Directive Influence of a Functional Group in Monosubstituted Benzene
CHXI13:HYDROCARBONS

318333 Which order is correct for the decreasing reactivity towards monobromination of the following compounds?
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{C}}{{\rm{H}}_{\rm{3}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{COOH}},{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{6}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{O}}_{\rm{2}}}\)
\(\,\,\,\,\,\,\,\,\,{\rm{I}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\rm{II}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\rm{III}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu}\,\,\,\,\,\,\, {\rm{IV}}\)

1 I \(>\) II \(>\) III \(>\) IV
2 I \(>\) III \(>\) II \(>\) IV
3 II \(>\) III \(>\) IV \(>\) I
4 III \(>\) I \(>\) II \(>\) IV
CHXI13:HYDROCARBONS

318334 Replacement of \(\mathrm{Cl}\) of chlorobenzene to give phenol requires drastic conditions, but \(\mathrm{Cl}\) of 2,4- dinitrochlorobenzene is readily replaced. This is because

1 \(-\mathrm{NO}_{2}\) group makes the ring electron rich at ortho and para positions
2 \(-\mathrm{NO}_{2}\) group withdraws electrons from meta position
3 \(-\mathrm{NO}_{2}\) donates electrons at meta position
4 \(-\mathrm{NO}_{2}\) withdraws electrons from ortho and para positions
CHXI13:HYDROCARBONS

318335 Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 IV \(>\) I \(>\) II \(>\) III
3 I \(>\) II \(>\) III \(>\) IV
4 II \(>\) I \(>\) III \(>\) IV
CHXI13:HYDROCARBONS

318336 Assertion :
Aryl halides are less reactive towards substitution of halogen atom.
Reason :
Halogens are \({\text{o, p}}\) -directing in nature.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXI13:HYDROCARBONS

318333 Which order is correct for the decreasing reactivity towards monobromination of the following compounds?
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{C}}{{\rm{H}}_{\rm{3}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{COOH}},{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{6}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{O}}_{\rm{2}}}\)
\(\,\,\,\,\,\,\,\,\,{\rm{I}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\rm{II}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\rm{III}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu}\,\,\,\,\,\,\, {\rm{IV}}\)

1 I \(>\) II \(>\) III \(>\) IV
2 I \(>\) III \(>\) II \(>\) IV
3 II \(>\) III \(>\) IV \(>\) I
4 III \(>\) I \(>\) II \(>\) IV
CHXI13:HYDROCARBONS

318334 Replacement of \(\mathrm{Cl}\) of chlorobenzene to give phenol requires drastic conditions, but \(\mathrm{Cl}\) of 2,4- dinitrochlorobenzene is readily replaced. This is because

1 \(-\mathrm{NO}_{2}\) group makes the ring electron rich at ortho and para positions
2 \(-\mathrm{NO}_{2}\) group withdraws electrons from meta position
3 \(-\mathrm{NO}_{2}\) donates electrons at meta position
4 \(-\mathrm{NO}_{2}\) withdraws electrons from ortho and para positions
CHXI13:HYDROCARBONS

318335 Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 IV \(>\) I \(>\) II \(>\) III
3 I \(>\) II \(>\) III \(>\) IV
4 II \(>\) I \(>\) III \(>\) IV
CHXI13:HYDROCARBONS

318336 Assertion :
Aryl halides are less reactive towards substitution of halogen atom.
Reason :
Halogens are \({\text{o, p}}\) -directing in nature.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318333 Which order is correct for the decreasing reactivity towards monobromination of the following compounds?
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{C}}{{\rm{H}}_{\rm{3}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{COOH}},{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{6}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{O}}_{\rm{2}}}\)
\(\,\,\,\,\,\,\,\,\,{\rm{I}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\rm{II}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\rm{III}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu}\,\,\,\,\,\,\, {\rm{IV}}\)

1 I \(>\) II \(>\) III \(>\) IV
2 I \(>\) III \(>\) II \(>\) IV
3 II \(>\) III \(>\) IV \(>\) I
4 III \(>\) I \(>\) II \(>\) IV
CHXI13:HYDROCARBONS

318334 Replacement of \(\mathrm{Cl}\) of chlorobenzene to give phenol requires drastic conditions, but \(\mathrm{Cl}\) of 2,4- dinitrochlorobenzene is readily replaced. This is because

1 \(-\mathrm{NO}_{2}\) group makes the ring electron rich at ortho and para positions
2 \(-\mathrm{NO}_{2}\) group withdraws electrons from meta position
3 \(-\mathrm{NO}_{2}\) donates electrons at meta position
4 \(-\mathrm{NO}_{2}\) withdraws electrons from ortho and para positions
CHXI13:HYDROCARBONS

318335 Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 IV \(>\) I \(>\) II \(>\) III
3 I \(>\) II \(>\) III \(>\) IV
4 II \(>\) I \(>\) III \(>\) IV
CHXI13:HYDROCARBONS

318336 Assertion :
Aryl halides are less reactive towards substitution of halogen atom.
Reason :
Halogens are \({\text{o, p}}\) -directing in nature.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318333 Which order is correct for the decreasing reactivity towards monobromination of the following compounds?
\({{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{C}}{{\rm{H}}_{\rm{3}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{COOH}},{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{6}}},\;{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{5}}}{\rm{N}}{{\rm{O}}_{\rm{2}}}\)
\(\,\,\,\,\,\,\,\,\,{\rm{I}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\rm{II}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\rm{III}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu}\,\,\,\,\,\,\, {\rm{IV}}\)

1 I \(>\) II \(>\) III \(>\) IV
2 I \(>\) III \(>\) II \(>\) IV
3 II \(>\) III \(>\) IV \(>\) I
4 III \(>\) I \(>\) II \(>\) IV
CHXI13:HYDROCARBONS

318334 Replacement of \(\mathrm{Cl}\) of chlorobenzene to give phenol requires drastic conditions, but \(\mathrm{Cl}\) of 2,4- dinitrochlorobenzene is readily replaced. This is because

1 \(-\mathrm{NO}_{2}\) group makes the ring electron rich at ortho and para positions
2 \(-\mathrm{NO}_{2}\) group withdraws electrons from meta position
3 \(-\mathrm{NO}_{2}\) donates electrons at meta position
4 \(-\mathrm{NO}_{2}\) withdraws electrons from ortho and para positions
CHXI13:HYDROCARBONS

318335 Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 IV \(>\) I \(>\) II \(>\) III
3 I \(>\) II \(>\) III \(>\) IV
4 II \(>\) I \(>\) III \(>\) IV
CHXI13:HYDROCARBONS

318336 Assertion :
Aryl halides are less reactive towards substitution of halogen atom.
Reason :
Halogens are \({\text{o, p}}\) -directing in nature.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here