow \mathrm{CH}_{3}-\mathrm{NH}_{2}+\mathrm{NaCl}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} \uparrow\end{aligned}\)
The structure of intermediate acetyl nitrene is \(\mathrm{CH}_{3}-\mathrm{CO}-\mathrm{N}\).
CHXII13:AMINES
324224
Which of the following alkene cannot be prepared by de-amination of \(\mathrm{n}-\mathrm{Bu}-\mathrm{NH}_{2}\) with \(\mathrm{NaNO}_{2} / \mathrm{HCl}\) ?
1 1-butene
2 cis-2-butene
3 trans-2-butene
4 Iso-butene
Explanation:
Formation of isobutene (branched alkene) does not take place by using n\(\mathrm{Bu} \mathrm{NH}_{2}\) (structure chain).
CHXII13:AMINES
324225
Which compound will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution
The compound which will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution is \(\mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}\). The reaction takes place as follows : \(\begin{aligned}& \mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}+\mathrm{NaHCO}_{3} \\& \rightarrow \mathrm{CH}_{3}-\mathrm{NH}_{2}+\mathrm{NaCl}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} \uparrow\end{aligned}\)
The structure of intermediate acetyl nitrene is \(\mathrm{CH}_{3}-\mathrm{CO}-\mathrm{N}\).
CHXII13:AMINES
324224
Which of the following alkene cannot be prepared by de-amination of \(\mathrm{n}-\mathrm{Bu}-\mathrm{NH}_{2}\) with \(\mathrm{NaNO}_{2} / \mathrm{HCl}\) ?
1 1-butene
2 cis-2-butene
3 trans-2-butene
4 Iso-butene
Explanation:
Formation of isobutene (branched alkene) does not take place by using n\(\mathrm{Bu} \mathrm{NH}_{2}\) (structure chain).
CHXII13:AMINES
324225
Which compound will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution
The compound which will liberate \(\mathrm{CO}_{2}\) from \(\mathrm{NaHCO}_{3}\) solution is \(\mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}\). The reaction takes place as follows : \(\begin{aligned}& \mathrm{CH}_{3} \mathrm{~N}^{+} \mathrm{H}_{3} \mathrm{Cl}^{-}+\mathrm{NaHCO}_{3} \\& \rightarrow \mathrm{CH}_{3}-\mathrm{NH}_{2}+\mathrm{NaCl}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} \uparrow\end{aligned}\)
