1 \(\mathrm{C}_{2} \mathrm{H}_{6}>\mathrm{C}_{2} \mathrm{H}_{4}>\mathrm{C}_{6} \mathrm{H}_{6}>\mathrm{C}_{2} \mathrm{H}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{2} < \mathrm{C}_{2} \mathrm{H}_{4} < \mathrm{C}_{6} \mathrm{H}_{6} < \mathrm{C}_{2} \mathrm{H}_{6}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{6}>\mathrm{C}_{2} \mathrm{H}_{2}>\mathrm{C}_{6} \mathrm{H}_{6}>\mathrm{C}_{2} \mathrm{H}_{4}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{4}>\mathrm{C}_{2} \mathrm{H}_{6}>\mathrm{C}_{6} \mathrm{H}_{2}>\mathrm{C}_{6} \mathrm{H}_{6}\)
Explanation:
\[\begin{array}{l}
{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{6}}}\,\,\,{\rm{ > }}\,\,\,{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{\rm{6}}}\,\,\,{\rm{ > }}\,\,\,{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{4}}}\,\,\,{\rm{ > }}\,\,\,{{\rm{C}}_{\rm{2}}}{{\rm{H}}_{\rm{2}}}\\
{\rm{1}}{\rm{.54}}\mathop {\rm{A}}\limits^{\rm{o}} \,\,\,\,\,\,{\rm{1}}{\rm{.39}}\mathop {\rm{A}}\limits^{\rm{o}} \,\,\,\,\,\,{\rm{1}}{\rm{.34}}\mathop {\rm{A}}\limits^{\rm{o}} \,\,\,\,\,\,{\rm{1}}{\rm{.20}}\mathop {\rm{A}}\limits^{\rm{o}} \end{array}\]