322952
Statement A : Statement B : Alkoxides are not only nucleophiles but also the strong base, so they can react with alkyl halide to form the eliminated product.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both statements are incorrect.
Explanation:
If tertiary alkyl halide is used, an alkene is the only reaction product and no ether is formed. It is because alkoxides are not only nucleophiles but also the strong bases. They react with alkyl halides leading to elimination reactions.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322953
The reaction, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{ONa}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I} \rightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{5}+\mathrm{NaI}\) is known as
1 Grignard's synthesis
2 Kolbe's synthesis
3 Wurtz synthesis
4 Williamson's synthesis
Explanation:
Williamson's synthesis is a method for the preparation of sample and mixed ether. It involves the heating of alkyl haliders with sodium or potassium alkoxides. \(\mathrm{RONa}+\mathrm{R} \text { 'X } \rightarrow \text { ROR'+NaX }\)
KCET - 2006
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322954
Williamson's synthesis of preparing dimethyl ether is a/an:
322952
Statement A : Statement B : Alkoxides are not only nucleophiles but also the strong base, so they can react with alkyl halide to form the eliminated product.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both statements are incorrect.
Explanation:
If tertiary alkyl halide is used, an alkene is the only reaction product and no ether is formed. It is because alkoxides are not only nucleophiles but also the strong bases. They react with alkyl halides leading to elimination reactions.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322953
The reaction, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{ONa}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I} \rightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{5}+\mathrm{NaI}\) is known as
1 Grignard's synthesis
2 Kolbe's synthesis
3 Wurtz synthesis
4 Williamson's synthesis
Explanation:
Williamson's synthesis is a method for the preparation of sample and mixed ether. It involves the heating of alkyl haliders with sodium or potassium alkoxides. \(\mathrm{RONa}+\mathrm{R} \text { 'X } \rightarrow \text { ROR'+NaX }\)
KCET - 2006
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322954
Williamson's synthesis of preparing dimethyl ether is a/an:
NEET Test Series from KOTA - 10 Papers In MS WORD
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CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322952
Statement A : Statement B : Alkoxides are not only nucleophiles but also the strong base, so they can react with alkyl halide to form the eliminated product.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both statements are incorrect.
Explanation:
If tertiary alkyl halide is used, an alkene is the only reaction product and no ether is formed. It is because alkoxides are not only nucleophiles but also the strong bases. They react with alkyl halides leading to elimination reactions.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322953
The reaction, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{ONa}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I} \rightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{5}+\mathrm{NaI}\) is known as
1 Grignard's synthesis
2 Kolbe's synthesis
3 Wurtz synthesis
4 Williamson's synthesis
Explanation:
Williamson's synthesis is a method for the preparation of sample and mixed ether. It involves the heating of alkyl haliders with sodium or potassium alkoxides. \(\mathrm{RONa}+\mathrm{R} \text { 'X } \rightarrow \text { ROR'+NaX }\)
KCET - 2006
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322954
Williamson's synthesis of preparing dimethyl ether is a/an:
322952
Statement A : Statement B : Alkoxides are not only nucleophiles but also the strong base, so they can react with alkyl halide to form the eliminated product.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both statements are incorrect.
Explanation:
If tertiary alkyl halide is used, an alkene is the only reaction product and no ether is formed. It is because alkoxides are not only nucleophiles but also the strong bases. They react with alkyl halides leading to elimination reactions.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322953
The reaction, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{ONa}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I} \rightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OC}_{2} \mathrm{H}_{5}+\mathrm{NaI}\) is known as
1 Grignard's synthesis
2 Kolbe's synthesis
3 Wurtz synthesis
4 Williamson's synthesis
Explanation:
Williamson's synthesis is a method for the preparation of sample and mixed ether. It involves the heating of alkyl haliders with sodium or potassium alkoxides. \(\mathrm{RONa}+\mathrm{R} \text { 'X } \rightarrow \text { ROR'+NaX }\)
KCET - 2006
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
322954
Williamson's synthesis of preparing dimethyl ether is a/an:
