4. Isomerism
GENERAL ORGANIC CHEMISTRY

232004 Which one of the following is not having two chiral centres?

1 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}(\mathrm{OH})-\mathrm{CH}_{3}$
2 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{3}$
3 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Cl})-\mathrm{CH}_{3}$
4 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
GENERAL ORGANIC CHEMISTRY

232005 Which one of the following of 2,3-butane diol is enantiomeric?

1 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{~S}, 3 \mathrm{~S}$
2 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{~S}, 3 \mathrm{R}$
3 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
4 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
GENERAL ORGANIC CHEMISTRY

232011 Which of the following structures represents a chiral compound?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

232013 Which of the following complexes can also represent facial (fac) and meridional (mer) isomers?

1 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]$
2 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{NO}_{2} \mathrm{Cl}\right]$
3 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{2}\right]$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}\right]$
GENERAL ORGANIC CHEMISTRY

232014 Maximum number of $\sigma$-bonds that may be present in an isomer of $\mathrm{C}_{4} \mathrm{H}_{8}$ are

1 10
2 11
3 12
4 13
GENERAL ORGANIC CHEMISTRY

232004 Which one of the following is not having two chiral centres?

1 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}(\mathrm{OH})-\mathrm{CH}_{3}$
2 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{3}$
3 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Cl})-\mathrm{CH}_{3}$
4 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
GENERAL ORGANIC CHEMISTRY

232005 Which one of the following of 2,3-butane diol is enantiomeric?

1 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{~S}, 3 \mathrm{~S}$
2 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{~S}, 3 \mathrm{R}$
3 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
4 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
GENERAL ORGANIC CHEMISTRY

232011 Which of the following structures represents a chiral compound?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

232013 Which of the following complexes can also represent facial (fac) and meridional (mer) isomers?

1 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]$
2 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{NO}_{2} \mathrm{Cl}\right]$
3 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{2}\right]$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}\right]$
GENERAL ORGANIC CHEMISTRY

232014 Maximum number of $\sigma$-bonds that may be present in an isomer of $\mathrm{C}_{4} \mathrm{H}_{8}$ are

1 10
2 11
3 12
4 13
GENERAL ORGANIC CHEMISTRY

232004 Which one of the following is not having two chiral centres?

1 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}(\mathrm{OH})-\mathrm{CH}_{3}$
2 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{3}$
3 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Cl})-\mathrm{CH}_{3}$
4 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
GENERAL ORGANIC CHEMISTRY

232005 Which one of the following of 2,3-butane diol is enantiomeric?

1 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{~S}, 3 \mathrm{~S}$
2 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{~S}, 3 \mathrm{R}$
3 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
4 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
GENERAL ORGANIC CHEMISTRY

232011 Which of the following structures represents a chiral compound?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

232013 Which of the following complexes can also represent facial (fac) and meridional (mer) isomers?

1 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]$
2 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{NO}_{2} \mathrm{Cl}\right]$
3 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{2}\right]$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}\right]$
GENERAL ORGANIC CHEMISTRY

232014 Maximum number of $\sigma$-bonds that may be present in an isomer of $\mathrm{C}_{4} \mathrm{H}_{8}$ are

1 10
2 11
3 12
4 13
GENERAL ORGANIC CHEMISTRY

232004 Which one of the following is not having two chiral centres?

1 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}(\mathrm{OH})-\mathrm{CH}_{3}$
2 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{3}$
3 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Cl})-\mathrm{CH}_{3}$
4 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
GENERAL ORGANIC CHEMISTRY

232005 Which one of the following of 2,3-butane diol is enantiomeric?

1 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{~S}, 3 \mathrm{~S}$
2 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{~S}, 3 \mathrm{R}$
3 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
4 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
GENERAL ORGANIC CHEMISTRY

232011 Which of the following structures represents a chiral compound?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

232013 Which of the following complexes can also represent facial (fac) and meridional (mer) isomers?

1 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]$
2 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{NO}_{2} \mathrm{Cl}\right]$
3 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{2}\right]$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}\right]$
GENERAL ORGANIC CHEMISTRY

232014 Maximum number of $\sigma$-bonds that may be present in an isomer of $\mathrm{C}_{4} \mathrm{H}_{8}$ are

1 10
2 11
3 12
4 13
GENERAL ORGANIC CHEMISTRY

232004 Which one of the following is not having two chiral centres?

1 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}(\mathrm{OH})-\mathrm{CH}_{3}$
2 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Br})-\mathrm{CH}_{3}$
3 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}(\mathrm{Cl})-\mathrm{CH}_{3}$
4 $\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}\left(\mathrm{NH}_{2}\right)-\mathrm{CH}_{2}-\mathrm{CH}_{3}$
GENERAL ORGANIC CHEMISTRY

232005 Which one of the following of 2,3-butane diol is enantiomeric?

1 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{~S}, 3 \mathrm{~S}$
2 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{~S}, 3 \mathrm{R}$
3 $2 \mathrm{R}, 3 \mathrm{R}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
4 $2 \mathrm{~S}, 3 \mathrm{~S}$ and $2 \mathrm{R}, 3 \mathrm{~S}$
GENERAL ORGANIC CHEMISTRY

232011 Which of the following structures represents a chiral compound?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

232013 Which of the following complexes can also represent facial (fac) and meridional (mer) isomers?

1 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]$
2 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{NO}_{2} \mathrm{Cl}\right]$
3 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}_{2}\right]$
4 $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{2}\left(\mathrm{NO}_{2}\right)_{3} \mathrm{Cl}\right]$
GENERAL ORGANIC CHEMISTRY

232014 Maximum number of $\sigma$-bonds that may be present in an isomer of $\mathrm{C}_{4} \mathrm{H}_{8}$ are

1 10
2 11
3 12
4 13