Le Chatelier’s Principle and Applications
CHXI07:EQUILIBRIUM

314828 When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction takes place and the reaction mixture becomes blue. On cooling the mixture it becomes pink. On the basis of this information mark the correct answer.
\(\left[ {{\text{Co(}}\mathop {{{\text{H}}_{\text{2}}}{\text{O}}}\limits_{{\text{Pink}}} {{\text{)}}_{\text{6}}}} \right]_{{\text{(aq)}}}^{{\text{3 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{{\text{ - }}} \rightleftharpoons \left[ {\mathop {{\text{CoC}}{{\text{l}}_{\text{4}}}}\limits_{{\text{(blue)}}} } \right]_{{\text{(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{\text{O}}\)

1 \({\rm{\Delta H > 0}}\) for the reaction
2 \({\rm{\Delta H < 0}}\) for the reaction
3 \({\rm{\Delta H = 0}}\) for the reaction
4 The sign of \({\rm{\Delta H}}\) cannot be predicted on the basis of this information.
CHXI07:EQUILIBRIUM

314829 Assertion :
According to Le Chatelier's principle addition of heat to an equilibrium
[Solid \(\rightleftharpoons\) liquid] results in decrease in the amount of solid.
Reason :
Reaction is endothermic, so on heating forward reaction is favoured.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314830 Assertion :
On cooling in a freezing mixture, colour of the following mixture turns to pink from deep blue for the reaction \({\text{Co}}\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)_{{\text{6(aq)}}}^{{\text{2 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{\text{ - }} \rightleftharpoons {\text{CoCl}}_{{\text{4(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{{\text{O}}_{{\text{(1)}}}}\)
Reason :
Reaction is endothermic. So on cooling, the reaction moves to backward direction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI07:EQUILIBRIUM

314831 In the dissociation of \(2 \mathrm{HI} \rightleftharpoons \mathrm{H}_{2}+\mathrm{I}_{2}\), the degree of dissociation will be affected by the

1 Addition of inert gas
2 Addition of catalyst
3 Increase of temperature
4 Increase of pressure
CHXI07:EQUILIBRIUM

314833 \({{\text{N}}_{{\text{2}}\left( {\text{g}} \right)}}{\text{ + 3}}{{\text{H}}_{{\text{2}}\left( {\text{g}} \right)}} \rightleftharpoons {\text{2N}}{{\text{H}}_{{\text{3}}\left( {\text{g}} \right)}}{\text{ + }}\) heat
What is the effect of the increase of temperature on the equilibrium of the reaction?

1 Equilibrium is unaltered
2 Reaction rates does not change
3 Equilibrium is shifted to the left
4 Equilibrium is shfited to the right
CHXI07:EQUILIBRIUM

314828 When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction takes place and the reaction mixture becomes blue. On cooling the mixture it becomes pink. On the basis of this information mark the correct answer.
\(\left[ {{\text{Co(}}\mathop {{{\text{H}}_{\text{2}}}{\text{O}}}\limits_{{\text{Pink}}} {{\text{)}}_{\text{6}}}} \right]_{{\text{(aq)}}}^{{\text{3 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{{\text{ - }}} \rightleftharpoons \left[ {\mathop {{\text{CoC}}{{\text{l}}_{\text{4}}}}\limits_{{\text{(blue)}}} } \right]_{{\text{(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{\text{O}}\)

1 \({\rm{\Delta H > 0}}\) for the reaction
2 \({\rm{\Delta H < 0}}\) for the reaction
3 \({\rm{\Delta H = 0}}\) for the reaction
4 The sign of \({\rm{\Delta H}}\) cannot be predicted on the basis of this information.
CHXI07:EQUILIBRIUM

314829 Assertion :
According to Le Chatelier's principle addition of heat to an equilibrium
[Solid \(\rightleftharpoons\) liquid] results in decrease in the amount of solid.
Reason :
Reaction is endothermic, so on heating forward reaction is favoured.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314830 Assertion :
On cooling in a freezing mixture, colour of the following mixture turns to pink from deep blue for the reaction \({\text{Co}}\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)_{{\text{6(aq)}}}^{{\text{2 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{\text{ - }} \rightleftharpoons {\text{CoCl}}_{{\text{4(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{{\text{O}}_{{\text{(1)}}}}\)
Reason :
Reaction is endothermic. So on cooling, the reaction moves to backward direction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI07:EQUILIBRIUM

314831 In the dissociation of \(2 \mathrm{HI} \rightleftharpoons \mathrm{H}_{2}+\mathrm{I}_{2}\), the degree of dissociation will be affected by the

1 Addition of inert gas
2 Addition of catalyst
3 Increase of temperature
4 Increase of pressure
CHXI07:EQUILIBRIUM

314833 \({{\text{N}}_{{\text{2}}\left( {\text{g}} \right)}}{\text{ + 3}}{{\text{H}}_{{\text{2}}\left( {\text{g}} \right)}} \rightleftharpoons {\text{2N}}{{\text{H}}_{{\text{3}}\left( {\text{g}} \right)}}{\text{ + }}\) heat
What is the effect of the increase of temperature on the equilibrium of the reaction?

1 Equilibrium is unaltered
2 Reaction rates does not change
3 Equilibrium is shifted to the left
4 Equilibrium is shfited to the right
CHXI07:EQUILIBRIUM

314828 When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction takes place and the reaction mixture becomes blue. On cooling the mixture it becomes pink. On the basis of this information mark the correct answer.
\(\left[ {{\text{Co(}}\mathop {{{\text{H}}_{\text{2}}}{\text{O}}}\limits_{{\text{Pink}}} {{\text{)}}_{\text{6}}}} \right]_{{\text{(aq)}}}^{{\text{3 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{{\text{ - }}} \rightleftharpoons \left[ {\mathop {{\text{CoC}}{{\text{l}}_{\text{4}}}}\limits_{{\text{(blue)}}} } \right]_{{\text{(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{\text{O}}\)

1 \({\rm{\Delta H > 0}}\) for the reaction
2 \({\rm{\Delta H < 0}}\) for the reaction
3 \({\rm{\Delta H = 0}}\) for the reaction
4 The sign of \({\rm{\Delta H}}\) cannot be predicted on the basis of this information.
CHXI07:EQUILIBRIUM

314829 Assertion :
According to Le Chatelier's principle addition of heat to an equilibrium
[Solid \(\rightleftharpoons\) liquid] results in decrease in the amount of solid.
Reason :
Reaction is endothermic, so on heating forward reaction is favoured.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314830 Assertion :
On cooling in a freezing mixture, colour of the following mixture turns to pink from deep blue for the reaction \({\text{Co}}\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)_{{\text{6(aq)}}}^{{\text{2 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{\text{ - }} \rightleftharpoons {\text{CoCl}}_{{\text{4(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{{\text{O}}_{{\text{(1)}}}}\)
Reason :
Reaction is endothermic. So on cooling, the reaction moves to backward direction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI07:EQUILIBRIUM

314831 In the dissociation of \(2 \mathrm{HI} \rightleftharpoons \mathrm{H}_{2}+\mathrm{I}_{2}\), the degree of dissociation will be affected by the

1 Addition of inert gas
2 Addition of catalyst
3 Increase of temperature
4 Increase of pressure
CHXI07:EQUILIBRIUM

314833 \({{\text{N}}_{{\text{2}}\left( {\text{g}} \right)}}{\text{ + 3}}{{\text{H}}_{{\text{2}}\left( {\text{g}} \right)}} \rightleftharpoons {\text{2N}}{{\text{H}}_{{\text{3}}\left( {\text{g}} \right)}}{\text{ + }}\) heat
What is the effect of the increase of temperature on the equilibrium of the reaction?

1 Equilibrium is unaltered
2 Reaction rates does not change
3 Equilibrium is shifted to the left
4 Equilibrium is shfited to the right
CHXI07:EQUILIBRIUM

314828 When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction takes place and the reaction mixture becomes blue. On cooling the mixture it becomes pink. On the basis of this information mark the correct answer.
\(\left[ {{\text{Co(}}\mathop {{{\text{H}}_{\text{2}}}{\text{O}}}\limits_{{\text{Pink}}} {{\text{)}}_{\text{6}}}} \right]_{{\text{(aq)}}}^{{\text{3 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{{\text{ - }}} \rightleftharpoons \left[ {\mathop {{\text{CoC}}{{\text{l}}_{\text{4}}}}\limits_{{\text{(blue)}}} } \right]_{{\text{(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{\text{O}}\)

1 \({\rm{\Delta H > 0}}\) for the reaction
2 \({\rm{\Delta H < 0}}\) for the reaction
3 \({\rm{\Delta H = 0}}\) for the reaction
4 The sign of \({\rm{\Delta H}}\) cannot be predicted on the basis of this information.
CHXI07:EQUILIBRIUM

314829 Assertion :
According to Le Chatelier's principle addition of heat to an equilibrium
[Solid \(\rightleftharpoons\) liquid] results in decrease in the amount of solid.
Reason :
Reaction is endothermic, so on heating forward reaction is favoured.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314830 Assertion :
On cooling in a freezing mixture, colour of the following mixture turns to pink from deep blue for the reaction \({\text{Co}}\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)_{{\text{6(aq)}}}^{{\text{2 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{\text{ - }} \rightleftharpoons {\text{CoCl}}_{{\text{4(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{{\text{O}}_{{\text{(1)}}}}\)
Reason :
Reaction is endothermic. So on cooling, the reaction moves to backward direction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI07:EQUILIBRIUM

314831 In the dissociation of \(2 \mathrm{HI} \rightleftharpoons \mathrm{H}_{2}+\mathrm{I}_{2}\), the degree of dissociation will be affected by the

1 Addition of inert gas
2 Addition of catalyst
3 Increase of temperature
4 Increase of pressure
CHXI07:EQUILIBRIUM

314833 \({{\text{N}}_{{\text{2}}\left( {\text{g}} \right)}}{\text{ + 3}}{{\text{H}}_{{\text{2}}\left( {\text{g}} \right)}} \rightleftharpoons {\text{2N}}{{\text{H}}_{{\text{3}}\left( {\text{g}} \right)}}{\text{ + }}\) heat
What is the effect of the increase of temperature on the equilibrium of the reaction?

1 Equilibrium is unaltered
2 Reaction rates does not change
3 Equilibrium is shifted to the left
4 Equilibrium is shfited to the right
CHXI07:EQUILIBRIUM

314828 When hydrochloric acid is added to cobalt nitrate solution at room temperature, the following reaction takes place and the reaction mixture becomes blue. On cooling the mixture it becomes pink. On the basis of this information mark the correct answer.
\(\left[ {{\text{Co(}}\mathop {{{\text{H}}_{\text{2}}}{\text{O}}}\limits_{{\text{Pink}}} {{\text{)}}_{\text{6}}}} \right]_{{\text{(aq)}}}^{{\text{3 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{{\text{ - }}} \rightleftharpoons \left[ {\mathop {{\text{CoC}}{{\text{l}}_{\text{4}}}}\limits_{{\text{(blue)}}} } \right]_{{\text{(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{\text{O}}\)

1 \({\rm{\Delta H > 0}}\) for the reaction
2 \({\rm{\Delta H < 0}}\) for the reaction
3 \({\rm{\Delta H = 0}}\) for the reaction
4 The sign of \({\rm{\Delta H}}\) cannot be predicted on the basis of this information.
CHXI07:EQUILIBRIUM

314829 Assertion :
According to Le Chatelier's principle addition of heat to an equilibrium
[Solid \(\rightleftharpoons\) liquid] results in decrease in the amount of solid.
Reason :
Reaction is endothermic, so on heating forward reaction is favoured.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314830 Assertion :
On cooling in a freezing mixture, colour of the following mixture turns to pink from deep blue for the reaction \({\text{Co}}\left( {{{\text{H}}_{\text{2}}}{\text{O}}} \right)_{{\text{6(aq)}}}^{{\text{2 + }}}{\text{ + 4Cl}}_{{\text{(aq)}}}^{\text{ - }} \rightleftharpoons {\text{CoCl}}_{{\text{4(aq)}}}^{{\text{2 - }}}{\text{ + 6}}{{\text{H}}_{\text{2}}}{{\text{O}}_{{\text{(1)}}}}\)
Reason :
Reaction is endothermic. So on cooling, the reaction moves to backward direction.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI07:EQUILIBRIUM

314831 In the dissociation of \(2 \mathrm{HI} \rightleftharpoons \mathrm{H}_{2}+\mathrm{I}_{2}\), the degree of dissociation will be affected by the

1 Addition of inert gas
2 Addition of catalyst
3 Increase of temperature
4 Increase of pressure
CHXI07:EQUILIBRIUM

314833 \({{\text{N}}_{{\text{2}}\left( {\text{g}} \right)}}{\text{ + 3}}{{\text{H}}_{{\text{2}}\left( {\text{g}} \right)}} \rightleftharpoons {\text{2N}}{{\text{H}}_{{\text{3}}\left( {\text{g}} \right)}}{\text{ + }}\) heat
What is the effect of the increase of temperature on the equilibrium of the reaction?

1 Equilibrium is unaltered
2 Reaction rates does not change
3 Equilibrium is shifted to the left
4 Equilibrium is shfited to the right