Valence Bond Theory
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CHXII09:COORDINATION COMPOUNDS

322255 Match the column I with column II and choose the correct option.
Column I
Column II
A
Tetracarbonyl nickel (0)
P
Octahedral
B
Pentacarbonly iron (0)
Q
Trigonal bipyramidal
C
Hexacarbonyl chromium (0)
R
Tetrahedral

1 \({\text{A - P, B - Q, C - R}}\)
2 \({\text{A - R, B - Q, C - P}}\)
3 \({\text{A - Q, B - R, C - P}}\)
4 \({\text{A - Q, B - P, C - R}}\)
CHXII09:COORDINATION COMPOUNDS

322256 Identify the following species in which \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation is shown by central atom.

1 \(\mathrm{BrF}_{5}\)
2 \(\mathrm{SF}_{6}\)
3 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
4 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
JEE - 2024
CHXII09:COORDINATION COMPOUNDS

322257 Read the Statement - A and Statement - B carefully to mark the correct options given below
Statement A :
\({\mathrm{\mathrm{PF}_{5}}}\) and \({\mathrm{\mathrm{BrF}_{5}}}\) both exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}}}\) hybridisation.
Statement B :
Both \({\mathrm{\mathrm{SF}_{6}}}\) and \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}}}\) exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}^{2}}}\) hybridisation.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
JEE Main - 2024
CHXII09:COORDINATION COMPOUNDS

322258 Match Column I with Column II.
supporting img

1 A - P, B - Q , C - R, D - S
2 A - Q , B - P, C - R, D - S
3 A - P, B - Q , C - S, D - R
4 A - Q , B - P, C - S, D - R
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322259 An octahedral complex is formed when hybrid orbitals of the following type are involved

1 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
2 \(\mathrm{sp}^{2} \mathrm{~d}^{2}\)
3 \(\mathrm{sp}^{3}\)
4 \(\mathrm{dsp}^{2}\)
KCET - 2008
NEET DIGITAL LIBRARY
CHXII09:COORDINATION COMPOUNDS

322255 Match the column I with column II and choose the correct option.
Column I
Column II
A
Tetracarbonyl nickel (0)
P
Octahedral
B
Pentacarbonly iron (0)
Q
Trigonal bipyramidal
C
Hexacarbonyl chromium (0)
R
Tetrahedral

1 \({\text{A - P, B - Q, C - R}}\)
2 \({\text{A - R, B - Q, C - P}}\)
3 \({\text{A - Q, B - R, C - P}}\)
4 \({\text{A - Q, B - P, C - R}}\)
CHXII09:COORDINATION COMPOUNDS

322256 Identify the following species in which \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation is shown by central atom.

1 \(\mathrm{BrF}_{5}\)
2 \(\mathrm{SF}_{6}\)
3 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
4 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
JEE - 2024
CHXII09:COORDINATION COMPOUNDS

322257 Read the Statement - A and Statement - B carefully to mark the correct options given below
Statement A :
\({\mathrm{\mathrm{PF}_{5}}}\) and \({\mathrm{\mathrm{BrF}_{5}}}\) both exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}}}\) hybridisation.
Statement B :
Both \({\mathrm{\mathrm{SF}_{6}}}\) and \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}}}\) exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}^{2}}}\) hybridisation.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
JEE Main - 2024
CHXII09:COORDINATION COMPOUNDS

322258 Match Column I with Column II.
supporting img

1 A - P, B - Q , C - R, D - S
2 A - Q , B - P, C - R, D - S
3 A - P, B - Q , C - S, D - R
4 A - Q , B - P, C - S, D - R
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322259 An octahedral complex is formed when hybrid orbitals of the following type are involved

1 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
2 \(\mathrm{sp}^{2} \mathrm{~d}^{2}\)
3 \(\mathrm{sp}^{3}\)
4 \(\mathrm{dsp}^{2}\)
KCET - 2008
Join With Us for More Updates
CHXII09:COORDINATION COMPOUNDS

322255 Match the column I with column II and choose the correct option.
Column I
Column II
A
Tetracarbonyl nickel (0)
P
Octahedral
B
Pentacarbonly iron (0)
Q
Trigonal bipyramidal
C
Hexacarbonyl chromium (0)
R
Tetrahedral

1 \({\text{A - P, B - Q, C - R}}\)
2 \({\text{A - R, B - Q, C - P}}\)
3 \({\text{A - Q, B - R, C - P}}\)
4 \({\text{A - Q, B - P, C - R}}\)
CHXII09:COORDINATION COMPOUNDS

322256 Identify the following species in which \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation is shown by central atom.

1 \(\mathrm{BrF}_{5}\)
2 \(\mathrm{SF}_{6}\)
3 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
4 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
JEE - 2024
CHXII09:COORDINATION COMPOUNDS

322257 Read the Statement - A and Statement - B carefully to mark the correct options given below
Statement A :
\({\mathrm{\mathrm{PF}_{5}}}\) and \({\mathrm{\mathrm{BrF}_{5}}}\) both exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}}}\) hybridisation.
Statement B :
Both \({\mathrm{\mathrm{SF}_{6}}}\) and \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}}}\) exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}^{2}}}\) hybridisation.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
JEE Main - 2024
CHXII09:COORDINATION COMPOUNDS

322258 Match Column I with Column II.
supporting img

1 A - P, B - Q , C - R, D - S
2 A - Q , B - P, C - R, D - S
3 A - P, B - Q , C - S, D - R
4 A - Q , B - P, C - S, D - R
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322259 An octahedral complex is formed when hybrid orbitals of the following type are involved

1 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
2 \(\mathrm{sp}^{2} \mathrm{~d}^{2}\)
3 \(\mathrm{sp}^{3}\)
4 \(\mathrm{dsp}^{2}\)
KCET - 2008
For More Updates join with Us
CHXII09:COORDINATION COMPOUNDS

322255 Match the column I with column II and choose the correct option.
Column I
Column II
A
Tetracarbonyl nickel (0)
P
Octahedral
B
Pentacarbonly iron (0)
Q
Trigonal bipyramidal
C
Hexacarbonyl chromium (0)
R
Tetrahedral

1 \({\text{A - P, B - Q, C - R}}\)
2 \({\text{A - R, B - Q, C - P}}\)
3 \({\text{A - Q, B - R, C - P}}\)
4 \({\text{A - Q, B - P, C - R}}\)
CHXII09:COORDINATION COMPOUNDS

322256 Identify the following species in which \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation is shown by central atom.

1 \(\mathrm{BrF}_{5}\)
2 \(\mathrm{SF}_{6}\)
3 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
4 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
JEE - 2024
CHXII09:COORDINATION COMPOUNDS

322257 Read the Statement - A and Statement - B carefully to mark the correct options given below
Statement A :
\({\mathrm{\mathrm{PF}_{5}}}\) and \({\mathrm{\mathrm{BrF}_{5}}}\) both exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}}}\) hybridisation.
Statement B :
Both \({\mathrm{\mathrm{SF}_{6}}}\) and \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}}}\) exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}^{2}}}\) hybridisation.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
JEE Main - 2024
CHXII09:COORDINATION COMPOUNDS

322258 Match Column I with Column II.
supporting img

1 A - P, B - Q , C - R, D - S
2 A - Q , B - P, C - R, D - S
3 A - P, B - Q , C - S, D - R
4 A - Q , B - P, C - S, D - R
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322259 An octahedral complex is formed when hybrid orbitals of the following type are involved

1 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
2 \(\mathrm{sp}^{2} \mathrm{~d}^{2}\)
3 \(\mathrm{sp}^{3}\)
4 \(\mathrm{dsp}^{2}\)
KCET - 2008
NEET DIGITAL LIBRARY
CHXII09:COORDINATION COMPOUNDS

322255 Match the column I with column II and choose the correct option.
Column I
Column II
A
Tetracarbonyl nickel (0)
P
Octahedral
B
Pentacarbonly iron (0)
Q
Trigonal bipyramidal
C
Hexacarbonyl chromium (0)
R
Tetrahedral

1 \({\text{A - P, B - Q, C - R}}\)
2 \({\text{A - R, B - Q, C - P}}\)
3 \({\text{A - Q, B - R, C - P}}\)
4 \({\text{A - Q, B - P, C - R}}\)
CHXII09:COORDINATION COMPOUNDS

322256 Identify the following species in which \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation is shown by central atom.

1 \(\mathrm{BrF}_{5}\)
2 \(\mathrm{SF}_{6}\)
3 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
4 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
JEE - 2024
CHXII09:COORDINATION COMPOUNDS

322257 Read the Statement - A and Statement - B carefully to mark the correct options given below
Statement A :
\({\mathrm{\mathrm{PF}_{5}}}\) and \({\mathrm{\mathrm{BrF}_{5}}}\) both exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}}}\) hybridisation.
Statement B :
Both \({\mathrm{\mathrm{SF}_{6}}}\) and \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}}}\) exhibit \({\mathrm{\mathrm{sp}^{3} \mathrm{~d}^{2}}}\) hybridisation.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
JEE Main - 2024
CHXII09:COORDINATION COMPOUNDS

322258 Match Column I with Column II.
supporting img

1 A - P, B - Q , C - R, D - S
2 A - Q , B - P, C - R, D - S
3 A - P, B - Q , C - S, D - R
4 A - Q , B - P, C - S, D - R
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322259 An octahedral complex is formed when hybrid orbitals of the following type are involved

1 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
2 \(\mathrm{sp}^{2} \mathrm{~d}^{2}\)
3 \(\mathrm{sp}^{3}\)
4 \(\mathrm{dsp}^{2}\)
KCET - 2008