10. HALOALKANES AND HALOARENES[KARNATAKA CET EXCLUSIVE]
CHEMISTRY(KCET)

285527 In the reaction
\(\text { 至BBr }+\mathrm{CH}_3 \mathrm{NH}_2 \xrightarrow{\text { Dry ether }} \mathrm{X}\)
The number of possible isomers for the organic compound \(X\) is

1 5
2 3
3 2 .
4 4
CHEMISTRY(KCET)

285528 Prolonged exposure of chloroform in humans may cause damage to liver. It is due to the formation of the following compound

1 \(\mathrm{COCl}_2\)
2 \(\mathrm{CH}_2 \mathrm{Cl}_2\)
3 \(\mathrm{Cl}_2\)
4 \(\mathrm{CCl}_4\)
CHEMISTRY(KCET)

285529 Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?

Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .

CHEMISTRY(KCET)

285530 The compound having longest\(\mathrm{C}-\mathrm{Cl}\) bond is

1 \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl}\)
CHEMISTRY(KCET)

285531 Which of the following statements is true in case of alkyl halides?

1 They are polar in nature.
2 They can form hydrogen bonds.
3 They are highly soluble in water.
4 They undergo addition reactions.
CHEMISTRY(KCET)

285527 In the reaction
\(\text { 至BBr }+\mathrm{CH}_3 \mathrm{NH}_2 \xrightarrow{\text { Dry ether }} \mathrm{X}\)
The number of possible isomers for the organic compound \(X\) is

1 5
2 3
3 2 .
4 4
CHEMISTRY(KCET)

285528 Prolonged exposure of chloroform in humans may cause damage to liver. It is due to the formation of the following compound

1 \(\mathrm{COCl}_2\)
2 \(\mathrm{CH}_2 \mathrm{Cl}_2\)
3 \(\mathrm{Cl}_2\)
4 \(\mathrm{CCl}_4\)
CHEMISTRY(KCET)

285529 Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?

Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .

CHEMISTRY(KCET)

285530 The compound having longest\(\mathrm{C}-\mathrm{Cl}\) bond is

1 \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl}\)
CHEMISTRY(KCET)

285531 Which of the following statements is true in case of alkyl halides?

1 They are polar in nature.
2 They can form hydrogen bonds.
3 They are highly soluble in water.
4 They undergo addition reactions.
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHEMISTRY(KCET)

285527 In the reaction
\(\text { 至BBr }+\mathrm{CH}_3 \mathrm{NH}_2 \xrightarrow{\text { Dry ether }} \mathrm{X}\)
The number of possible isomers for the organic compound \(X\) is

1 5
2 3
3 2 .
4 4
CHEMISTRY(KCET)

285528 Prolonged exposure of chloroform in humans may cause damage to liver. It is due to the formation of the following compound

1 \(\mathrm{COCl}_2\)
2 \(\mathrm{CH}_2 \mathrm{Cl}_2\)
3 \(\mathrm{Cl}_2\)
4 \(\mathrm{CCl}_4\)
CHEMISTRY(KCET)

285529 Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?

Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .

CHEMISTRY(KCET)

285530 The compound having longest\(\mathrm{C}-\mathrm{Cl}\) bond is

1 \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl}\)
CHEMISTRY(KCET)

285531 Which of the following statements is true in case of alkyl halides?

1 They are polar in nature.
2 They can form hydrogen bonds.
3 They are highly soluble in water.
4 They undergo addition reactions.
CHEMISTRY(KCET)

285527 In the reaction
\(\text { 至BBr }+\mathrm{CH}_3 \mathrm{NH}_2 \xrightarrow{\text { Dry ether }} \mathrm{X}\)
The number of possible isomers for the organic compound \(X\) is

1 5
2 3
3 2 .
4 4
CHEMISTRY(KCET)

285528 Prolonged exposure of chloroform in humans may cause damage to liver. It is due to the formation of the following compound

1 \(\mathrm{COCl}_2\)
2 \(\mathrm{CH}_2 \mathrm{Cl}_2\)
3 \(\mathrm{Cl}_2\)
4 \(\mathrm{CCl}_4\)
CHEMISTRY(KCET)

285529 Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?

Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .

CHEMISTRY(KCET)

285530 The compound having longest\(\mathrm{C}-\mathrm{Cl}\) bond is

1 \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl}\)
CHEMISTRY(KCET)

285531 Which of the following statements is true in case of alkyl halides?

1 They are polar in nature.
2 They can form hydrogen bonds.
3 They are highly soluble in water.
4 They undergo addition reactions.
CHEMISTRY(KCET)

285527 In the reaction
\(\text { 至BBr }+\mathrm{CH}_3 \mathrm{NH}_2 \xrightarrow{\text { Dry ether }} \mathrm{X}\)
The number of possible isomers for the organic compound \(X\) is

1 5
2 3
3 2 .
4 4
CHEMISTRY(KCET)

285528 Prolonged exposure of chloroform in humans may cause damage to liver. It is due to the formation of the following compound

1 \(\mathrm{COCl}_2\)
2 \(\mathrm{CH}_2 \mathrm{Cl}_2\)
3 \(\mathrm{Cl}_2\)
4 \(\mathrm{CCl}_4\)
CHEMISTRY(KCET)

285529 Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?

Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .

CHEMISTRY(KCET)

285530 The compound having longest\(\mathrm{C}-\mathrm{Cl}\) bond is

1 \(\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl}\)
CHEMISTRY(KCET)

285531 Which of the following statements is true in case of alkyl halides?

1 They are polar in nature.
2 They can form hydrogen bonds.
3 They are highly soluble in water.
4 They undergo addition reactions.