Chemical Properties and General Characteristics of Group – 13 Elements
CHXI11:THE P-BLOCK ELEMENTS

316214 Assertion :
Anhydrous \(\mathrm{AlCl}_{3}\) is covalent but hydrated \(\mathrm{AlCl}_{3}\) is ionic.
Reason :
In water, \(\mathrm{Al}_{2} \mathrm{Cl}_{6}\) dissociates into hydrated \(\mathrm{Al}^{3+}\) and \(\mathrm{Cl}^{-}\)ions due to high heat of hydration of these ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316215 Which one of the following elements is unable to form \({\text{MF}}_{\text{6}}^{{\text{3 - }}}\) ion?

1 \(\mathrm{B}\)
2 \(\mathrm{In}\)
3 \(\mathrm{Al}\)
4 \(\mathrm{Ga}\)
CHXI11:THE P-BLOCK ELEMENTS

316233 Assertion :
Although \(\mathrm{PF}_{5}, \mathrm{PCl}_{5}\) and \(\mathrm{PBr}_{5}\) are known, the pentahalides of nitrogen have not been observed.
Reason :
Phosphorus has lower electronegativity than nitrogen

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316216 The Lewis acid character of boron trihalides follows the order

1 \(\mathrm{BF}_{3}>\mathrm{BCl}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
2 \(\mathrm{BI}_{3}>\mathrm{BBr}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
3 \(\mathrm{BBr}_{3}>\mathrm{BI}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
4 \(\mathrm{BCl}_{3}>\mathrm{BF}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
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CHXI11:THE P-BLOCK ELEMENTS

316214 Assertion :
Anhydrous \(\mathrm{AlCl}_{3}\) is covalent but hydrated \(\mathrm{AlCl}_{3}\) is ionic.
Reason :
In water, \(\mathrm{Al}_{2} \mathrm{Cl}_{6}\) dissociates into hydrated \(\mathrm{Al}^{3+}\) and \(\mathrm{Cl}^{-}\)ions due to high heat of hydration of these ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316215 Which one of the following elements is unable to form \({\text{MF}}_{\text{6}}^{{\text{3 - }}}\) ion?

1 \(\mathrm{B}\)
2 \(\mathrm{In}\)
3 \(\mathrm{Al}\)
4 \(\mathrm{Ga}\)
CHXI11:THE P-BLOCK ELEMENTS

316233 Assertion :
Although \(\mathrm{PF}_{5}, \mathrm{PCl}_{5}\) and \(\mathrm{PBr}_{5}\) are known, the pentahalides of nitrogen have not been observed.
Reason :
Phosphorus has lower electronegativity than nitrogen

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316216 The Lewis acid character of boron trihalides follows the order

1 \(\mathrm{BF}_{3}>\mathrm{BCl}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
2 \(\mathrm{BI}_{3}>\mathrm{BBr}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
3 \(\mathrm{BBr}_{3}>\mathrm{BI}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
4 \(\mathrm{BCl}_{3}>\mathrm{BF}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316214 Assertion :
Anhydrous \(\mathrm{AlCl}_{3}\) is covalent but hydrated \(\mathrm{AlCl}_{3}\) is ionic.
Reason :
In water, \(\mathrm{Al}_{2} \mathrm{Cl}_{6}\) dissociates into hydrated \(\mathrm{Al}^{3+}\) and \(\mathrm{Cl}^{-}\)ions due to high heat of hydration of these ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316215 Which one of the following elements is unable to form \({\text{MF}}_{\text{6}}^{{\text{3 - }}}\) ion?

1 \(\mathrm{B}\)
2 \(\mathrm{In}\)
3 \(\mathrm{Al}\)
4 \(\mathrm{Ga}\)
CHXI11:THE P-BLOCK ELEMENTS

316233 Assertion :
Although \(\mathrm{PF}_{5}, \mathrm{PCl}_{5}\) and \(\mathrm{PBr}_{5}\) are known, the pentahalides of nitrogen have not been observed.
Reason :
Phosphorus has lower electronegativity than nitrogen

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316216 The Lewis acid character of boron trihalides follows the order

1 \(\mathrm{BF}_{3}>\mathrm{BCl}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
2 \(\mathrm{BI}_{3}>\mathrm{BBr}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
3 \(\mathrm{BBr}_{3}>\mathrm{BI}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
4 \(\mathrm{BCl}_{3}>\mathrm{BF}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316214 Assertion :
Anhydrous \(\mathrm{AlCl}_{3}\) is covalent but hydrated \(\mathrm{AlCl}_{3}\) is ionic.
Reason :
In water, \(\mathrm{Al}_{2} \mathrm{Cl}_{6}\) dissociates into hydrated \(\mathrm{Al}^{3+}\) and \(\mathrm{Cl}^{-}\)ions due to high heat of hydration of these ions.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316215 Which one of the following elements is unable to form \({\text{MF}}_{\text{6}}^{{\text{3 - }}}\) ion?

1 \(\mathrm{B}\)
2 \(\mathrm{In}\)
3 \(\mathrm{Al}\)
4 \(\mathrm{Ga}\)
CHXI11:THE P-BLOCK ELEMENTS

316233 Assertion :
Although \(\mathrm{PF}_{5}, \mathrm{PCl}_{5}\) and \(\mathrm{PBr}_{5}\) are known, the pentahalides of nitrogen have not been observed.
Reason :
Phosphorus has lower electronegativity than nitrogen

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316216 The Lewis acid character of boron trihalides follows the order

1 \(\mathrm{BF}_{3}>\mathrm{BCl}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)
2 \(\mathrm{BI}_{3}>\mathrm{BBr}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
3 \(\mathrm{BBr}_{3}>\mathrm{BI}_{3}>\mathrm{BCl}_{3}>\mathrm{BF}_{3}\)
4 \(\mathrm{BCl}_{3}>\mathrm{BF}_{3}>\mathrm{BBr}_{3}>\mathrm{BI}_{3}\)