321687
Read the Assertion and Reason carefully and mark correct options. Assertion : 5 f electrons can participate in bonding to a far greater extent than 4 f electrons. Reason : 5 f orbitals are not as buried as 4f orbitals.
1 Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
2 Assertion is false but Reason is true.
3 Assertion is true but Reason is false.
4 Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
Explanation:
The 5 f electrons are comparatively less attracted by the nucleus than the 4 f electrons. Thus, they can better participate in bonding.
JEE - 2023
CHXII08:THE D- & F-BLOCK ELEMENTS
321688
Which of the following is the approximate radius of Hf (in \( \mathop {\rm{A}}^{\circ} \) unit), if radius of Zr is 1.45 \( \mathop {\rm{A}}^{\circ} \) ?
1 0.45 \( \mathop {\rm{A}}^{\circ} \)
2 1.32 \( \mathop {\rm{A}}^{\circ} \)
3 1.44 \( \mathop {\rm{A}}^{\circ} \)
4 2.45 \( \mathop {\rm{A}}^{\circ} \)
Explanation:
Due to Lanthanoid contraction, 4d - series \((\mathrm{Zr})\) and 5d- series (Hf) will have almost same atomic radius.
CHXII08:THE D- & F-BLOCK ELEMENTS
321689
The lanthanide contraction is due to
1 perfect shielding of 4f-electrons
2 imperfect shielding of 4f -electrons
3 perfect shielding of 3d-electrons
4 imperfect shielding of 3d -electrons.
Explanation:
Lanthanide contraction is due to poor shielding of 4f-electrons.
321687
Read the Assertion and Reason carefully and mark correct options. Assertion : 5 f electrons can participate in bonding to a far greater extent than 4 f electrons. Reason : 5 f orbitals are not as buried as 4f orbitals.
1 Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
2 Assertion is false but Reason is true.
3 Assertion is true but Reason is false.
4 Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
Explanation:
The 5 f electrons are comparatively less attracted by the nucleus than the 4 f electrons. Thus, they can better participate in bonding.
JEE - 2023
CHXII08:THE D- & F-BLOCK ELEMENTS
321688
Which of the following is the approximate radius of Hf (in \( \mathop {\rm{A}}^{\circ} \) unit), if radius of Zr is 1.45 \( \mathop {\rm{A}}^{\circ} \) ?
1 0.45 \( \mathop {\rm{A}}^{\circ} \)
2 1.32 \( \mathop {\rm{A}}^{\circ} \)
3 1.44 \( \mathop {\rm{A}}^{\circ} \)
4 2.45 \( \mathop {\rm{A}}^{\circ} \)
Explanation:
Due to Lanthanoid contraction, 4d - series \((\mathrm{Zr})\) and 5d- series (Hf) will have almost same atomic radius.
CHXII08:THE D- & F-BLOCK ELEMENTS
321689
The lanthanide contraction is due to
1 perfect shielding of 4f-electrons
2 imperfect shielding of 4f -electrons
3 perfect shielding of 3d-electrons
4 imperfect shielding of 3d -electrons.
Explanation:
Lanthanide contraction is due to poor shielding of 4f-electrons.
321687
Read the Assertion and Reason carefully and mark correct options. Assertion : 5 f electrons can participate in bonding to a far greater extent than 4 f electrons. Reason : 5 f orbitals are not as buried as 4f orbitals.
1 Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
2 Assertion is false but Reason is true.
3 Assertion is true but Reason is false.
4 Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
Explanation:
The 5 f electrons are comparatively less attracted by the nucleus than the 4 f electrons. Thus, they can better participate in bonding.
JEE - 2023
CHXII08:THE D- & F-BLOCK ELEMENTS
321688
Which of the following is the approximate radius of Hf (in \( \mathop {\rm{A}}^{\circ} \) unit), if radius of Zr is 1.45 \( \mathop {\rm{A}}^{\circ} \) ?
1 0.45 \( \mathop {\rm{A}}^{\circ} \)
2 1.32 \( \mathop {\rm{A}}^{\circ} \)
3 1.44 \( \mathop {\rm{A}}^{\circ} \)
4 2.45 \( \mathop {\rm{A}}^{\circ} \)
Explanation:
Due to Lanthanoid contraction, 4d - series \((\mathrm{Zr})\) and 5d- series (Hf) will have almost same atomic radius.
CHXII08:THE D- & F-BLOCK ELEMENTS
321689
The lanthanide contraction is due to
1 perfect shielding of 4f-electrons
2 imperfect shielding of 4f -electrons
3 perfect shielding of 3d-electrons
4 imperfect shielding of 3d -electrons.
Explanation:
Lanthanide contraction is due to poor shielding of 4f-electrons.
321687
Read the Assertion and Reason carefully and mark correct options. Assertion : 5 f electrons can participate in bonding to a far greater extent than 4 f electrons. Reason : 5 f orbitals are not as buried as 4f orbitals.
1 Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
2 Assertion is false but Reason is true.
3 Assertion is true but Reason is false.
4 Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
Explanation:
The 5 f electrons are comparatively less attracted by the nucleus than the 4 f electrons. Thus, they can better participate in bonding.
JEE - 2023
CHXII08:THE D- & F-BLOCK ELEMENTS
321688
Which of the following is the approximate radius of Hf (in \( \mathop {\rm{A}}^{\circ} \) unit), if radius of Zr is 1.45 \( \mathop {\rm{A}}^{\circ} \) ?
1 0.45 \( \mathop {\rm{A}}^{\circ} \)
2 1.32 \( \mathop {\rm{A}}^{\circ} \)
3 1.44 \( \mathop {\rm{A}}^{\circ} \)
4 2.45 \( \mathop {\rm{A}}^{\circ} \)
Explanation:
Due to Lanthanoid contraction, 4d - series \((\mathrm{Zr})\) and 5d- series (Hf) will have almost same atomic radius.
CHXII08:THE D- & F-BLOCK ELEMENTS
321689
The lanthanide contraction is due to
1 perfect shielding of 4f-electrons
2 imperfect shielding of 4f -electrons
3 perfect shielding of 3d-electrons
4 imperfect shielding of 3d -electrons.
Explanation:
Lanthanide contraction is due to poor shielding of 4f-electrons.