321991
\(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\) and \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) are known as
1 ionisation isomers
2 coordination isomers
3 linkage isomers
4 polymerisation isomers
Explanation:
The ligands are interchanged in both the anionic and cationic entities of different metal ions present in a complex, so they are called coordination isomers.
CHXII09:COORDINATION COMPOUNDS
321992
The type of isomerism shown by \(\left[\mathrm{Co}(e n)_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl}\) and \(\left[\mathrm{Co}(\text { en })_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \text { is }\)
1 Ionization
2 Coordination
3 Linkage
4 All of these
Explanation:
On ionisation different species are formed to show ionisation isomerism: \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS})_{2}\right]+\mathrm{Cl}^{-}\) \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS}) \mathrm{Cl}\right]+\mathrm{NCS}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321993
Compounds \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\), shows the following type of isomerism.
1 Hydrate isomerism
2 Ionisation isomerism
3 Linkage isomerism
4 Coordination position isomerism
Explanation:
Since, the complexes \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and\(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\) have the same molecular formula but on ionisation they give different ions, they exhibit ionisation isomerism. \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2} \rightleftharpoons\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Br}^{-}\) \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2} \rightleftharpoons\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Cl}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321994
Coordination isomerism is caused by the interchange of ligands between the
1 Cis and trans structures
2 Complex cation and complex anion
3 Inner sphere and outer sphere
4 Low oxidation and higher oxidation states
Explanation:
Coordination isomerism is caused by the interchange of ligands between complex cation and complex anion.
321991
\(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\) and \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) are known as
1 ionisation isomers
2 coordination isomers
3 linkage isomers
4 polymerisation isomers
Explanation:
The ligands are interchanged in both the anionic and cationic entities of different metal ions present in a complex, so they are called coordination isomers.
CHXII09:COORDINATION COMPOUNDS
321992
The type of isomerism shown by \(\left[\mathrm{Co}(e n)_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl}\) and \(\left[\mathrm{Co}(\text { en })_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \text { is }\)
1 Ionization
2 Coordination
3 Linkage
4 All of these
Explanation:
On ionisation different species are formed to show ionisation isomerism: \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS})_{2}\right]+\mathrm{Cl}^{-}\) \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS}) \mathrm{Cl}\right]+\mathrm{NCS}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321993
Compounds \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\), shows the following type of isomerism.
1 Hydrate isomerism
2 Ionisation isomerism
3 Linkage isomerism
4 Coordination position isomerism
Explanation:
Since, the complexes \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and\(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\) have the same molecular formula but on ionisation they give different ions, they exhibit ionisation isomerism. \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2} \rightleftharpoons\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Br}^{-}\) \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2} \rightleftharpoons\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Cl}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321994
Coordination isomerism is caused by the interchange of ligands between the
1 Cis and trans structures
2 Complex cation and complex anion
3 Inner sphere and outer sphere
4 Low oxidation and higher oxidation states
Explanation:
Coordination isomerism is caused by the interchange of ligands between complex cation and complex anion.
321991
\(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\) and \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) are known as
1 ionisation isomers
2 coordination isomers
3 linkage isomers
4 polymerisation isomers
Explanation:
The ligands are interchanged in both the anionic and cationic entities of different metal ions present in a complex, so they are called coordination isomers.
CHXII09:COORDINATION COMPOUNDS
321992
The type of isomerism shown by \(\left[\mathrm{Co}(e n)_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl}\) and \(\left[\mathrm{Co}(\text { en })_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \text { is }\)
1 Ionization
2 Coordination
3 Linkage
4 All of these
Explanation:
On ionisation different species are formed to show ionisation isomerism: \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS})_{2}\right]+\mathrm{Cl}^{-}\) \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS}) \mathrm{Cl}\right]+\mathrm{NCS}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321993
Compounds \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\), shows the following type of isomerism.
1 Hydrate isomerism
2 Ionisation isomerism
3 Linkage isomerism
4 Coordination position isomerism
Explanation:
Since, the complexes \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and\(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\) have the same molecular formula but on ionisation they give different ions, they exhibit ionisation isomerism. \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2} \rightleftharpoons\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Br}^{-}\) \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2} \rightleftharpoons\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Cl}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321994
Coordination isomerism is caused by the interchange of ligands between the
1 Cis and trans structures
2 Complex cation and complex anion
3 Inner sphere and outer sphere
4 Low oxidation and higher oxidation states
Explanation:
Coordination isomerism is caused by the interchange of ligands between complex cation and complex anion.
321991
\(\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\) and \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) are known as
1 ionisation isomers
2 coordination isomers
3 linkage isomers
4 polymerisation isomers
Explanation:
The ligands are interchanged in both the anionic and cationic entities of different metal ions present in a complex, so they are called coordination isomers.
CHXII09:COORDINATION COMPOUNDS
321992
The type of isomerism shown by \(\left[\mathrm{Co}(e n)_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl}\) and \(\left[\mathrm{Co}(\text { en })_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \text { is }\)
1 Ionization
2 Coordination
3 Linkage
4 All of these
Explanation:
On ionisation different species are formed to show ionisation isomerism: \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS})_{2}\right] \mathrm{Cl} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS})_{2}\right]+\mathrm{Cl}^{-}\) \(\left[\mathrm{Co}(\mathrm{en})_{2}(\mathrm{NCS}) \mathrm{Cl}\right] \mathrm{NCS} \rightleftharpoons\left[\mathrm{Co}\left(\mathrm{en}_{2}\right)(\mathrm{NCS}) \mathrm{Cl}\right]+\mathrm{NCS}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321993
Compounds \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\), shows the following type of isomerism.
1 Hydrate isomerism
2 Ionisation isomerism
3 Linkage isomerism
4 Coordination position isomerism
Explanation:
Since, the complexes \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2}\) and\(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2}\) have the same molecular formula but on ionisation they give different ions, they exhibit ionisation isomerism. \(\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Br}_{2} \rightleftharpoons\left[\mathrm{PtCl}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Br}^{-}\) \(\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right] \mathrm{Cl}_{2} \rightleftharpoons\left[\mathrm{PtBr}_{2}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}+2 \mathrm{Cl}^{-}\)
CHXII09:COORDINATION COMPOUNDS
321994
Coordination isomerism is caused by the interchange of ligands between the
1 Cis and trans structures
2 Complex cation and complex anion
3 Inner sphere and outer sphere
4 Low oxidation and higher oxidation states
Explanation:
Coordination isomerism is caused by the interchange of ligands between complex cation and complex anion.
