Werner’s Theory of Coordination Compounds
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CHXII09:COORDINATION COMPOUNDS

322354 An excess of \(\mathrm{AgNO}_{3}\) is added to \(100 \mathrm{~mL}\) of a 0.01 M solution of dichlorotetraaquachromium (III) chloride. The number of moles of \(\mathrm{AgCl}\) precipitated would be

1 0.01
2 0.001
3 0.002
4 0.003
CHXII09:COORDINATION COMPOUNDS

322355 A six coordinate complex of formula \(\mathrm{CrCl}_{3} 6 \mathrm{H}_{2} \mathrm{O}\) has green colour. A \(0.1 \mathrm{M}\) solution of the complex when treated with excess of \(\mathrm{AgNO}_{3}\) gave \(28.7 \mathrm{~g}\) of white precipitate. The formula of the complex would be:

1 \(\left.\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right)\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{CrCl}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5}\right] \mathrm{Cl}_{2} \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[ {{\text{CrC}}{{\text{l}}_{\text{2}}}{{\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)}_{\text{4}}}} \right]{\text{Cl 2}}{{\text{H}}_{\text{2}}}{\text{O}}\)
4 \(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322356 Which of the following will have greatest molar conductance at infinite dilution?

1 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{4}\)
2 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{4}\right]\)
3 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}_{2}\)
4 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322357 On treatment of \(100 \mathrm{~mL}\) of \(0.1 \mathrm{M}\) solution of \(\mathrm{CoCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}\) with exces \(\mathrm{AgNO}_{3} ; 1.2 \times 10^{22}\) ions are precipitated . The complex is :-

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6} \mathrm{Cl}_{2}\right] \mathrm{Cl} \cdot 2 \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right] \cdot 3 \mathrm{H}_{2} \mathrm{O}\)
4 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2} \cdot \mathrm{H}_{2} \mathrm{O}\)
CHXII09:COORDINATION COMPOUNDS

322354 An excess of \(\mathrm{AgNO}_{3}\) is added to \(100 \mathrm{~mL}\) of a 0.01 M solution of dichlorotetraaquachromium (III) chloride. The number of moles of \(\mathrm{AgCl}\) precipitated would be

1 0.01
2 0.001
3 0.002
4 0.003
CHXII09:COORDINATION COMPOUNDS

322355 A six coordinate complex of formula \(\mathrm{CrCl}_{3} 6 \mathrm{H}_{2} \mathrm{O}\) has green colour. A \(0.1 \mathrm{M}\) solution of the complex when treated with excess of \(\mathrm{AgNO}_{3}\) gave \(28.7 \mathrm{~g}\) of white precipitate. The formula of the complex would be:

1 \(\left.\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right)\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{CrCl}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5}\right] \mathrm{Cl}_{2} \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[ {{\text{CrC}}{{\text{l}}_{\text{2}}}{{\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)}_{\text{4}}}} \right]{\text{Cl 2}}{{\text{H}}_{\text{2}}}{\text{O}}\)
4 \(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322356 Which of the following will have greatest molar conductance at infinite dilution?

1 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{4}\)
2 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{4}\right]\)
3 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}_{2}\)
4 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322357 On treatment of \(100 \mathrm{~mL}\) of \(0.1 \mathrm{M}\) solution of \(\mathrm{CoCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}\) with exces \(\mathrm{AgNO}_{3} ; 1.2 \times 10^{22}\) ions are precipitated . The complex is :-

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6} \mathrm{Cl}_{2}\right] \mathrm{Cl} \cdot 2 \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right] \cdot 3 \mathrm{H}_{2} \mathrm{O}\)
4 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2} \cdot \mathrm{H}_{2} \mathrm{O}\)
CHXII09:COORDINATION COMPOUNDS

322354 An excess of \(\mathrm{AgNO}_{3}\) is added to \(100 \mathrm{~mL}\) of a 0.01 M solution of dichlorotetraaquachromium (III) chloride. The number of moles of \(\mathrm{AgCl}\) precipitated would be

1 0.01
2 0.001
3 0.002
4 0.003
CHXII09:COORDINATION COMPOUNDS

322355 A six coordinate complex of formula \(\mathrm{CrCl}_{3} 6 \mathrm{H}_{2} \mathrm{O}\) has green colour. A \(0.1 \mathrm{M}\) solution of the complex when treated with excess of \(\mathrm{AgNO}_{3}\) gave \(28.7 \mathrm{~g}\) of white precipitate. The formula of the complex would be:

1 \(\left.\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right)\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{CrCl}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5}\right] \mathrm{Cl}_{2} \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[ {{\text{CrC}}{{\text{l}}_{\text{2}}}{{\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)}_{\text{4}}}} \right]{\text{Cl 2}}{{\text{H}}_{\text{2}}}{\text{O}}\)
4 \(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322356 Which of the following will have greatest molar conductance at infinite dilution?

1 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{4}\)
2 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{4}\right]\)
3 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}_{2}\)
4 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322357 On treatment of \(100 \mathrm{~mL}\) of \(0.1 \mathrm{M}\) solution of \(\mathrm{CoCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}\) with exces \(\mathrm{AgNO}_{3} ; 1.2 \times 10^{22}\) ions are precipitated . The complex is :-

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6} \mathrm{Cl}_{2}\right] \mathrm{Cl} \cdot 2 \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right] \cdot 3 \mathrm{H}_{2} \mathrm{O}\)
4 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2} \cdot \mathrm{H}_{2} \mathrm{O}\)
CHXII09:COORDINATION COMPOUNDS

322354 An excess of \(\mathrm{AgNO}_{3}\) is added to \(100 \mathrm{~mL}\) of a 0.01 M solution of dichlorotetraaquachromium (III) chloride. The number of moles of \(\mathrm{AgCl}\) precipitated would be

1 0.01
2 0.001
3 0.002
4 0.003
CHXII09:COORDINATION COMPOUNDS

322355 A six coordinate complex of formula \(\mathrm{CrCl}_{3} 6 \mathrm{H}_{2} \mathrm{O}\) has green colour. A \(0.1 \mathrm{M}\) solution of the complex when treated with excess of \(\mathrm{AgNO}_{3}\) gave \(28.7 \mathrm{~g}\) of white precipitate. The formula of the complex would be:

1 \(\left.\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right)\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{CrCl}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5}\right] \mathrm{Cl}_{2} \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[ {{\text{CrC}}{{\text{l}}_{\text{2}}}{{\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)}_{\text{4}}}} \right]{\text{Cl 2}}{{\text{H}}_{\text{2}}}{\text{O}}\)
4 \(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322356 Which of the following will have greatest molar conductance at infinite dilution?

1 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{4}\)
2 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{4}\right]\)
3 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}_{2}\)
4 \(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{3}\)
CHXII09:COORDINATION COMPOUNDS

322357 On treatment of \(100 \mathrm{~mL}\) of \(0.1 \mathrm{M}\) solution of \(\mathrm{CoCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}\) with exces \(\mathrm{AgNO}_{3} ; 1.2 \times 10^{22}\) ions are precipitated . The complex is :-

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
2 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6} \mathrm{Cl}_{2}\right] \mathrm{Cl} \cdot 2 \mathrm{H}_{2} \mathrm{O}\)
3 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right] \cdot 3 \mathrm{H}_{2} \mathrm{O}\)
4 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2} \cdot \mathrm{H}_{2} \mathrm{O}\)