Explanation:
\(\mathrm{\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}+4 \mathrm{NaCl}+6 \mathrm{H}_{2} \mathrm{SO}_{4} \rightarrow}\) \(\mathrm{2 \mathrm{CrO}_{2} \mathrm{Cl}_{2}+4 \mathrm{NaHSO}_{4}+2 \mathrm{KHSO}_{4}+3 \mathrm{H}_{2} \mathrm{O}}\)
Red vapours
\(\mathrm{4 \mathrm{NaOH}+\mathrm{CrO}_{2} \mathrm{Cl}_{2} \rightarrow \mathrm{Na}_{2} \mathrm{CrO}_{4}+2 \mathrm{NaCl}+2 \mathrm{H}_{2} \mathrm{O}}\) Yellow soln
\({\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{Cr}}{{\rm{O}}_{\rm{4}}}{\rm{ + (C}}{{\rm{H}}_{\rm{3}}}{\rm{COO}}{{\rm{)}}_{\rm{2}}}{\rm{Pb}} \to \mathop {{\rm{PbCr}}{{\rm{O}}_{\rm{4}}}}\limits_{{\rm{yellow}}\,\,{\rm{ppt}}{\rm{.}}} {\rm{ + }}\)
\(\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\rm{2C}}{{\rm{H}}_{\rm{3}}}{\rm{COONa}}\)