Amines
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CHXII13:AMINES

324200 Assertion :
Primary aliphatic amines react with \(\mathrm{CS}_{2}\) and \(\mathrm{HgCl}_{2}\), give precipitate of \(\mathrm{HgS}\).
Reason :
Secondary amine does not give precipitate of \(\mathrm{HgS}\) in this reaction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII13:AMINES

324201 In the reaction,\(\mathrm{RNH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{ROH}+\mathrm{H}_{2} \mathrm{O}+\mathrm{C} \uparrow ; \mathrm{C}\) is

1 \(\mathrm{NH}_{3}\)
2 \(\mathrm{N}_{2}\)
3 \(\mathrm{O}_{2}\)
4 \(\mathrm{CO}_{2}\)
CHXII13:AMINES

324202 A mixture of \(1^{\circ}, 2^{\circ}\) and \(3^{\circ}\) amines can be separated by Hinsberg's reagent which is

1 Benzene sulphonyl chloride
2 Benzoyl chloride
3 Benzyl chloride
4 Acetyl chloride
CHXII13:AMINES

324203 An aliphatic amine on treatment with alcoholic carbon disulphide and mercuric chloride forms ethyl isothiocyanate, the reaciton is known as

1 Hofmann's reaction
2 Hofmann's rearrangement
3 Hofmann's mustard oil reaction
4 Hofmann's bromamide degradation reaction
AIIMS - 2007
For More Updates join with Us
CHXII13:AMINES

324200 Assertion :
Primary aliphatic amines react with \(\mathrm{CS}_{2}\) and \(\mathrm{HgCl}_{2}\), give precipitate of \(\mathrm{HgS}\).
Reason :
Secondary amine does not give precipitate of \(\mathrm{HgS}\) in this reaction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII13:AMINES

324201 In the reaction,\(\mathrm{RNH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{ROH}+\mathrm{H}_{2} \mathrm{O}+\mathrm{C} \uparrow ; \mathrm{C}\) is

1 \(\mathrm{NH}_{3}\)
2 \(\mathrm{N}_{2}\)
3 \(\mathrm{O}_{2}\)
4 \(\mathrm{CO}_{2}\)
CHXII13:AMINES

324202 A mixture of \(1^{\circ}, 2^{\circ}\) and \(3^{\circ}\) amines can be separated by Hinsberg's reagent which is

1 Benzene sulphonyl chloride
2 Benzoyl chloride
3 Benzyl chloride
4 Acetyl chloride
CHXII13:AMINES

324203 An aliphatic amine on treatment with alcoholic carbon disulphide and mercuric chloride forms ethyl isothiocyanate, the reaciton is known as

1 Hofmann's reaction
2 Hofmann's rearrangement
3 Hofmann's mustard oil reaction
4 Hofmann's bromamide degradation reaction
AIIMS - 2007
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CHXII13:AMINES

324200 Assertion :
Primary aliphatic amines react with \(\mathrm{CS}_{2}\) and \(\mathrm{HgCl}_{2}\), give precipitate of \(\mathrm{HgS}\).
Reason :
Secondary amine does not give precipitate of \(\mathrm{HgS}\) in this reaction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII13:AMINES

324201 In the reaction,\(\mathrm{RNH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{ROH}+\mathrm{H}_{2} \mathrm{O}+\mathrm{C} \uparrow ; \mathrm{C}\) is

1 \(\mathrm{NH}_{3}\)
2 \(\mathrm{N}_{2}\)
3 \(\mathrm{O}_{2}\)
4 \(\mathrm{CO}_{2}\)
CHXII13:AMINES

324202 A mixture of \(1^{\circ}, 2^{\circ}\) and \(3^{\circ}\) amines can be separated by Hinsberg's reagent which is

1 Benzene sulphonyl chloride
2 Benzoyl chloride
3 Benzyl chloride
4 Acetyl chloride
CHXII13:AMINES

324203 An aliphatic amine on treatment with alcoholic carbon disulphide and mercuric chloride forms ethyl isothiocyanate, the reaciton is known as

1 Hofmann's reaction
2 Hofmann's rearrangement
3 Hofmann's mustard oil reaction
4 Hofmann's bromamide degradation reaction
AIIMS - 2007
Join With Us for More Updates
CHXII13:AMINES

324200 Assertion :
Primary aliphatic amines react with \(\mathrm{CS}_{2}\) and \(\mathrm{HgCl}_{2}\), give precipitate of \(\mathrm{HgS}\).
Reason :
Secondary amine does not give precipitate of \(\mathrm{HgS}\) in this reaction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII13:AMINES

324201 In the reaction,\(\mathrm{RNH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{ROH}+\mathrm{H}_{2} \mathrm{O}+\mathrm{C} \uparrow ; \mathrm{C}\) is

1 \(\mathrm{NH}_{3}\)
2 \(\mathrm{N}_{2}\)
3 \(\mathrm{O}_{2}\)
4 \(\mathrm{CO}_{2}\)
CHXII13:AMINES

324202 A mixture of \(1^{\circ}, 2^{\circ}\) and \(3^{\circ}\) amines can be separated by Hinsberg's reagent which is

1 Benzene sulphonyl chloride
2 Benzoyl chloride
3 Benzyl chloride
4 Acetyl chloride
CHXII13:AMINES

324203 An aliphatic amine on treatment with alcoholic carbon disulphide and mercuric chloride forms ethyl isothiocyanate, the reaciton is known as

1 Hofmann's reaction
2 Hofmann's rearrangement
3 Hofmann's mustard oil reaction
4 Hofmann's bromamide degradation reaction
AIIMS - 2007
For More Updates join with Us
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