04. CHEMICAL KINETICS[KARNATAKA CET EXCLUSIVE]
CHEMISTRY(KCET)

285415 In which one of the following reactions, rate constant has the unit mol L \({ }^{-1} \mathrm{~s}^{-1}\) ?

1 Acid catalysed hydrolysis of \(\mathrm{CH}_3 \mathrm{COOCH}_3\)
2 \(\mathrm{CHCl}_3+\mathrm{Cl}_2 \longrightarrow \mathrm{CCl}_4+\mathrm{HCl}\)
3 2 NO (g) \(+\mathrm{O}_2\) (g) \(\longrightarrow 2 \mathrm{NO}_2\) (g)
4 Decomposition of HI on the surface of Gold
CHEMISTRY(KCET)

285416 For a reaction, the value of rate constant at 300 K is \(6.0 \times 10^5 \mathrm{~s}^{-1}\). The value of Arrhenius factor A at infinitely high temperature is:

1 \(6 \times 15^5 \times \mathrm{e}^{-\mathrm{E}^2 / 300 \mathrm{R}}\)
2 \(\mathrm{e}^{-\mathrm{E}_{\mathrm{a}} / 300 \mathrm{R}}\)
3 \(\frac{6 \times 10^{-5}}{300}\)
4 \(6 \times 10^5\)
CHEMISTRY(KCET)

285417 The rate constants \(\mathrm{k}_1\) and \(\mathrm{k}_2\) for two different reactions are \(10^{16} \times \mathrm{e}^{-2000 / \mathrm{T}}\) and \(10^{15} \times \mathrm{e}^{-1000 / \mathrm{T}}\) respectively. The temperature at which \(k_1=k_2\) is:

1 \(\frac{2000}{2.303} \mathrm{~K}\)
2 2000 K
3 \(\frac{1000}{2.303} \mathrm{~K}\)
4 1000 K
CHEMISTRY(KCET)

285418 A first order reaction is half completed in 45 min . How long it need \(99.9 \%\) of the reaction to be completed?

1 10 hours
2 20 hours
3 5 hours
4 7.5 hours
CHEMISTRY(KCET)

285415 In which one of the following reactions, rate constant has the unit mol L \({ }^{-1} \mathrm{~s}^{-1}\) ?

1 Acid catalysed hydrolysis of \(\mathrm{CH}_3 \mathrm{COOCH}_3\)
2 \(\mathrm{CHCl}_3+\mathrm{Cl}_2 \longrightarrow \mathrm{CCl}_4+\mathrm{HCl}\)
3 2 NO (g) \(+\mathrm{O}_2\) (g) \(\longrightarrow 2 \mathrm{NO}_2\) (g)
4 Decomposition of HI on the surface of Gold
CHEMISTRY(KCET)

285416 For a reaction, the value of rate constant at 300 K is \(6.0 \times 10^5 \mathrm{~s}^{-1}\). The value of Arrhenius factor A at infinitely high temperature is:

1 \(6 \times 15^5 \times \mathrm{e}^{-\mathrm{E}^2 / 300 \mathrm{R}}\)
2 \(\mathrm{e}^{-\mathrm{E}_{\mathrm{a}} / 300 \mathrm{R}}\)
3 \(\frac{6 \times 10^{-5}}{300}\)
4 \(6 \times 10^5\)
CHEMISTRY(KCET)

285417 The rate constants \(\mathrm{k}_1\) and \(\mathrm{k}_2\) for two different reactions are \(10^{16} \times \mathrm{e}^{-2000 / \mathrm{T}}\) and \(10^{15} \times \mathrm{e}^{-1000 / \mathrm{T}}\) respectively. The temperature at which \(k_1=k_2\) is:

1 \(\frac{2000}{2.303} \mathrm{~K}\)
2 2000 K
3 \(\frac{1000}{2.303} \mathrm{~K}\)
4 1000 K
CHEMISTRY(KCET)

285418 A first order reaction is half completed in 45 min . How long it need \(99.9 \%\) of the reaction to be completed?

1 10 hours
2 20 hours
3 5 hours
4 7.5 hours
CHEMISTRY(KCET)

285415 In which one of the following reactions, rate constant has the unit mol L \({ }^{-1} \mathrm{~s}^{-1}\) ?

1 Acid catalysed hydrolysis of \(\mathrm{CH}_3 \mathrm{COOCH}_3\)
2 \(\mathrm{CHCl}_3+\mathrm{Cl}_2 \longrightarrow \mathrm{CCl}_4+\mathrm{HCl}\)
3 2 NO (g) \(+\mathrm{O}_2\) (g) \(\longrightarrow 2 \mathrm{NO}_2\) (g)
4 Decomposition of HI on the surface of Gold
CHEMISTRY(KCET)

285416 For a reaction, the value of rate constant at 300 K is \(6.0 \times 10^5 \mathrm{~s}^{-1}\). The value of Arrhenius factor A at infinitely high temperature is:

1 \(6 \times 15^5 \times \mathrm{e}^{-\mathrm{E}^2 / 300 \mathrm{R}}\)
2 \(\mathrm{e}^{-\mathrm{E}_{\mathrm{a}} / 300 \mathrm{R}}\)
3 \(\frac{6 \times 10^{-5}}{300}\)
4 \(6 \times 10^5\)
CHEMISTRY(KCET)

285417 The rate constants \(\mathrm{k}_1\) and \(\mathrm{k}_2\) for two different reactions are \(10^{16} \times \mathrm{e}^{-2000 / \mathrm{T}}\) and \(10^{15} \times \mathrm{e}^{-1000 / \mathrm{T}}\) respectively. The temperature at which \(k_1=k_2\) is:

1 \(\frac{2000}{2.303} \mathrm{~K}\)
2 2000 K
3 \(\frac{1000}{2.303} \mathrm{~K}\)
4 1000 K
CHEMISTRY(KCET)

285418 A first order reaction is half completed in 45 min . How long it need \(99.9 \%\) of the reaction to be completed?

1 10 hours
2 20 hours
3 5 hours
4 7.5 hours
CHEMISTRY(KCET)

285415 In which one of the following reactions, rate constant has the unit mol L \({ }^{-1} \mathrm{~s}^{-1}\) ?

1 Acid catalysed hydrolysis of \(\mathrm{CH}_3 \mathrm{COOCH}_3\)
2 \(\mathrm{CHCl}_3+\mathrm{Cl}_2 \longrightarrow \mathrm{CCl}_4+\mathrm{HCl}\)
3 2 NO (g) \(+\mathrm{O}_2\) (g) \(\longrightarrow 2 \mathrm{NO}_2\) (g)
4 Decomposition of HI on the surface of Gold
CHEMISTRY(KCET)

285416 For a reaction, the value of rate constant at 300 K is \(6.0 \times 10^5 \mathrm{~s}^{-1}\). The value of Arrhenius factor A at infinitely high temperature is:

1 \(6 \times 15^5 \times \mathrm{e}^{-\mathrm{E}^2 / 300 \mathrm{R}}\)
2 \(\mathrm{e}^{-\mathrm{E}_{\mathrm{a}} / 300 \mathrm{R}}\)
3 \(\frac{6 \times 10^{-5}}{300}\)
4 \(6 \times 10^5\)
CHEMISTRY(KCET)

285417 The rate constants \(\mathrm{k}_1\) and \(\mathrm{k}_2\) for two different reactions are \(10^{16} \times \mathrm{e}^{-2000 / \mathrm{T}}\) and \(10^{15} \times \mathrm{e}^{-1000 / \mathrm{T}}\) respectively. The temperature at which \(k_1=k_2\) is:

1 \(\frac{2000}{2.303} \mathrm{~K}\)
2 2000 K
3 \(\frac{1000}{2.303} \mathrm{~K}\)
4 1000 K
CHEMISTRY(KCET)

285418 A first order reaction is half completed in 45 min . How long it need \(99.9 \%\) of the reaction to be completed?

1 10 hours
2 20 hours
3 5 hours
4 7.5 hours