285529
Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?
Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .
285529
Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?
Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .
285529
Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?
Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .
285529
Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?
Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .
285529
Which of the following halides undergoes hydrolysis on warming with water/aqueous NaOH ?
Ans:d
Exp:(d) Chlorobenzene does not react with aqueous NaOH at room temperature but presence of electron withdrawing groups like\(-\mathrm{NO}_2,-\mathrm{CN}\), at ortho or para position enhance the reactivity of aryl halides towards nucleophilic substitution.
Further, greater the number of such groups at oand \(p\)-position wr.t. the halogen, more reactive is the haloarene. Hence, 1-chloro-2, 4, 6trinitrobenzene will be hydrolysed the most on warming with water/aqueous NaOH .