Amines
CHXII13:AMINES

324149 The incorrect statement regarding the reaction given below is
supporting img

1 The reaction occurs at low temperature.
2 The electrophile involved in the reaction is \(\mathrm{NO}^{+}\).
3 The product ' B ' formed in the above reaction is p -nitroso compound at low temperature.
4 B ' is N – Nitroso ammonium compound.
CHXII13:AMINES

324150 The correct match of Column I (Amines) and Column II (Property) is
Column I
Column II
A
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
P
Undergoes Lieberman nitrosoamine
B
\({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
Q
Undergoes Hoffmann bromamide reaction
C
\({{\text{(C}}{{\text{H}}_{\text{3}}}{\text{)}}_{\text{2}}}{\text{NH}}\)
R
Gives azo dye test
D
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{CON}}{{\text{H}}_{\text{2}}}\)
S
With alcoholic KOH and \({\text{CHC}}{{\text{l}}_{\text{3}}}\) producesbad smell

1 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{P}, \quad \mathrm{D}-\mathrm{Q}\)
2 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{P}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{Q}\)
3 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{Q}, \quad \mathrm{D}-\mathrm{P}\)
4 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{Q}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{P}\)
CHXII13:AMINES

324151 A compound of molecular formulae \({{\rm{C}}_{\rm{3}}}{{\rm{H}}_{\rm{6}}}{\rm{N}}\) shows following characteristics
(i) Get dissolved in acidic medium.
(ii) Does not react with benzoylchloride
(iii) Does not give carbylamine test
(iv) Does not evolute nitrogen gas on reacting with \(\mathrm{HNO}_{2}\)
The structure of the compound is

1 trimethylamine
2 isopropylamine
3 propylamine
4 None of these
CHXII13:AMINES

324152 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{~N}_{2} \mathrm{Cl}\) in presence of KCN and CuCN gives an organic compound, which on acid hydrolysis gives ' X '. The compound ' X ' may be

1 benzonitrile
2 benzoic acid
3 benzonitrite
4 phenylacetic acid.
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CHXII13:AMINES

324149 The incorrect statement regarding the reaction given below is
supporting img

1 The reaction occurs at low temperature.
2 The electrophile involved in the reaction is \(\mathrm{NO}^{+}\).
3 The product ' B ' formed in the above reaction is p -nitroso compound at low temperature.
4 B ' is N – Nitroso ammonium compound.
CHXII13:AMINES

324150 The correct match of Column I (Amines) and Column II (Property) is
Column I
Column II
A
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
P
Undergoes Lieberman nitrosoamine
B
\({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
Q
Undergoes Hoffmann bromamide reaction
C
\({{\text{(C}}{{\text{H}}_{\text{3}}}{\text{)}}_{\text{2}}}{\text{NH}}\)
R
Gives azo dye test
D
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{CON}}{{\text{H}}_{\text{2}}}\)
S
With alcoholic KOH and \({\text{CHC}}{{\text{l}}_{\text{3}}}\) producesbad smell

1 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{P}, \quad \mathrm{D}-\mathrm{Q}\)
2 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{P}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{Q}\)
3 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{Q}, \quad \mathrm{D}-\mathrm{P}\)
4 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{Q}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{P}\)
CHXII13:AMINES

324151 A compound of molecular formulae \({{\rm{C}}_{\rm{3}}}{{\rm{H}}_{\rm{6}}}{\rm{N}}\) shows following characteristics
(i) Get dissolved in acidic medium.
(ii) Does not react with benzoylchloride
(iii) Does not give carbylamine test
(iv) Does not evolute nitrogen gas on reacting with \(\mathrm{HNO}_{2}\)
The structure of the compound is

1 trimethylamine
2 isopropylamine
3 propylamine
4 None of these
CHXII13:AMINES

324152 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{~N}_{2} \mathrm{Cl}\) in presence of KCN and CuCN gives an organic compound, which on acid hydrolysis gives ' X '. The compound ' X ' may be

1 benzonitrile
2 benzoic acid
3 benzonitrite
4 phenylacetic acid.
CHXII13:AMINES

324149 The incorrect statement regarding the reaction given below is
supporting img

1 The reaction occurs at low temperature.
2 The electrophile involved in the reaction is \(\mathrm{NO}^{+}\).
3 The product ' B ' formed in the above reaction is p -nitroso compound at low temperature.
4 B ' is N – Nitroso ammonium compound.
CHXII13:AMINES

324150 The correct match of Column I (Amines) and Column II (Property) is
Column I
Column II
A
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
P
Undergoes Lieberman nitrosoamine
B
\({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
Q
Undergoes Hoffmann bromamide reaction
C
\({{\text{(C}}{{\text{H}}_{\text{3}}}{\text{)}}_{\text{2}}}{\text{NH}}\)
R
Gives azo dye test
D
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{CON}}{{\text{H}}_{\text{2}}}\)
S
With alcoholic KOH and \({\text{CHC}}{{\text{l}}_{\text{3}}}\) producesbad smell

1 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{P}, \quad \mathrm{D}-\mathrm{Q}\)
2 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{P}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{Q}\)
3 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{Q}, \quad \mathrm{D}-\mathrm{P}\)
4 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{Q}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{P}\)
CHXII13:AMINES

324151 A compound of molecular formulae \({{\rm{C}}_{\rm{3}}}{{\rm{H}}_{\rm{6}}}{\rm{N}}\) shows following characteristics
(i) Get dissolved in acidic medium.
(ii) Does not react with benzoylchloride
(iii) Does not give carbylamine test
(iv) Does not evolute nitrogen gas on reacting with \(\mathrm{HNO}_{2}\)
The structure of the compound is

1 trimethylamine
2 isopropylamine
3 propylamine
4 None of these
CHXII13:AMINES

324152 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{~N}_{2} \mathrm{Cl}\) in presence of KCN and CuCN gives an organic compound, which on acid hydrolysis gives ' X '. The compound ' X ' may be

1 benzonitrile
2 benzoic acid
3 benzonitrite
4 phenylacetic acid.
CHXII13:AMINES

324149 The incorrect statement regarding the reaction given below is
supporting img

1 The reaction occurs at low temperature.
2 The electrophile involved in the reaction is \(\mathrm{NO}^{+}\).
3 The product ' B ' formed in the above reaction is p -nitroso compound at low temperature.
4 B ' is N – Nitroso ammonium compound.
CHXII13:AMINES

324150 The correct match of Column I (Amines) and Column II (Property) is
Column I
Column II
A
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
P
Undergoes Lieberman nitrosoamine
B
\({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{N}}{{\text{H}}_{\text{2}}}\)
Q
Undergoes Hoffmann bromamide reaction
C
\({{\text{(C}}{{\text{H}}_{\text{3}}}{\text{)}}_{\text{2}}}{\text{NH}}\)
R
Gives azo dye test
D
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{CON}}{{\text{H}}_{\text{2}}}\)
S
With alcoholic KOH and \({\text{CHC}}{{\text{l}}_{\text{3}}}\) producesbad smell

1 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{P}, \quad \mathrm{D}-\mathrm{Q}\)
2 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{P}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{Q}\)
3 \(\mathrm{A}-\mathrm{S}, \mathrm{B}-\mathrm{R}, \quad \mathrm{C}-\mathrm{Q}, \quad \mathrm{D}-\mathrm{P}\)
4 \(\mathrm{A}-\mathrm{R}, \mathrm{B}-\mathrm{Q}, \quad \mathrm{C}-\mathrm{S}, \quad \mathrm{D}-\mathrm{P}\)
CHXII13:AMINES

324151 A compound of molecular formulae \({{\rm{C}}_{\rm{3}}}{{\rm{H}}_{\rm{6}}}{\rm{N}}\) shows following characteristics
(i) Get dissolved in acidic medium.
(ii) Does not react with benzoylchloride
(iii) Does not give carbylamine test
(iv) Does not evolute nitrogen gas on reacting with \(\mathrm{HNO}_{2}\)
The structure of the compound is

1 trimethylamine
2 isopropylamine
3 propylamine
4 None of these
CHXII13:AMINES

324152 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{~N}_{2} \mathrm{Cl}\) in presence of KCN and CuCN gives an organic compound, which on acid hydrolysis gives ' X '. The compound ' X ' may be

1 benzonitrile
2 benzoic acid
3 benzonitrite
4 phenylacetic acid.