Chemical Reactions of Aldehydes and Ketones
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323658 Amongst the following the total number of compounds that gives positive iodoform test are ____ .
\({\mathrm{\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \quad \mathrm{PhCHO}, \quad \mathrm{CH}_{3} \mathrm{COCH}_{3}}}\), \({\mathrm{\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}, \quad \mathrm{HCHO}, \quad \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{COCH}_{3}}}\), \({\mathrm{\mathrm{PhCH}_{2} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COPh}}}\)

1 6
2 3
3 5
4 4
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323659 Assertion :
\(\mathrm{CCl}_{3} \mathrm{CHO}\) forms an isolable crystalline hydrate.
Reason :
Electron withdrawing chlorine atoms stabilise hydrate by intramolecular H-bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323660 A solution of \(\mathrm{CuSO}_{4}\) with Rochelle salt and \(\mathrm{NaOH}\) is called

1 Benedict's solution
2 Schiff's reagent
3 Fehling's solution
4 Tollen's reagent
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323661 Compound (A), \(\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}\), is inert to \(\mathrm{Br}_{2}\) in \(\mathrm{CCl}_{4}\). Vigorous oxidation with hot alkaline \(\mathrm{KMnO}_{4}\) yields benzoic acid. Compound "A" gives red precipitate with 2,4-dinitrophenylhydrazine and yellow with \(\mathrm{NaOI}\). The possible structure of compound (A) will be :

1 \(\mathrm{PhCOCH}_{2} \mathrm{CH}_{3}\)
2 \(\mathrm{PhCH}_{2} \mathrm{COCH}_{3}\)
3 \(\mathrm{PhCH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{PhCH}\left(\mathrm{CH}_{3}\right) \mathrm{CHO}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323662 An organic liquid has an empirical formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}\). The liquid gives a pale yellow precipitate on warming with iodine in alkaline potassium hydroxide solution. The structural formula of the organic liquid could be

1 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
2 \(\mathrm{CH}_{2}=\mathrm{CHCH}(\mathrm{OH}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}=\mathrm{CH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323658 Amongst the following the total number of compounds that gives positive iodoform test are ____ .
\({\mathrm{\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \quad \mathrm{PhCHO}, \quad \mathrm{CH}_{3} \mathrm{COCH}_{3}}}\), \({\mathrm{\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}, \quad \mathrm{HCHO}, \quad \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{COCH}_{3}}}\), \({\mathrm{\mathrm{PhCH}_{2} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COPh}}}\)

1 6
2 3
3 5
4 4
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323659 Assertion :
\(\mathrm{CCl}_{3} \mathrm{CHO}\) forms an isolable crystalline hydrate.
Reason :
Electron withdrawing chlorine atoms stabilise hydrate by intramolecular H-bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323660 A solution of \(\mathrm{CuSO}_{4}\) with Rochelle salt and \(\mathrm{NaOH}\) is called

1 Benedict's solution
2 Schiff's reagent
3 Fehling's solution
4 Tollen's reagent
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323661 Compound (A), \(\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}\), is inert to \(\mathrm{Br}_{2}\) in \(\mathrm{CCl}_{4}\). Vigorous oxidation with hot alkaline \(\mathrm{KMnO}_{4}\) yields benzoic acid. Compound "A" gives red precipitate with 2,4-dinitrophenylhydrazine and yellow with \(\mathrm{NaOI}\). The possible structure of compound (A) will be :

1 \(\mathrm{PhCOCH}_{2} \mathrm{CH}_{3}\)
2 \(\mathrm{PhCH}_{2} \mathrm{COCH}_{3}\)
3 \(\mathrm{PhCH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{PhCH}\left(\mathrm{CH}_{3}\right) \mathrm{CHO}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323662 An organic liquid has an empirical formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}\). The liquid gives a pale yellow precipitate on warming with iodine in alkaline potassium hydroxide solution. The structural formula of the organic liquid could be

1 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
2 \(\mathrm{CH}_{2}=\mathrm{CHCH}(\mathrm{OH}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}=\mathrm{CH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323658 Amongst the following the total number of compounds that gives positive iodoform test are ____ .
\({\mathrm{\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \quad \mathrm{PhCHO}, \quad \mathrm{CH}_{3} \mathrm{COCH}_{3}}}\), \({\mathrm{\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}, \quad \mathrm{HCHO}, \quad \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{COCH}_{3}}}\), \({\mathrm{\mathrm{PhCH}_{2} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COPh}}}\)

1 6
2 3
3 5
4 4
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323659 Assertion :
\(\mathrm{CCl}_{3} \mathrm{CHO}\) forms an isolable crystalline hydrate.
Reason :
Electron withdrawing chlorine atoms stabilise hydrate by intramolecular H-bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323660 A solution of \(\mathrm{CuSO}_{4}\) with Rochelle salt and \(\mathrm{NaOH}\) is called

1 Benedict's solution
2 Schiff's reagent
3 Fehling's solution
4 Tollen's reagent
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323661 Compound (A), \(\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}\), is inert to \(\mathrm{Br}_{2}\) in \(\mathrm{CCl}_{4}\). Vigorous oxidation with hot alkaline \(\mathrm{KMnO}_{4}\) yields benzoic acid. Compound "A" gives red precipitate with 2,4-dinitrophenylhydrazine and yellow with \(\mathrm{NaOI}\). The possible structure of compound (A) will be :

1 \(\mathrm{PhCOCH}_{2} \mathrm{CH}_{3}\)
2 \(\mathrm{PhCH}_{2} \mathrm{COCH}_{3}\)
3 \(\mathrm{PhCH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{PhCH}\left(\mathrm{CH}_{3}\right) \mathrm{CHO}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323662 An organic liquid has an empirical formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}\). The liquid gives a pale yellow precipitate on warming with iodine in alkaline potassium hydroxide solution. The structural formula of the organic liquid could be

1 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
2 \(\mathrm{CH}_{2}=\mathrm{CHCH}(\mathrm{OH}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}=\mathrm{CH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323658 Amongst the following the total number of compounds that gives positive iodoform test are ____ .
\({\mathrm{\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \quad \mathrm{PhCHO}, \quad \mathrm{CH}_{3} \mathrm{COCH}_{3}}}\), \({\mathrm{\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}, \quad \mathrm{HCHO}, \quad \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{COCH}_{3}}}\), \({\mathrm{\mathrm{PhCH}_{2} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COPh}}}\)

1 6
2 3
3 5
4 4
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323659 Assertion :
\(\mathrm{CCl}_{3} \mathrm{CHO}\) forms an isolable crystalline hydrate.
Reason :
Electron withdrawing chlorine atoms stabilise hydrate by intramolecular H-bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323660 A solution of \(\mathrm{CuSO}_{4}\) with Rochelle salt and \(\mathrm{NaOH}\) is called

1 Benedict's solution
2 Schiff's reagent
3 Fehling's solution
4 Tollen's reagent
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323661 Compound (A), \(\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}\), is inert to \(\mathrm{Br}_{2}\) in \(\mathrm{CCl}_{4}\). Vigorous oxidation with hot alkaline \(\mathrm{KMnO}_{4}\) yields benzoic acid. Compound "A" gives red precipitate with 2,4-dinitrophenylhydrazine and yellow with \(\mathrm{NaOI}\). The possible structure of compound (A) will be :

1 \(\mathrm{PhCOCH}_{2} \mathrm{CH}_{3}\)
2 \(\mathrm{PhCH}_{2} \mathrm{COCH}_{3}\)
3 \(\mathrm{PhCH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{PhCH}\left(\mathrm{CH}_{3}\right) \mathrm{CHO}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323662 An organic liquid has an empirical formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}\). The liquid gives a pale yellow precipitate on warming with iodine in alkaline potassium hydroxide solution. The structural formula of the organic liquid could be

1 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
2 \(\mathrm{CH}_{2}=\mathrm{CHCH}(\mathrm{OH}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}=\mathrm{CH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323658 Amongst the following the total number of compounds that gives positive iodoform test are ____ .
\({\mathrm{\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}, \quad \mathrm{PhCHO}, \quad \mathrm{CH}_{3} \mathrm{COCH}_{3}}}\), \({\mathrm{\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}, \quad \mathrm{HCHO}, \quad \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{COCH}_{3}}}\), \({\mathrm{\mathrm{PhCH}_{2} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COPh}}}\)

1 6
2 3
3 5
4 4
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323659 Assertion :
\(\mathrm{CCl}_{3} \mathrm{CHO}\) forms an isolable crystalline hydrate.
Reason :
Electron withdrawing chlorine atoms stabilise hydrate by intramolecular H-bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323660 A solution of \(\mathrm{CuSO}_{4}\) with Rochelle salt and \(\mathrm{NaOH}\) is called

1 Benedict's solution
2 Schiff's reagent
3 Fehling's solution
4 Tollen's reagent
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323661 Compound (A), \(\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}\), is inert to \(\mathrm{Br}_{2}\) in \(\mathrm{CCl}_{4}\). Vigorous oxidation with hot alkaline \(\mathrm{KMnO}_{4}\) yields benzoic acid. Compound "A" gives red precipitate with 2,4-dinitrophenylhydrazine and yellow with \(\mathrm{NaOI}\). The possible structure of compound (A) will be :

1 \(\mathrm{PhCOCH}_{2} \mathrm{CH}_{3}\)
2 \(\mathrm{PhCH}_{2} \mathrm{COCH}_{3}\)
3 \(\mathrm{PhCH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{PhCH}\left(\mathrm{CH}_{3}\right) \mathrm{CHO}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323662 An organic liquid has an empirical formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}\). The liquid gives a pale yellow precipitate on warming with iodine in alkaline potassium hydroxide solution. The structural formula of the organic liquid could be

1 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
2 \(\mathrm{CH}_{2}=\mathrm{CHCH}(\mathrm{OH}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CHO}\)
4 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}=\mathrm{CH}_{2}\)