Gibbs Free Energy and Standard Free Energy Change
CHXI06:THERMODYNAMICS

369411 Calculate the change in molar Gibb's energy of carbon dioxide gas at \(\mathrm{20^{\circ} \mathrm{C}}\) when it is isothermally expanded from 1.0 to \({\rm{2}}{\rm{.0}}\,{\rm{bar}}\)

1 \(\mathrm{2.4 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-2.4 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{1.7 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{-1.7 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369412 Which of the following is not correct?

1 \(\mathrm{\Delta G}\) is zero for a reversible reaction.
2 \(\mathrm{\Delta \mathrm{G}}\) is positive for a spontaneous reaction.
3 \(\mathrm{\Delta \mathrm{G}}\) is negative for a spontaneous reaction.
4 \(\mathrm{\Delta \mathrm{G}}\) is positive for a non-spontaneous reaction.
CHXI06:THERMODYNAMICS

369413 \(\mathrm{\Delta G=-177 \mathrm{kcal}}\) for \(\mathrm{2 \mathrm{Fe}_{(s)}+\dfrac{3}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}}\) and \(\mathrm{\Delta G=-19 \mathrm{kcal}}\) for \(\mathrm{4 \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}+\mathrm{Fe}_{(\mathrm{s})}}\) \(\mathrm{\rightarrow 3 \mathrm{Fe}_{3} \mathrm{O}_{4(\mathrm{~s})}}\)
what is the Gibb's free energy of formation of \(\mathrm{\mathrm{Fe}_{3} \mathrm{O}_{4}}\) ?

1 \(\mathrm{+229.6 \mathrm{kcal} / \mathrm{mol}}\)
2 \(\mathrm{-242.4 \mathrm{kcal} / \mathrm{mol}}\)
3 \(\mathrm{-727 \mathrm{kcal} / \mathrm{mol}}\)
4 \(\mathrm{-229.6 \mathrm{kcal} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369414 Assertion :
An exothermic process, non-spontaneous at high temperature, may become spontaneous at low temperature.
Reason :
With decrease in temperature. randomness (entropy) increases.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369415 Assertion :
The thermodynamic function which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative.
Reason :
The change in free energy is related to the change in enthalpy and change in entropy. The change in entropy for a process must always be positive if it is spontaneous.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369411 Calculate the change in molar Gibb's energy of carbon dioxide gas at \(\mathrm{20^{\circ} \mathrm{C}}\) when it is isothermally expanded from 1.0 to \({\rm{2}}{\rm{.0}}\,{\rm{bar}}\)

1 \(\mathrm{2.4 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-2.4 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{1.7 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{-1.7 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369412 Which of the following is not correct?

1 \(\mathrm{\Delta G}\) is zero for a reversible reaction.
2 \(\mathrm{\Delta \mathrm{G}}\) is positive for a spontaneous reaction.
3 \(\mathrm{\Delta \mathrm{G}}\) is negative for a spontaneous reaction.
4 \(\mathrm{\Delta \mathrm{G}}\) is positive for a non-spontaneous reaction.
CHXI06:THERMODYNAMICS

369413 \(\mathrm{\Delta G=-177 \mathrm{kcal}}\) for \(\mathrm{2 \mathrm{Fe}_{(s)}+\dfrac{3}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}}\) and \(\mathrm{\Delta G=-19 \mathrm{kcal}}\) for \(\mathrm{4 \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}+\mathrm{Fe}_{(\mathrm{s})}}\) \(\mathrm{\rightarrow 3 \mathrm{Fe}_{3} \mathrm{O}_{4(\mathrm{~s})}}\)
what is the Gibb's free energy of formation of \(\mathrm{\mathrm{Fe}_{3} \mathrm{O}_{4}}\) ?

1 \(\mathrm{+229.6 \mathrm{kcal} / \mathrm{mol}}\)
2 \(\mathrm{-242.4 \mathrm{kcal} / \mathrm{mol}}\)
3 \(\mathrm{-727 \mathrm{kcal} / \mathrm{mol}}\)
4 \(\mathrm{-229.6 \mathrm{kcal} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369414 Assertion :
An exothermic process, non-spontaneous at high temperature, may become spontaneous at low temperature.
Reason :
With decrease in temperature. randomness (entropy) increases.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369415 Assertion :
The thermodynamic function which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative.
Reason :
The change in free energy is related to the change in enthalpy and change in entropy. The change in entropy for a process must always be positive if it is spontaneous.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369411 Calculate the change in molar Gibb's energy of carbon dioxide gas at \(\mathrm{20^{\circ} \mathrm{C}}\) when it is isothermally expanded from 1.0 to \({\rm{2}}{\rm{.0}}\,{\rm{bar}}\)

1 \(\mathrm{2.4 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-2.4 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{1.7 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{-1.7 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369412 Which of the following is not correct?

1 \(\mathrm{\Delta G}\) is zero for a reversible reaction.
2 \(\mathrm{\Delta \mathrm{G}}\) is positive for a spontaneous reaction.
3 \(\mathrm{\Delta \mathrm{G}}\) is negative for a spontaneous reaction.
4 \(\mathrm{\Delta \mathrm{G}}\) is positive for a non-spontaneous reaction.
CHXI06:THERMODYNAMICS

369413 \(\mathrm{\Delta G=-177 \mathrm{kcal}}\) for \(\mathrm{2 \mathrm{Fe}_{(s)}+\dfrac{3}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}}\) and \(\mathrm{\Delta G=-19 \mathrm{kcal}}\) for \(\mathrm{4 \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}+\mathrm{Fe}_{(\mathrm{s})}}\) \(\mathrm{\rightarrow 3 \mathrm{Fe}_{3} \mathrm{O}_{4(\mathrm{~s})}}\)
what is the Gibb's free energy of formation of \(\mathrm{\mathrm{Fe}_{3} \mathrm{O}_{4}}\) ?

1 \(\mathrm{+229.6 \mathrm{kcal} / \mathrm{mol}}\)
2 \(\mathrm{-242.4 \mathrm{kcal} / \mathrm{mol}}\)
3 \(\mathrm{-727 \mathrm{kcal} / \mathrm{mol}}\)
4 \(\mathrm{-229.6 \mathrm{kcal} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369414 Assertion :
An exothermic process, non-spontaneous at high temperature, may become spontaneous at low temperature.
Reason :
With decrease in temperature. randomness (entropy) increases.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369415 Assertion :
The thermodynamic function which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative.
Reason :
The change in free energy is related to the change in enthalpy and change in entropy. The change in entropy for a process must always be positive if it is spontaneous.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369411 Calculate the change in molar Gibb's energy of carbon dioxide gas at \(\mathrm{20^{\circ} \mathrm{C}}\) when it is isothermally expanded from 1.0 to \({\rm{2}}{\rm{.0}}\,{\rm{bar}}\)

1 \(\mathrm{2.4 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-2.4 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{1.7 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{-1.7 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369412 Which of the following is not correct?

1 \(\mathrm{\Delta G}\) is zero for a reversible reaction.
2 \(\mathrm{\Delta \mathrm{G}}\) is positive for a spontaneous reaction.
3 \(\mathrm{\Delta \mathrm{G}}\) is negative for a spontaneous reaction.
4 \(\mathrm{\Delta \mathrm{G}}\) is positive for a non-spontaneous reaction.
CHXI06:THERMODYNAMICS

369413 \(\mathrm{\Delta G=-177 \mathrm{kcal}}\) for \(\mathrm{2 \mathrm{Fe}_{(s)}+\dfrac{3}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}}\) and \(\mathrm{\Delta G=-19 \mathrm{kcal}}\) for \(\mathrm{4 \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}+\mathrm{Fe}_{(\mathrm{s})}}\) \(\mathrm{\rightarrow 3 \mathrm{Fe}_{3} \mathrm{O}_{4(\mathrm{~s})}}\)
what is the Gibb's free energy of formation of \(\mathrm{\mathrm{Fe}_{3} \mathrm{O}_{4}}\) ?

1 \(\mathrm{+229.6 \mathrm{kcal} / \mathrm{mol}}\)
2 \(\mathrm{-242.4 \mathrm{kcal} / \mathrm{mol}}\)
3 \(\mathrm{-727 \mathrm{kcal} / \mathrm{mol}}\)
4 \(\mathrm{-229.6 \mathrm{kcal} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369414 Assertion :
An exothermic process, non-spontaneous at high temperature, may become spontaneous at low temperature.
Reason :
With decrease in temperature. randomness (entropy) increases.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369415 Assertion :
The thermodynamic function which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative.
Reason :
The change in free energy is related to the change in enthalpy and change in entropy. The change in entropy for a process must always be positive if it is spontaneous.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369411 Calculate the change in molar Gibb's energy of carbon dioxide gas at \(\mathrm{20^{\circ} \mathrm{C}}\) when it is isothermally expanded from 1.0 to \({\rm{2}}{\rm{.0}}\,{\rm{bar}}\)

1 \(\mathrm{2.4 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-2.4 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{1.7 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{-1.7 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369412 Which of the following is not correct?

1 \(\mathrm{\Delta G}\) is zero for a reversible reaction.
2 \(\mathrm{\Delta \mathrm{G}}\) is positive for a spontaneous reaction.
3 \(\mathrm{\Delta \mathrm{G}}\) is negative for a spontaneous reaction.
4 \(\mathrm{\Delta \mathrm{G}}\) is positive for a non-spontaneous reaction.
CHXI06:THERMODYNAMICS

369413 \(\mathrm{\Delta G=-177 \mathrm{kcal}}\) for \(\mathrm{2 \mathrm{Fe}_{(s)}+\dfrac{3}{2} \mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}}\) and \(\mathrm{\Delta G=-19 \mathrm{kcal}}\) for \(\mathrm{4 \mathrm{Fe}_{2} \mathrm{O}_{3(\mathrm{~s})}+\mathrm{Fe}_{(\mathrm{s})}}\) \(\mathrm{\rightarrow 3 \mathrm{Fe}_{3} \mathrm{O}_{4(\mathrm{~s})}}\)
what is the Gibb's free energy of formation of \(\mathrm{\mathrm{Fe}_{3} \mathrm{O}_{4}}\) ?

1 \(\mathrm{+229.6 \mathrm{kcal} / \mathrm{mol}}\)
2 \(\mathrm{-242.4 \mathrm{kcal} / \mathrm{mol}}\)
3 \(\mathrm{-727 \mathrm{kcal} / \mathrm{mol}}\)
4 \(\mathrm{-229.6 \mathrm{kcal} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369414 Assertion :
An exothermic process, non-spontaneous at high temperature, may become spontaneous at low temperature.
Reason :
With decrease in temperature. randomness (entropy) increases.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI06:THERMODYNAMICS

369415 Assertion :
The thermodynamic function which determines the spontaneity of a process is the free energy. For a process to be spontaneous, the change in free energy must be negative.
Reason :
The change in free energy is related to the change in enthalpy and change in entropy. The change in entropy for a process must always be positive if it is spontaneous.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.