Reactions of Alcohols
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323175 Read the Assertion and Reason carefully to mark the correct option out of the options given below.
Assertion :
Alcohols react both as nucleophiles and electrophiles.
Reason :
Alcohols react with active metals such sodium,potassium and aluminium to yeild corresponding alkoxides and liberate hydrogen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323176 Which of the following statements are correct regarding esterification of alcohols?
I. Alcohols react with carboxylic acids, acid chlorides, and acid anhydrides to form esters.
II. The reaction with carboxylic acid and acid anhydride is carried out in presence of a small amount of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
III. The reaction with acid chloride is carried out in presence of a base (pyridine) to neutralize the side product HCl .
IV. The reaction with carboxylic acid and acid anhydride is reversible while with acid chloride, it is irreversible.

1 I, II and III
2 II and III
3 I, II and IV
4 I, II, III and IV
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323177 The gas evolved on heating \(\mathrm{CH}_{3} \mathrm{MgBr}\) in methanol is:

1 Propane
2 Ethane
3 HBr
4 Methane
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323178 0.218 g of acetyl derivative of polyhydric alcohol with molecular mass \({\mathrm{=92}}\), requires 0.168 g of KOH for hydrolysis. The number of \({\mathrm{(-\mathrm{OH})}}\) groups in the alcohol being halved is ____ .

1 3
2 1.5
3 6
4 2.5
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323175 Read the Assertion and Reason carefully to mark the correct option out of the options given below.
Assertion :
Alcohols react both as nucleophiles and electrophiles.
Reason :
Alcohols react with active metals such sodium,potassium and aluminium to yeild corresponding alkoxides and liberate hydrogen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323176 Which of the following statements are correct regarding esterification of alcohols?
I. Alcohols react with carboxylic acids, acid chlorides, and acid anhydrides to form esters.
II. The reaction with carboxylic acid and acid anhydride is carried out in presence of a small amount of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
III. The reaction with acid chloride is carried out in presence of a base (pyridine) to neutralize the side product HCl .
IV. The reaction with carboxylic acid and acid anhydride is reversible while with acid chloride, it is irreversible.

1 I, II and III
2 II and III
3 I, II and IV
4 I, II, III and IV
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323177 The gas evolved on heating \(\mathrm{CH}_{3} \mathrm{MgBr}\) in methanol is:

1 Propane
2 Ethane
3 HBr
4 Methane
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323178 0.218 g of acetyl derivative of polyhydric alcohol with molecular mass \({\mathrm{=92}}\), requires 0.168 g of KOH for hydrolysis. The number of \({\mathrm{(-\mathrm{OH})}}\) groups in the alcohol being halved is ____ .

1 3
2 1.5
3 6
4 2.5
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323175 Read the Assertion and Reason carefully to mark the correct option out of the options given below.
Assertion :
Alcohols react both as nucleophiles and electrophiles.
Reason :
Alcohols react with active metals such sodium,potassium and aluminium to yeild corresponding alkoxides and liberate hydrogen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323176 Which of the following statements are correct regarding esterification of alcohols?
I. Alcohols react with carboxylic acids, acid chlorides, and acid anhydrides to form esters.
II. The reaction with carboxylic acid and acid anhydride is carried out in presence of a small amount of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
III. The reaction with acid chloride is carried out in presence of a base (pyridine) to neutralize the side product HCl .
IV. The reaction with carboxylic acid and acid anhydride is reversible while with acid chloride, it is irreversible.

1 I, II and III
2 II and III
3 I, II and IV
4 I, II, III and IV
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323177 The gas evolved on heating \(\mathrm{CH}_{3} \mathrm{MgBr}\) in methanol is:

1 Propane
2 Ethane
3 HBr
4 Methane
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323178 0.218 g of acetyl derivative of polyhydric alcohol with molecular mass \({\mathrm{=92}}\), requires 0.168 g of KOH for hydrolysis. The number of \({\mathrm{(-\mathrm{OH})}}\) groups in the alcohol being halved is ____ .

1 3
2 1.5
3 6
4 2.5
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323175 Read the Assertion and Reason carefully to mark the correct option out of the options given below.
Assertion :
Alcohols react both as nucleophiles and electrophiles.
Reason :
Alcohols react with active metals such sodium,potassium and aluminium to yeild corresponding alkoxides and liberate hydrogen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323176 Which of the following statements are correct regarding esterification of alcohols?
I. Alcohols react with carboxylic acids, acid chlorides, and acid anhydrides to form esters.
II. The reaction with carboxylic acid and acid anhydride is carried out in presence of a small amount of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\).
III. The reaction with acid chloride is carried out in presence of a base (pyridine) to neutralize the side product HCl .
IV. The reaction with carboxylic acid and acid anhydride is reversible while with acid chloride, it is irreversible.

1 I, II and III
2 II and III
3 I, II and IV
4 I, II, III and IV
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323177 The gas evolved on heating \(\mathrm{CH}_{3} \mathrm{MgBr}\) in methanol is:

1 Propane
2 Ethane
3 HBr
4 Methane
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323178 0.218 g of acetyl derivative of polyhydric alcohol with molecular mass \({\mathrm{=92}}\), requires 0.168 g of KOH for hydrolysis. The number of \({\mathrm{(-\mathrm{OH})}}\) groups in the alcohol being halved is ____ .

1 3
2 1.5
3 6
4 2.5
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