\(CH_3COOH < ClCH_2COOH < Cl_2CH_2COOH < Cl_3CCOOH\) Increasing order of acidic nature.
ALDEHYDES, KETONES AND CARBOXYLIC ACID
28096
Consider the acidity of the carboxylic acids Which of the following order is correct?\((a)\) \(PhCOOH\)\((B)\) \(o-NO_2C_6H_4COOH\)\((C)\) \(p-NO_2C_6H_4COOH\)\((D)\) \(m-NO_2C_6H_4COOH\)
1 \(b > d > a > c\)
2 \(b > d > c > a\)
3 \(a > b > c > d\)
4 \(b > c > d > a\)
Explanation:
(d)
Electron withdrawing group, increases the acidity of benzoic acid, \(O-\) isomer will have higher acidity then corresponding \(m\) and \(p-\) isomer due to ortho effect.
\(CH_3COOH < ClCH_2COOH < Cl_2CH_2COOH < Cl_3CCOOH\) Increasing order of acidic nature.
ALDEHYDES, KETONES AND CARBOXYLIC ACID
28096
Consider the acidity of the carboxylic acids Which of the following order is correct?\((a)\) \(PhCOOH\)\((B)\) \(o-NO_2C_6H_4COOH\)\((C)\) \(p-NO_2C_6H_4COOH\)\((D)\) \(m-NO_2C_6H_4COOH\)
1 \(b > d > a > c\)
2 \(b > d > c > a\)
3 \(a > b > c > d\)
4 \(b > c > d > a\)
Explanation:
(d)
Electron withdrawing group, increases the acidity of benzoic acid, \(O-\) isomer will have higher acidity then corresponding \(m\) and \(p-\) isomer due to ortho effect.
\(CH_3COOH < ClCH_2COOH < Cl_2CH_2COOH < Cl_3CCOOH\) Increasing order of acidic nature.
ALDEHYDES, KETONES AND CARBOXYLIC ACID
28096
Consider the acidity of the carboxylic acids Which of the following order is correct?\((a)\) \(PhCOOH\)\((B)\) \(o-NO_2C_6H_4COOH\)\((C)\) \(p-NO_2C_6H_4COOH\)\((D)\) \(m-NO_2C_6H_4COOH\)
1 \(b > d > a > c\)
2 \(b > d > c > a\)
3 \(a > b > c > d\)
4 \(b > c > d > a\)
Explanation:
(d)
Electron withdrawing group, increases the acidity of benzoic acid, \(O-\) isomer will have higher acidity then corresponding \(m\) and \(p-\) isomer due to ortho effect.
\(CH_3COOH < ClCH_2COOH < Cl_2CH_2COOH < Cl_3CCOOH\) Increasing order of acidic nature.
ALDEHYDES, KETONES AND CARBOXYLIC ACID
28096
Consider the acidity of the carboxylic acids Which of the following order is correct?\((a)\) \(PhCOOH\)\((B)\) \(o-NO_2C_6H_4COOH\)\((C)\) \(p-NO_2C_6H_4COOH\)\((D)\) \(m-NO_2C_6H_4COOH\)
1 \(b > d > a > c\)
2 \(b > d > c > a\)
3 \(a > b > c > d\)
4 \(b > c > d > a\)
Explanation:
(d)
Electron withdrawing group, increases the acidity of benzoic acid, \(O-\) isomer will have higher acidity then corresponding \(m\) and \(p-\) isomer due to ortho effect.