Amines
CHXII13:AMINES

324157 What is the end product in the following sequence of operations?
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{A} \stackrel{\mathrm{PCl}_{5}}{\longrightarrow} \mathrm{B} \stackrel{\mathrm{NH}_{3}}{\longrightarrow} \mathrm{C}\)

1 Ethyl cyanide
2 Methyl amine
3 Ethyl amine
4 Acetamide
CHXII13:AMINES

324158 Match the column I (reaction condition) with column II (nature of amine) and choose the correct option.
Column I
Column II
A
Gabriel phthalimide reaction
P
Used for ascent amine series preparation
B
Reduction with \({\rm{LiAl}}{{\rm{H}}_{\rm{4}}}\)
Q
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)
C
Reduction of nitrobenzene with \({\rm{Sn + HCl}}\)
R
One carbon less amine than the reactant
D
\({{\rm{1}}^{\rm{o}}}\) Amide with \({\rm{B}}{{\rm{r}}_{\rm{2}}}{\rm{ + KOH}}\)
S
\({\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{C}}{{\rm{H}}_{\rm{2}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)

1 A - S, B - P, C - Q, D - R
2 A - S, B - P, C - R, D - S
3 A - S, B - R, C - Q, D - S
4 A - Q, B - P, C - R, D - S
CHXII13:AMINES

324159 supporting img
Structure of (D) is :

1 \(\mathrm{Ph}-\mathrm{CH}_{2} \mathrm{NH}_{2}\)
2 \(\mathrm{Ph}-\mathrm{NC}\)
3 \(\mathrm{PhCH}_{2} \mathrm{NC}\)
4 \(\mathrm{PhCH}_{2} \mathrm{CN}\)
CHXII13:AMINES

324160 An organic compound \((\mathrm{A})\) on reduction gives compound (B). (B) on treatment with \(\mathrm{CHCl}_{3}\) and alcoholic \(\mathrm{KOH}\) gives (C) . (C) on catalytic reduction gives \(\mathrm{N}\)-methylaniline. The compound ' \({\text{A}}\) ' is

1 Methylamine
2 Nitromethane
3 Aniline
4 Nitrobenzene
CHXII13:AMINES

324161 Identify the product ' \(\mathrm{C}\) ' in the following reaction.
\({\text{Aniline}}\xrightarrow[{{\text{Pyridine}}}]{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}{\text{CO}}} \right)}_{\text{2}}}{\text{O}}}}{\text{A}}\xrightarrow[{{\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}}]{{{\text{B}}{{\text{r}}_{\text{2}}}}}{\text{B}}\xrightarrow{{{{\text{H}}^{\text{ + }}}\,\,{\text{or}}\,\,{\text{O}}{{\text{H}}^{\text{ - }}}}}{\text{C}}\)

1 Acetanilide
2 p-bromoacetanilide
3 p-bromoaniline
4 o-bromoaniline
CHXII13:AMINES

324157 What is the end product in the following sequence of operations?
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{A} \stackrel{\mathrm{PCl}_{5}}{\longrightarrow} \mathrm{B} \stackrel{\mathrm{NH}_{3}}{\longrightarrow} \mathrm{C}\)

1 Ethyl cyanide
2 Methyl amine
3 Ethyl amine
4 Acetamide
CHXII13:AMINES

324158 Match the column I (reaction condition) with column II (nature of amine) and choose the correct option.
Column I
Column II
A
Gabriel phthalimide reaction
P
Used for ascent amine series preparation
B
Reduction with \({\rm{LiAl}}{{\rm{H}}_{\rm{4}}}\)
Q
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)
C
Reduction of nitrobenzene with \({\rm{Sn + HCl}}\)
R
One carbon less amine than the reactant
D
\({{\rm{1}}^{\rm{o}}}\) Amide with \({\rm{B}}{{\rm{r}}_{\rm{2}}}{\rm{ + KOH}}\)
S
\({\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{C}}{{\rm{H}}_{\rm{2}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)

1 A - S, B - P, C - Q, D - R
2 A - S, B - P, C - R, D - S
3 A - S, B - R, C - Q, D - S
4 A - Q, B - P, C - R, D - S
CHXII13:AMINES

324159 supporting img
Structure of (D) is :

1 \(\mathrm{Ph}-\mathrm{CH}_{2} \mathrm{NH}_{2}\)
2 \(\mathrm{Ph}-\mathrm{NC}\)
3 \(\mathrm{PhCH}_{2} \mathrm{NC}\)
4 \(\mathrm{PhCH}_{2} \mathrm{CN}\)
CHXII13:AMINES

324160 An organic compound \((\mathrm{A})\) on reduction gives compound (B). (B) on treatment with \(\mathrm{CHCl}_{3}\) and alcoholic \(\mathrm{KOH}\) gives (C) . (C) on catalytic reduction gives \(\mathrm{N}\)-methylaniline. The compound ' \({\text{A}}\) ' is

1 Methylamine
2 Nitromethane
3 Aniline
4 Nitrobenzene
CHXII13:AMINES

324161 Identify the product ' \(\mathrm{C}\) ' in the following reaction.
\({\text{Aniline}}\xrightarrow[{{\text{Pyridine}}}]{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}{\text{CO}}} \right)}_{\text{2}}}{\text{O}}}}{\text{A}}\xrightarrow[{{\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}}]{{{\text{B}}{{\text{r}}_{\text{2}}}}}{\text{B}}\xrightarrow{{{{\text{H}}^{\text{ + }}}\,\,{\text{or}}\,\,{\text{O}}{{\text{H}}^{\text{ - }}}}}{\text{C}}\)

1 Acetanilide
2 p-bromoacetanilide
3 p-bromoaniline
4 o-bromoaniline
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII13:AMINES

324157 What is the end product in the following sequence of operations?
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{A} \stackrel{\mathrm{PCl}_{5}}{\longrightarrow} \mathrm{B} \stackrel{\mathrm{NH}_{3}}{\longrightarrow} \mathrm{C}\)

1 Ethyl cyanide
2 Methyl amine
3 Ethyl amine
4 Acetamide
CHXII13:AMINES

324158 Match the column I (reaction condition) with column II (nature of amine) and choose the correct option.
Column I
Column II
A
Gabriel phthalimide reaction
P
Used for ascent amine series preparation
B
Reduction with \({\rm{LiAl}}{{\rm{H}}_{\rm{4}}}\)
Q
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)
C
Reduction of nitrobenzene with \({\rm{Sn + HCl}}\)
R
One carbon less amine than the reactant
D
\({{\rm{1}}^{\rm{o}}}\) Amide with \({\rm{B}}{{\rm{r}}_{\rm{2}}}{\rm{ + KOH}}\)
S
\({\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{C}}{{\rm{H}}_{\rm{2}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)

1 A - S, B - P, C - Q, D - R
2 A - S, B - P, C - R, D - S
3 A - S, B - R, C - Q, D - S
4 A - Q, B - P, C - R, D - S
CHXII13:AMINES

324159 supporting img
Structure of (D) is :

1 \(\mathrm{Ph}-\mathrm{CH}_{2} \mathrm{NH}_{2}\)
2 \(\mathrm{Ph}-\mathrm{NC}\)
3 \(\mathrm{PhCH}_{2} \mathrm{NC}\)
4 \(\mathrm{PhCH}_{2} \mathrm{CN}\)
CHXII13:AMINES

324160 An organic compound \((\mathrm{A})\) on reduction gives compound (B). (B) on treatment with \(\mathrm{CHCl}_{3}\) and alcoholic \(\mathrm{KOH}\) gives (C) . (C) on catalytic reduction gives \(\mathrm{N}\)-methylaniline. The compound ' \({\text{A}}\) ' is

1 Methylamine
2 Nitromethane
3 Aniline
4 Nitrobenzene
CHXII13:AMINES

324161 Identify the product ' \(\mathrm{C}\) ' in the following reaction.
\({\text{Aniline}}\xrightarrow[{{\text{Pyridine}}}]{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}{\text{CO}}} \right)}_{\text{2}}}{\text{O}}}}{\text{A}}\xrightarrow[{{\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}}]{{{\text{B}}{{\text{r}}_{\text{2}}}}}{\text{B}}\xrightarrow{{{{\text{H}}^{\text{ + }}}\,\,{\text{or}}\,\,{\text{O}}{{\text{H}}^{\text{ - }}}}}{\text{C}}\)

1 Acetanilide
2 p-bromoacetanilide
3 p-bromoaniline
4 o-bromoaniline
CHXII13:AMINES

324157 What is the end product in the following sequence of operations?
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{A} \stackrel{\mathrm{PCl}_{5}}{\longrightarrow} \mathrm{B} \stackrel{\mathrm{NH}_{3}}{\longrightarrow} \mathrm{C}\)

1 Ethyl cyanide
2 Methyl amine
3 Ethyl amine
4 Acetamide
CHXII13:AMINES

324158 Match the column I (reaction condition) with column II (nature of amine) and choose the correct option.
Column I
Column II
A
Gabriel phthalimide reaction
P
Used for ascent amine series preparation
B
Reduction with \({\rm{LiAl}}{{\rm{H}}_{\rm{4}}}\)
Q
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)
C
Reduction of nitrobenzene with \({\rm{Sn + HCl}}\)
R
One carbon less amine than the reactant
D
\({{\rm{1}}^{\rm{o}}}\) Amide with \({\rm{B}}{{\rm{r}}_{\rm{2}}}{\rm{ + KOH}}\)
S
\({\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{C}}{{\rm{H}}_{\rm{2}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)

1 A - S, B - P, C - Q, D - R
2 A - S, B - P, C - R, D - S
3 A - S, B - R, C - Q, D - S
4 A - Q, B - P, C - R, D - S
CHXII13:AMINES

324159 supporting img
Structure of (D) is :

1 \(\mathrm{Ph}-\mathrm{CH}_{2} \mathrm{NH}_{2}\)
2 \(\mathrm{Ph}-\mathrm{NC}\)
3 \(\mathrm{PhCH}_{2} \mathrm{NC}\)
4 \(\mathrm{PhCH}_{2} \mathrm{CN}\)
CHXII13:AMINES

324160 An organic compound \((\mathrm{A})\) on reduction gives compound (B). (B) on treatment with \(\mathrm{CHCl}_{3}\) and alcoholic \(\mathrm{KOH}\) gives (C) . (C) on catalytic reduction gives \(\mathrm{N}\)-methylaniline. The compound ' \({\text{A}}\) ' is

1 Methylamine
2 Nitromethane
3 Aniline
4 Nitrobenzene
CHXII13:AMINES

324161 Identify the product ' \(\mathrm{C}\) ' in the following reaction.
\({\text{Aniline}}\xrightarrow[{{\text{Pyridine}}}]{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}{\text{CO}}} \right)}_{\text{2}}}{\text{O}}}}{\text{A}}\xrightarrow[{{\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}}]{{{\text{B}}{{\text{r}}_{\text{2}}}}}{\text{B}}\xrightarrow{{{{\text{H}}^{\text{ + }}}\,\,{\text{or}}\,\,{\text{O}}{{\text{H}}^{\text{ - }}}}}{\text{C}}\)

1 Acetanilide
2 p-bromoacetanilide
3 p-bromoaniline
4 o-bromoaniline
CHXII13:AMINES

324157 What is the end product in the following sequence of operations?
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2} \stackrel{\mathrm{HNO}_{2}}{\longrightarrow} \mathrm{A} \stackrel{\mathrm{PCl}_{5}}{\longrightarrow} \mathrm{B} \stackrel{\mathrm{NH}_{3}}{\longrightarrow} \mathrm{C}\)

1 Ethyl cyanide
2 Methyl amine
3 Ethyl amine
4 Acetamide
CHXII13:AMINES

324158 Match the column I (reaction condition) with column II (nature of amine) and choose the correct option.
Column I
Column II
A
Gabriel phthalimide reaction
P
Used for ascent amine series preparation
B
Reduction with \({\rm{LiAl}}{{\rm{H}}_{\rm{4}}}\)
Q
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)
C
Reduction of nitrobenzene with \({\rm{Sn + HCl}}\)
R
One carbon less amine than the reactant
D
\({{\rm{1}}^{\rm{o}}}\) Amide with \({\rm{B}}{{\rm{r}}_{\rm{2}}}{\rm{ + KOH}}\)
S
\({\rm{C}}{{\rm{H}}_{\rm{3}}}{\rm{C}}{{\rm{H}}_{\rm{2}}}{\rm{N}}{{\rm{H}}_{\rm{2}}}\)

1 A - S, B - P, C - Q, D - R
2 A - S, B - P, C - R, D - S
3 A - S, B - R, C - Q, D - S
4 A - Q, B - P, C - R, D - S
CHXII13:AMINES

324159 supporting img
Structure of (D) is :

1 \(\mathrm{Ph}-\mathrm{CH}_{2} \mathrm{NH}_{2}\)
2 \(\mathrm{Ph}-\mathrm{NC}\)
3 \(\mathrm{PhCH}_{2} \mathrm{NC}\)
4 \(\mathrm{PhCH}_{2} \mathrm{CN}\)
CHXII13:AMINES

324160 An organic compound \((\mathrm{A})\) on reduction gives compound (B). (B) on treatment with \(\mathrm{CHCl}_{3}\) and alcoholic \(\mathrm{KOH}\) gives (C) . (C) on catalytic reduction gives \(\mathrm{N}\)-methylaniline. The compound ' \({\text{A}}\) ' is

1 Methylamine
2 Nitromethane
3 Aniline
4 Nitrobenzene
CHXII13:AMINES

324161 Identify the product ' \(\mathrm{C}\) ' in the following reaction.
\({\text{Aniline}}\xrightarrow[{{\text{Pyridine}}}]{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}{\text{CO}}} \right)}_{\text{2}}}{\text{O}}}}{\text{A}}\xrightarrow[{{\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}}]{{{\text{B}}{{\text{r}}_{\text{2}}}}}{\text{B}}\xrightarrow{{{{\text{H}}^{\text{ + }}}\,\,{\text{or}}\,\,{\text{O}}{{\text{H}}^{\text{ - }}}}}{\text{C}}\)

1 Acetanilide
2 p-bromoacetanilide
3 p-bromoaniline
4 o-bromoaniline