CHXII06:GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS
321052
Roasted gold ore \( + {\text{C}}{{\text{N}}^ - } + {{\text{H}}_2}{\text{O}}\xrightarrow{{{{\text{O}}_2}}}[{\text{X}}] + {\text{O}}{{\text{H}}^ - }\)
\([{\rm{X}}] + {\rm{Zn}} \to [{\rm{Y}}] + {\rm{Au}}]\) [X] and [Y] are
1 \({\rm{X}} = {\left[ {{\rm{Au}}{{({\rm{CN}})}_2}} \right]^ - };{\rm{Y}} = {\left[ {{\rm{Zn}}{{({\rm{CN}})}_4}} \right]^{2 - }}\)
2 \({\rm{X}} = {\left[ {{\rm{Au}}{{({\rm{CN}})}_4}} \right]^{3 - }};{\rm{Y}} = {\left[ {{\rm{Zn}}{{({\rm{CN}})}_4}} \right]^{2 - }}\)
3 \({\rm{X}} = {\left[ {{\rm{Au}}{{({\rm{CN}})}_2}} \right]^ - };{\rm{Y}} = {\left[ {{\rm{Zn}}{{({\rm{CN}})}_6}} \right]^{4 - }}\)
4 \({\rm{X}} = {\left[ {{\rm{Au}}{{({\rm{CN}})}_4}} \right]^{3 - }};{\rm{Y}} = {\left[ {{\rm{Zn}}{{({\rm{CN}})}_6}} \right]^{4 - }}\)
Explanation:
\({\text{2Au}} + 4{\text{C}}{{\text{N}}^ - } + {{\text{H}}_{\text{2}}}{\text{O}} + \frac{1}{2}{{\text{O}}_2} \to \) \(2\mathop {{{\left[ {{\text{Au}}{{({\text{CN}})}_2}} \right]}^ - }}\limits_{({\text{X}})} + 2{\text{O}}{{\text{H}}^ - }\)
\(2{\left[ {{\text{Au}}{{({\text{CN}})}_2}} \right]^ - } + {\text{Zn}} \to \mathop {{{\left[ {{\text{Zn}}{{({\text{CN}})}_4}} \right]}^{2 - }}}\limits_{({\text{Y}})} + 2{\text{Au}}\)