Elimination Reactions of Haloalkanes
CHXII10:HALOALKANES AND HALOARENES

322405 The order of reactivity of alkyl halides towards elimination reaction is

1 \(3^{\circ}>2^{\circ}>1^{\circ}\)
2 \({{\rm{2}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{1}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{3}}^{\rm{^\circ }}}\)
3 \(3^{\circ}>1^{\circ}>2^{\circ}\)
4 \(1^{\circ}>2^{\circ}>3^{\circ}\)
CHXII10:HALOALKANES AND HALOARENES

322407 Which one of the following compound will be least susceptible to elimination of hydrogen bromide?

1 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{NO}_{2}\)
2 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CH}_{3}\)
3 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CN}\)
4 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CO}_{2} \mathrm{Et}\)
CHXII10:HALOALKANES AND HALOARENES

322408 1,2-Dibromopropane on treatment with \({\mathrm{X}}\) moles of \({\mathrm{\mathrm{NaNH}_{2}}}\) followed by treatment with \({\mathrm{\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}}}\) gives a pentyne. The value of \({\mathrm{X}}\) is:

1 1
2 2
3 3
4 4
CHXII10:HALOALKANES AND HALOARENES

322409 An unknown alkyl halide (A) reacts with alcoholic \(\mathrm{KOH}\) to produce a hydrocarbon \(\left(\mathrm{C}_{4} \mathrm{H}_{8}\right)\). Ozonolysis of the hydrocarbon affords one mole of propionaldehyde and one mole of formaldehyde. Suggest which organic structure among the following is the correct structure of the above alkyl halide( \(\mathrm{A})\) ?

1 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{Br}\)
2 \(\mathrm{CH}_{3} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
4 \(\mathrm{Br}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{Br}\)
CHXII10:HALOALKANES AND HALOARENES

322410 \({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_2} - {\text{Br}}\xrightarrow{{{\text{Alc}}{\text{.KOH}}}}\) Final product is

1 propene
2 propanol
3 cyclopropane
4 propane-1, 2-diol
CHXII10:HALOALKANES AND HALOARENES

322405 The order of reactivity of alkyl halides towards elimination reaction is

1 \(3^{\circ}>2^{\circ}>1^{\circ}\)
2 \({{\rm{2}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{1}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{3}}^{\rm{^\circ }}}\)
3 \(3^{\circ}>1^{\circ}>2^{\circ}\)
4 \(1^{\circ}>2^{\circ}>3^{\circ}\)
CHXII10:HALOALKANES AND HALOARENES

322407 Which one of the following compound will be least susceptible to elimination of hydrogen bromide?

1 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{NO}_{2}\)
2 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CH}_{3}\)
3 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CN}\)
4 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CO}_{2} \mathrm{Et}\)
CHXII10:HALOALKANES AND HALOARENES

322408 1,2-Dibromopropane on treatment with \({\mathrm{X}}\) moles of \({\mathrm{\mathrm{NaNH}_{2}}}\) followed by treatment with \({\mathrm{\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}}}\) gives a pentyne. The value of \({\mathrm{X}}\) is:

1 1
2 2
3 3
4 4
CHXII10:HALOALKANES AND HALOARENES

322409 An unknown alkyl halide (A) reacts with alcoholic \(\mathrm{KOH}\) to produce a hydrocarbon \(\left(\mathrm{C}_{4} \mathrm{H}_{8}\right)\). Ozonolysis of the hydrocarbon affords one mole of propionaldehyde and one mole of formaldehyde. Suggest which organic structure among the following is the correct structure of the above alkyl halide( \(\mathrm{A})\) ?

1 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{Br}\)
2 \(\mathrm{CH}_{3} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
4 \(\mathrm{Br}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{Br}\)
CHXII10:HALOALKANES AND HALOARENES

322410 \({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_2} - {\text{Br}}\xrightarrow{{{\text{Alc}}{\text{.KOH}}}}\) Final product is

1 propene
2 propanol
3 cyclopropane
4 propane-1, 2-diol
CHXII10:HALOALKANES AND HALOARENES

322405 The order of reactivity of alkyl halides towards elimination reaction is

1 \(3^{\circ}>2^{\circ}>1^{\circ}\)
2 \({{\rm{2}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{1}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{3}}^{\rm{^\circ }}}\)
3 \(3^{\circ}>1^{\circ}>2^{\circ}\)
4 \(1^{\circ}>2^{\circ}>3^{\circ}\)
CHXII10:HALOALKANES AND HALOARENES

322407 Which one of the following compound will be least susceptible to elimination of hydrogen bromide?

1 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{NO}_{2}\)
2 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CH}_{3}\)
3 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CN}\)
4 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CO}_{2} \mathrm{Et}\)
CHXII10:HALOALKANES AND HALOARENES

322408 1,2-Dibromopropane on treatment with \({\mathrm{X}}\) moles of \({\mathrm{\mathrm{NaNH}_{2}}}\) followed by treatment with \({\mathrm{\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}}}\) gives a pentyne. The value of \({\mathrm{X}}\) is:

1 1
2 2
3 3
4 4
CHXII10:HALOALKANES AND HALOARENES

322409 An unknown alkyl halide (A) reacts with alcoholic \(\mathrm{KOH}\) to produce a hydrocarbon \(\left(\mathrm{C}_{4} \mathrm{H}_{8}\right)\). Ozonolysis of the hydrocarbon affords one mole of propionaldehyde and one mole of formaldehyde. Suggest which organic structure among the following is the correct structure of the above alkyl halide( \(\mathrm{A})\) ?

1 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{Br}\)
2 \(\mathrm{CH}_{3} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
4 \(\mathrm{Br}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{Br}\)
CHXII10:HALOALKANES AND HALOARENES

322410 \({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_2} - {\text{Br}}\xrightarrow{{{\text{Alc}}{\text{.KOH}}}}\) Final product is

1 propene
2 propanol
3 cyclopropane
4 propane-1, 2-diol
CHXII10:HALOALKANES AND HALOARENES

322405 The order of reactivity of alkyl halides towards elimination reaction is

1 \(3^{\circ}>2^{\circ}>1^{\circ}\)
2 \({{\rm{2}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{1}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{3}}^{\rm{^\circ }}}\)
3 \(3^{\circ}>1^{\circ}>2^{\circ}\)
4 \(1^{\circ}>2^{\circ}>3^{\circ}\)
CHXII10:HALOALKANES AND HALOARENES

322407 Which one of the following compound will be least susceptible to elimination of hydrogen bromide?

1 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{NO}_{2}\)
2 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CH}_{3}\)
3 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CN}\)
4 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CO}_{2} \mathrm{Et}\)
CHXII10:HALOALKANES AND HALOARENES

322408 1,2-Dibromopropane on treatment with \({\mathrm{X}}\) moles of \({\mathrm{\mathrm{NaNH}_{2}}}\) followed by treatment with \({\mathrm{\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}}}\) gives a pentyne. The value of \({\mathrm{X}}\) is:

1 1
2 2
3 3
4 4
CHXII10:HALOALKANES AND HALOARENES

322409 An unknown alkyl halide (A) reacts with alcoholic \(\mathrm{KOH}\) to produce a hydrocarbon \(\left(\mathrm{C}_{4} \mathrm{H}_{8}\right)\). Ozonolysis of the hydrocarbon affords one mole of propionaldehyde and one mole of formaldehyde. Suggest which organic structure among the following is the correct structure of the above alkyl halide( \(\mathrm{A})\) ?

1 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{Br}\)
2 \(\mathrm{CH}_{3} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
4 \(\mathrm{Br}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{Br}\)
CHXII10:HALOALKANES AND HALOARENES

322410 \({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_2} - {\text{Br}}\xrightarrow{{{\text{Alc}}{\text{.KOH}}}}\) Final product is

1 propene
2 propanol
3 cyclopropane
4 propane-1, 2-diol
CHXII10:HALOALKANES AND HALOARENES

322405 The order of reactivity of alkyl halides towards elimination reaction is

1 \(3^{\circ}>2^{\circ}>1^{\circ}\)
2 \({{\rm{2}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{1}}^{\rm{^\circ }}}{\rm{ > }}{{\rm{3}}^{\rm{^\circ }}}\)
3 \(3^{\circ}>1^{\circ}>2^{\circ}\)
4 \(1^{\circ}>2^{\circ}>3^{\circ}\)
CHXII10:HALOALKANES AND HALOARENES

322407 Which one of the following compound will be least susceptible to elimination of hydrogen bromide?

1 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{NO}_{2}\)
2 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CH}_{3}\)
3 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CN}\)
4 \(\mathrm{Br}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CO}_{2} \mathrm{Et}\)
CHXII10:HALOALKANES AND HALOARENES

322408 1,2-Dibromopropane on treatment with \({\mathrm{X}}\) moles of \({\mathrm{\mathrm{NaNH}_{2}}}\) followed by treatment with \({\mathrm{\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}}}\) gives a pentyne. The value of \({\mathrm{X}}\) is:

1 1
2 2
3 3
4 4
CHXII10:HALOALKANES AND HALOARENES

322409 An unknown alkyl halide (A) reacts with alcoholic \(\mathrm{KOH}\) to produce a hydrocarbon \(\left(\mathrm{C}_{4} \mathrm{H}_{8}\right)\). Ozonolysis of the hydrocarbon affords one mole of propionaldehyde and one mole of formaldehyde. Suggest which organic structure among the following is the correct structure of the above alkyl halide( \(\mathrm{A})\) ?

1 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{3} \mathrm{Br}\)
2 \(\mathrm{CH}_{3} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}(\mathrm{Br}) \mathrm{CH}_{3}\)
4 \(\mathrm{Br}\left(\mathrm{CH}_{2}\right)_{4} \mathrm{Br}\)
CHXII10:HALOALKANES AND HALOARENES

322410 \({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_2} - {\text{Br}}\xrightarrow{{{\text{Alc}}{\text{.KOH}}}}\) Final product is

1 propene
2 propanol
3 cyclopropane
4 propane-1, 2-diol