Abnormal Molar Masses and Van't Hoff Factor
CHXII02:SOLUTIONS

318969 Which among the following colligative properties is useful to determine molar masses of very expensive solutes?

1 Freezing point depression
2 Osmotic pressure
3 Vapour pressure lowering
4 Boiling point elevation
CHXII02:SOLUTIONS

318970 Arrange the following solutions in increasing order of their osmotic pressure.
(i) 34.2 g/litre sucrose
(ii) 60 g/litre of urea
(iii) 90 g/litre of glucose
(iv) 58.5 g/litre of sodium chloride

1 (i) < (iii) < (ii) < (iv)
2 (iii) < (i) < (iv) < (ii)
3 (i) < (iii) < (iv) < (ii)
4 (ii) < (iv) < (i) < (iii)
CHXII02:SOLUTIONS

318971 In a 0.2 molal aqueous solution of a weak acid \(\mathrm{HX}\), the degree of ionization is 0.3 . Taking \(\mathrm{k}_{\mathrm{f}}\) for water as 1.85 , the freezing point of the solution will be nearest to

1 \(-0.360^{\circ} \mathrm{C}\)
2 \(-0.260^{\circ} \mathrm{C}\)
3 \(+0.480^{\circ} \mathrm{C}\)
4 \(-0.480^{\circ} \mathrm{C}\)
CHXII02:SOLUTIONS

318972 The freezing point depression constant for water is \({\rm{1}}{\rm{.8}}{{\rm{6}}^{\rm{^\circ }}}{\rm{C}}{{\rm{m}}^{{\rm{ - 1}}}}{\rm{.If}}\,\,{\rm{5}}{\rm{.00}}\,{\rm{g}}\,\,{\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\) is dissolved in \({\rm{45}}{\rm{.0}}{\mkern 1mu} {\mkern 1mu} {\rm{g}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O}}\), the freezing point is changed by \({\rm{ - 3}}{\rm{.8}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\), Calculate the van’t Hoff factor for \({\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\).

1 2.05
2 3.11
3 0.381
4 2.63
CHXII02:SOLUTIONS

318969 Which among the following colligative properties is useful to determine molar masses of very expensive solutes?

1 Freezing point depression
2 Osmotic pressure
3 Vapour pressure lowering
4 Boiling point elevation
CHXII02:SOLUTIONS

318970 Arrange the following solutions in increasing order of their osmotic pressure.
(i) 34.2 g/litre sucrose
(ii) 60 g/litre of urea
(iii) 90 g/litre of glucose
(iv) 58.5 g/litre of sodium chloride

1 (i) < (iii) < (ii) < (iv)
2 (iii) < (i) < (iv) < (ii)
3 (i) < (iii) < (iv) < (ii)
4 (ii) < (iv) < (i) < (iii)
CHXII02:SOLUTIONS

318971 In a 0.2 molal aqueous solution of a weak acid \(\mathrm{HX}\), the degree of ionization is 0.3 . Taking \(\mathrm{k}_{\mathrm{f}}\) for water as 1.85 , the freezing point of the solution will be nearest to

1 \(-0.360^{\circ} \mathrm{C}\)
2 \(-0.260^{\circ} \mathrm{C}\)
3 \(+0.480^{\circ} \mathrm{C}\)
4 \(-0.480^{\circ} \mathrm{C}\)
CHXII02:SOLUTIONS

318972 The freezing point depression constant for water is \({\rm{1}}{\rm{.8}}{{\rm{6}}^{\rm{^\circ }}}{\rm{C}}{{\rm{m}}^{{\rm{ - 1}}}}{\rm{.If}}\,\,{\rm{5}}{\rm{.00}}\,{\rm{g}}\,\,{\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\) is dissolved in \({\rm{45}}{\rm{.0}}{\mkern 1mu} {\mkern 1mu} {\rm{g}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O}}\), the freezing point is changed by \({\rm{ - 3}}{\rm{.8}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\), Calculate the van’t Hoff factor for \({\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\).

1 2.05
2 3.11
3 0.381
4 2.63
CHXII02:SOLUTIONS

318969 Which among the following colligative properties is useful to determine molar masses of very expensive solutes?

1 Freezing point depression
2 Osmotic pressure
3 Vapour pressure lowering
4 Boiling point elevation
CHXII02:SOLUTIONS

318970 Arrange the following solutions in increasing order of their osmotic pressure.
(i) 34.2 g/litre sucrose
(ii) 60 g/litre of urea
(iii) 90 g/litre of glucose
(iv) 58.5 g/litre of sodium chloride

1 (i) < (iii) < (ii) < (iv)
2 (iii) < (i) < (iv) < (ii)
3 (i) < (iii) < (iv) < (ii)
4 (ii) < (iv) < (i) < (iii)
CHXII02:SOLUTIONS

318971 In a 0.2 molal aqueous solution of a weak acid \(\mathrm{HX}\), the degree of ionization is 0.3 . Taking \(\mathrm{k}_{\mathrm{f}}\) for water as 1.85 , the freezing point of the solution will be nearest to

1 \(-0.360^{\circ} \mathrm{C}\)
2 \(-0.260^{\circ} \mathrm{C}\)
3 \(+0.480^{\circ} \mathrm{C}\)
4 \(-0.480^{\circ} \mathrm{C}\)
CHXII02:SOLUTIONS

318972 The freezing point depression constant for water is \({\rm{1}}{\rm{.8}}{{\rm{6}}^{\rm{^\circ }}}{\rm{C}}{{\rm{m}}^{{\rm{ - 1}}}}{\rm{.If}}\,\,{\rm{5}}{\rm{.00}}\,{\rm{g}}\,\,{\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\) is dissolved in \({\rm{45}}{\rm{.0}}{\mkern 1mu} {\mkern 1mu} {\rm{g}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O}}\), the freezing point is changed by \({\rm{ - 3}}{\rm{.8}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\), Calculate the van’t Hoff factor for \({\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\).

1 2.05
2 3.11
3 0.381
4 2.63
CHXII02:SOLUTIONS

318969 Which among the following colligative properties is useful to determine molar masses of very expensive solutes?

1 Freezing point depression
2 Osmotic pressure
3 Vapour pressure lowering
4 Boiling point elevation
CHXII02:SOLUTIONS

318970 Arrange the following solutions in increasing order of their osmotic pressure.
(i) 34.2 g/litre sucrose
(ii) 60 g/litre of urea
(iii) 90 g/litre of glucose
(iv) 58.5 g/litre of sodium chloride

1 (i) < (iii) < (ii) < (iv)
2 (iii) < (i) < (iv) < (ii)
3 (i) < (iii) < (iv) < (ii)
4 (ii) < (iv) < (i) < (iii)
CHXII02:SOLUTIONS

318971 In a 0.2 molal aqueous solution of a weak acid \(\mathrm{HX}\), the degree of ionization is 0.3 . Taking \(\mathrm{k}_{\mathrm{f}}\) for water as 1.85 , the freezing point of the solution will be nearest to

1 \(-0.360^{\circ} \mathrm{C}\)
2 \(-0.260^{\circ} \mathrm{C}\)
3 \(+0.480^{\circ} \mathrm{C}\)
4 \(-0.480^{\circ} \mathrm{C}\)
CHXII02:SOLUTIONS

318972 The freezing point depression constant for water is \({\rm{1}}{\rm{.8}}{{\rm{6}}^{\rm{^\circ }}}{\rm{C}}{{\rm{m}}^{{\rm{ - 1}}}}{\rm{.If}}\,\,{\rm{5}}{\rm{.00}}\,{\rm{g}}\,\,{\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\) is dissolved in \({\rm{45}}{\rm{.0}}{\mkern 1mu} {\mkern 1mu} {\rm{g}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O}}\), the freezing point is changed by \({\rm{ - 3}}{\rm{.8}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\), Calculate the van’t Hoff factor for \({\rm{N}}{{\rm{a}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\).

1 2.05
2 3.11
3 0.381
4 2.63