Vapour Pressure of Liquid Solutions
CHXII02:SOLUTIONS

319510 An ideal mixture of liquids A and B with 2 mol of A and 2 mol B has a total vapour pressure of 1 atm at a certain temperature. Another mixture with 1 mol of A and 3 mol of B has a vapour pressure greater than 1 atm. But if 4 mol of C are added to the second mixture, the vapour pressure come down to 1 atm. Vapour pressure of C, \({\rm{P}}_{\rm{C}}^{\rm{o}}{\rm{ = 8}}{\mkern 1mu} {\mkern 1mu} {\rm{atm}}\). Calculate the vapour pressure of pure A and pure B.

1 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.7 atm}}\)
2 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.2 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
3 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
4 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm}}\)
CHXII02:SOLUTIONS

319511 The vapour pressure of pure liquid ‘A’ at \({\rm{310^\circ C}}\) is 120 torr. The vapour pressure of this liquid in solution with liquid B is 72 torr. Calculate the mole fraction of ‘A’ in solution if the mixture obeys Raoult’s law.

1 0.06
2 0.9
3 0.3
4 0.6
CHXII02:SOLUTIONS

319512 Benzene and Napthalene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and naphthalene at 300 K are 50.71 mm of Hg and 32.06 mm of Hg respectively. What will be the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene?

1 0.35
2 0.0675
3 0.675
4 0.5
CHXII02:SOLUTIONS

319513 Which of the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene is correct? Assume that the temperature is constant at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\). (Given, vapour pressure data at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\), benzene = 12.8 kPa, toluene = 3.85 kPa)

1 The vapour will contain a higher percentage of toluene.
2 The vapour will contain equal amounts of benzene and toluene.
3 The vapour will contain a higher percentage of benzene.
4 Not enough information is given to make a prediction.
CHXII02:SOLUTIONS

319510 An ideal mixture of liquids A and B with 2 mol of A and 2 mol B has a total vapour pressure of 1 atm at a certain temperature. Another mixture with 1 mol of A and 3 mol of B has a vapour pressure greater than 1 atm. But if 4 mol of C are added to the second mixture, the vapour pressure come down to 1 atm. Vapour pressure of C, \({\rm{P}}_{\rm{C}}^{\rm{o}}{\rm{ = 8}}{\mkern 1mu} {\mkern 1mu} {\rm{atm}}\). Calculate the vapour pressure of pure A and pure B.

1 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.7 atm}}\)
2 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.2 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
3 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
4 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm}}\)
CHXII02:SOLUTIONS

319511 The vapour pressure of pure liquid ‘A’ at \({\rm{310^\circ C}}\) is 120 torr. The vapour pressure of this liquid in solution with liquid B is 72 torr. Calculate the mole fraction of ‘A’ in solution if the mixture obeys Raoult’s law.

1 0.06
2 0.9
3 0.3
4 0.6
CHXII02:SOLUTIONS

319512 Benzene and Napthalene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and naphthalene at 300 K are 50.71 mm of Hg and 32.06 mm of Hg respectively. What will be the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene?

1 0.35
2 0.0675
3 0.675
4 0.5
CHXII02:SOLUTIONS

319513 Which of the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene is correct? Assume that the temperature is constant at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\). (Given, vapour pressure data at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\), benzene = 12.8 kPa, toluene = 3.85 kPa)

1 The vapour will contain a higher percentage of toluene.
2 The vapour will contain equal amounts of benzene and toluene.
3 The vapour will contain a higher percentage of benzene.
4 Not enough information is given to make a prediction.
CHXII02:SOLUTIONS

319510 An ideal mixture of liquids A and B with 2 mol of A and 2 mol B has a total vapour pressure of 1 atm at a certain temperature. Another mixture with 1 mol of A and 3 mol of B has a vapour pressure greater than 1 atm. But if 4 mol of C are added to the second mixture, the vapour pressure come down to 1 atm. Vapour pressure of C, \({\rm{P}}_{\rm{C}}^{\rm{o}}{\rm{ = 8}}{\mkern 1mu} {\mkern 1mu} {\rm{atm}}\). Calculate the vapour pressure of pure A and pure B.

1 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.7 atm}}\)
2 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.2 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
3 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
4 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm}}\)
CHXII02:SOLUTIONS

319511 The vapour pressure of pure liquid ‘A’ at \({\rm{310^\circ C}}\) is 120 torr. The vapour pressure of this liquid in solution with liquid B is 72 torr. Calculate the mole fraction of ‘A’ in solution if the mixture obeys Raoult’s law.

1 0.06
2 0.9
3 0.3
4 0.6
CHXII02:SOLUTIONS

319512 Benzene and Napthalene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and naphthalene at 300 K are 50.71 mm of Hg and 32.06 mm of Hg respectively. What will be the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene?

1 0.35
2 0.0675
3 0.675
4 0.5
CHXII02:SOLUTIONS

319513 Which of the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene is correct? Assume that the temperature is constant at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\). (Given, vapour pressure data at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\), benzene = 12.8 kPa, toluene = 3.85 kPa)

1 The vapour will contain a higher percentage of toluene.
2 The vapour will contain equal amounts of benzene and toluene.
3 The vapour will contain a higher percentage of benzene.
4 Not enough information is given to make a prediction.
CHXII02:SOLUTIONS

319510 An ideal mixture of liquids A and B with 2 mol of A and 2 mol B has a total vapour pressure of 1 atm at a certain temperature. Another mixture with 1 mol of A and 3 mol of B has a vapour pressure greater than 1 atm. But if 4 mol of C are added to the second mixture, the vapour pressure come down to 1 atm. Vapour pressure of C, \({\rm{P}}_{\rm{C}}^{\rm{o}}{\rm{ = 8}}{\mkern 1mu} {\mkern 1mu} {\rm{atm}}\). Calculate the vapour pressure of pure A and pure B.

1 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.7 atm}}\)
2 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.2 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
3 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm}}\)
4 \({\rm{P}}_{\rm{A}}^{\rm{o}}{\rm{ = 0}}{\rm{.6 atm,P}}_{\rm{B}}^{\rm{o}}{\rm{ = 1}}{\rm{.4 atm}}\)
CHXII02:SOLUTIONS

319511 The vapour pressure of pure liquid ‘A’ at \({\rm{310^\circ C}}\) is 120 torr. The vapour pressure of this liquid in solution with liquid B is 72 torr. Calculate the mole fraction of ‘A’ in solution if the mixture obeys Raoult’s law.

1 0.06
2 0.9
3 0.3
4 0.6
CHXII02:SOLUTIONS

319512 Benzene and Napthalene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and naphthalene at 300 K are 50.71 mm of Hg and 32.06 mm of Hg respectively. What will be the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene?

1 0.35
2 0.0675
3 0.675
4 0.5
CHXII02:SOLUTIONS

319513 Which of the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene is correct? Assume that the temperature is constant at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\). (Given, vapour pressure data at \({\rm{2}}{{\rm{5}}^{\rm{^\circ }}}{\rm{C}}\), benzene = 12.8 kPa, toluene = 3.85 kPa)

1 The vapour will contain a higher percentage of toluene.
2 The vapour will contain equal amounts of benzene and toluene.
3 The vapour will contain a higher percentage of benzene.
4 Not enough information is given to make a prediction.