Directive Influence of a Functional Group in Monosubstituted Benzene
CHXI13:HYDROCARBONS

318307 supporting img

Set of reagents for above conversion is / are

1 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2}}}\), sunlight
2 (i) \({\mathrm{\mathrm{Cl}_{2}, \mathrm{Fe}}}\), dark
(ii) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
3 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2} / \mathrm{Fe} /}}\) dark
4 (i) \({\mathrm{\mathrm{HNO}_{2}}}\)
(ii) \({\mathrm{\mathrm{Cu} / \mathrm{HCl}}}\)
CHXI13:HYDROCARBONS

318308 supporting img
electrophilic substitution will occur at

1 meta in second ring
2 ortho/para in the first ring
3 meta in the first ring
4 ortho/para in the second ring
CHXI13:HYDROCARBONS

318309 A deactivating group in electrophilic substitution reaction is

1 Deactivates only ortho- and para-positions.
2 Deactivates only meta-position
3 Deactivates only meta-position more than ortho-and para- positions.
4 Deactivates ortho- and para- positions more than meta-position.
CHXI13:HYDROCARBONS

318310 The order of reactivity of following compounds
\[\begin{array}{*{20}{c}}
{\mathop {\phi - {\text{C}}{{\text{H}}_{\text{3}}}}\limits_{\text{I}} }&{\mathop {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \phi - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_3}}\limits_{{\text{II}}} } \\
{\mathop {\phi - {\text{C}}{{\text{H}}_2}{{\left( {{\text{C}}{{\text{H}}_3}} \right)}_2}}\limits_{{\text{III}}} }&{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \mathop {{{\left. {\phi - {{\text{C}}_2}{\text{C}}{{\text{H}}_3}} \right)}_3}}\limits_{{\text{IV}}} }
\end{array}\]
towards electrophilic substitution will be [ Where \(\left. {\phi = {{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}} \right]\)

1 \({\text{I > II > III > IV}}\)
2 \({\text{IV > III > II > I}}\)
3 \({\text{II > I > III > IV}}\)
4 \({\text{III > II > I > IV}}\)
CHXI13:HYDROCARBONS

318311 Assertion :
Toluene on Friedal Crafts methylation gives \({\text{o - and p - xylene}}{\text{.}}\)
Reason :
\(-\mathrm{CH}_{3}\) group bonded to benzene ring increases electron density at \({\text{o - and p - }}{\text{.}}\) positions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI13:HYDROCARBONS

318307 supporting img

Set of reagents for above conversion is / are

1 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2}}}\), sunlight
2 (i) \({\mathrm{\mathrm{Cl}_{2}, \mathrm{Fe}}}\), dark
(ii) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
3 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2} / \mathrm{Fe} /}}\) dark
4 (i) \({\mathrm{\mathrm{HNO}_{2}}}\)
(ii) \({\mathrm{\mathrm{Cu} / \mathrm{HCl}}}\)
CHXI13:HYDROCARBONS

318308 supporting img
electrophilic substitution will occur at

1 meta in second ring
2 ortho/para in the first ring
3 meta in the first ring
4 ortho/para in the second ring
CHXI13:HYDROCARBONS

318309 A deactivating group in electrophilic substitution reaction is

1 Deactivates only ortho- and para-positions.
2 Deactivates only meta-position
3 Deactivates only meta-position more than ortho-and para- positions.
4 Deactivates ortho- and para- positions more than meta-position.
CHXI13:HYDROCARBONS

318310 The order of reactivity of following compounds
\[\begin{array}{*{20}{c}}
{\mathop {\phi - {\text{C}}{{\text{H}}_{\text{3}}}}\limits_{\text{I}} }&{\mathop {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \phi - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_3}}\limits_{{\text{II}}} } \\
{\mathop {\phi - {\text{C}}{{\text{H}}_2}{{\left( {{\text{C}}{{\text{H}}_3}} \right)}_2}}\limits_{{\text{III}}} }&{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \mathop {{{\left. {\phi - {{\text{C}}_2}{\text{C}}{{\text{H}}_3}} \right)}_3}}\limits_{{\text{IV}}} }
\end{array}\]
towards electrophilic substitution will be [ Where \(\left. {\phi = {{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}} \right]\)

1 \({\text{I > II > III > IV}}\)
2 \({\text{IV > III > II > I}}\)
3 \({\text{II > I > III > IV}}\)
4 \({\text{III > II > I > IV}}\)
CHXI13:HYDROCARBONS

318311 Assertion :
Toluene on Friedal Crafts methylation gives \({\text{o - and p - xylene}}{\text{.}}\)
Reason :
\(-\mathrm{CH}_{3}\) group bonded to benzene ring increases electron density at \({\text{o - and p - }}{\text{.}}\) positions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI13:HYDROCARBONS

318307 supporting img

Set of reagents for above conversion is / are

1 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2}}}\), sunlight
2 (i) \({\mathrm{\mathrm{Cl}_{2}, \mathrm{Fe}}}\), dark
(ii) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
3 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2} / \mathrm{Fe} /}}\) dark
4 (i) \({\mathrm{\mathrm{HNO}_{2}}}\)
(ii) \({\mathrm{\mathrm{Cu} / \mathrm{HCl}}}\)
CHXI13:HYDROCARBONS

318308 supporting img
electrophilic substitution will occur at

1 meta in second ring
2 ortho/para in the first ring
3 meta in the first ring
4 ortho/para in the second ring
CHXI13:HYDROCARBONS

318309 A deactivating group in electrophilic substitution reaction is

1 Deactivates only ortho- and para-positions.
2 Deactivates only meta-position
3 Deactivates only meta-position more than ortho-and para- positions.
4 Deactivates ortho- and para- positions more than meta-position.
CHXI13:HYDROCARBONS

318310 The order of reactivity of following compounds
\[\begin{array}{*{20}{c}}
{\mathop {\phi - {\text{C}}{{\text{H}}_{\text{3}}}}\limits_{\text{I}} }&{\mathop {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \phi - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_3}}\limits_{{\text{II}}} } \\
{\mathop {\phi - {\text{C}}{{\text{H}}_2}{{\left( {{\text{C}}{{\text{H}}_3}} \right)}_2}}\limits_{{\text{III}}} }&{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \mathop {{{\left. {\phi - {{\text{C}}_2}{\text{C}}{{\text{H}}_3}} \right)}_3}}\limits_{{\text{IV}}} }
\end{array}\]
towards electrophilic substitution will be [ Where \(\left. {\phi = {{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}} \right]\)

1 \({\text{I > II > III > IV}}\)
2 \({\text{IV > III > II > I}}\)
3 \({\text{II > I > III > IV}}\)
4 \({\text{III > II > I > IV}}\)
CHXI13:HYDROCARBONS

318311 Assertion :
Toluene on Friedal Crafts methylation gives \({\text{o - and p - xylene}}{\text{.}}\)
Reason :
\(-\mathrm{CH}_{3}\) group bonded to benzene ring increases electron density at \({\text{o - and p - }}{\text{.}}\) positions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXI13:HYDROCARBONS

318307 supporting img

Set of reagents for above conversion is / are

1 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2}}}\), sunlight
2 (i) \({\mathrm{\mathrm{Cl}_{2}, \mathrm{Fe}}}\), dark
(ii) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
3 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2} / \mathrm{Fe} /}}\) dark
4 (i) \({\mathrm{\mathrm{HNO}_{2}}}\)
(ii) \({\mathrm{\mathrm{Cu} / \mathrm{HCl}}}\)
CHXI13:HYDROCARBONS

318308 supporting img
electrophilic substitution will occur at

1 meta in second ring
2 ortho/para in the first ring
3 meta in the first ring
4 ortho/para in the second ring
CHXI13:HYDROCARBONS

318309 A deactivating group in electrophilic substitution reaction is

1 Deactivates only ortho- and para-positions.
2 Deactivates only meta-position
3 Deactivates only meta-position more than ortho-and para- positions.
4 Deactivates ortho- and para- positions more than meta-position.
CHXI13:HYDROCARBONS

318310 The order of reactivity of following compounds
\[\begin{array}{*{20}{c}}
{\mathop {\phi - {\text{C}}{{\text{H}}_{\text{3}}}}\limits_{\text{I}} }&{\mathop {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \phi - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_3}}\limits_{{\text{II}}} } \\
{\mathop {\phi - {\text{C}}{{\text{H}}_2}{{\left( {{\text{C}}{{\text{H}}_3}} \right)}_2}}\limits_{{\text{III}}} }&{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \mathop {{{\left. {\phi - {{\text{C}}_2}{\text{C}}{{\text{H}}_3}} \right)}_3}}\limits_{{\text{IV}}} }
\end{array}\]
towards electrophilic substitution will be [ Where \(\left. {\phi = {{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}} \right]\)

1 \({\text{I > II > III > IV}}\)
2 \({\text{IV > III > II > I}}\)
3 \({\text{II > I > III > IV}}\)
4 \({\text{III > II > I > IV}}\)
CHXI13:HYDROCARBONS

318311 Assertion :
Toluene on Friedal Crafts methylation gives \({\text{o - and p - xylene}}{\text{.}}\)
Reason :
\(-\mathrm{CH}_{3}\) group bonded to benzene ring increases electron density at \({\text{o - and p - }}{\text{.}}\) positions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI13:HYDROCARBONS

318307 supporting img

Set of reagents for above conversion is / are

1 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2}}}\), sunlight
2 (i) \({\mathrm{\mathrm{Cl}_{2}, \mathrm{Fe}}}\), dark
(ii) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
3 (i) Conc \({\mathrm{\mathrm{HNO}_{3}+}}\) conc \({\mathrm{\mathrm{H}_{2} \mathrm{SO}_{4}}}\)
(ii) \({\mathrm{\mathrm{Cl}_{2} / \mathrm{Fe} /}}\) dark
4 (i) \({\mathrm{\mathrm{HNO}_{2}}}\)
(ii) \({\mathrm{\mathrm{Cu} / \mathrm{HCl}}}\)
CHXI13:HYDROCARBONS

318308 supporting img
electrophilic substitution will occur at

1 meta in second ring
2 ortho/para in the first ring
3 meta in the first ring
4 ortho/para in the second ring
CHXI13:HYDROCARBONS

318309 A deactivating group in electrophilic substitution reaction is

1 Deactivates only ortho- and para-positions.
2 Deactivates only meta-position
3 Deactivates only meta-position more than ortho-and para- positions.
4 Deactivates ortho- and para- positions more than meta-position.
CHXI13:HYDROCARBONS

318310 The order of reactivity of following compounds
\[\begin{array}{*{20}{c}}
{\mathop {\phi - {\text{C}}{{\text{H}}_{\text{3}}}}\limits_{\text{I}} }&{\mathop {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \phi - {\text{C}}{{\text{H}}_2} - {\text{C}}{{\text{H}}_3}}\limits_{{\text{II}}} } \\
{\mathop {\phi - {\text{C}}{{\text{H}}_2}{{\left( {{\text{C}}{{\text{H}}_3}} \right)}_2}}\limits_{{\text{III}}} }&{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \mathop {{{\left. {\phi - {{\text{C}}_2}{\text{C}}{{\text{H}}_3}} \right)}_3}}\limits_{{\text{IV}}} }
\end{array}\]
towards electrophilic substitution will be [ Where \(\left. {\phi = {{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}} \right]\)

1 \({\text{I > II > III > IV}}\)
2 \({\text{IV > III > II > I}}\)
3 \({\text{II > I > III > IV}}\)
4 \({\text{III > II > I > IV}}\)
CHXI13:HYDROCARBONS

318311 Assertion :
Toluene on Friedal Crafts methylation gives \({\text{o - and p - xylene}}{\text{.}}\)
Reason :
\(-\mathrm{CH}_{3}\) group bonded to benzene ring increases electron density at \({\text{o - and p - }}{\text{.}}\) positions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.