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ALDEHYDES, KETONES AND CARBOXYLIC ACID

28330 Find product $V$ is $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\to_{H_{3} O^{+}}^{L i A l H_{4}}$ $I \overset{P B r_{3}}{\to} I I \to_{e t h e r}^{M g}$ $I I I \overset{C O_{2}}{\to} I V \overset{H_{2} O^{+} / H^{+}}{\to} V$

1

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} B r \end{matrix}

2

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C - C O O H \\ | \\ B r \end{matrix}

3

\begin{matrix} C H_{3} & O \\ | & | | \\ C H_{3} - C H - C H_{2} - O - & C - H \end{matrix}

4

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}

Explanation:

$\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\overset{L i A l H_{4}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - O H \end{matrix}$ $\overset{P B r_{3}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - B r \end{matrix}$ $\overset{M g / e t h e r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - M g . B r \end{matrix}$ $\overset{C O_{2} / H B r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}$

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28331 Match the column $I$ with column $I I$ to identify the products of oxidation of alkanes and mark the appropriate choiceColumn $I$

Column $I I$

$(A)$
${(C H_{3})}_{3} C H + 2 O_{2} \to_{[O]}^{K M n O_{4}}$
$(i)$
$C H_{3} C O O H + H_{2} O$

$(B)$
$2 C H_{4} + O_{2} \to_{100 a t m}^{C u / 523 K}$
$(i i)$
$(C H_{3})_{3} C O H$

$(C)$
$C H_{4} + O_{2} \to_{Δ}^{M o_{2} O_{3}}$
$(i i i)$
$2 C H_{3} O H$

$(D)$
$C H_{3} - C H_{3} + \frac{3}{2} O_{2} \overset{{(C H_{3} C O O)}_{2} M n}{\to}$
$(i v)$
$H C H O + H_{2} O$

1

(A) \to (i), (B) \to (i i), (C) \to (i i i), (D) \to (i v)

2

(A) \to (i i), (B) \to (i i i), (C) \to (i v), (D) \to (i)

3

(A) \to (i v), (B) \to (i i), (C) \to (i i i), (D) \to (i)

4

(A) \to (i i i), (B) \to (i), (C) \to (i i), (D) \to (i v)

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28332 Which compound on oxidation with acidic $K M n O_{4}$ give Benzoic acid

1

2

3

4 All of these

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28333 Tribasic acid is

1 Succinic acid

2 Tartaric acid

3 Citric acid

4 Adipic acid

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28330 Find product $V$ is $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\to_{H_{3} O^{+}}^{L i A l H_{4}}$ $I \overset{P B r_{3}}{\to} I I \to_{e t h e r}^{M g}$ $I I I \overset{C O_{2}}{\to} I V \overset{H_{2} O^{+} / H^{+}}{\to} V$

1

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} B r \end{matrix}

2

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C - C O O H \\ | \\ B r \end{matrix}

3

\begin{matrix} C H_{3} & O \\ | & | | \\ C H_{3} - C H - C H_{2} - O - & C - H \end{matrix}

4

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}

Explanation:

$\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\overset{L i A l H_{4}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - O H \end{matrix}$ $\overset{P B r_{3}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - B r \end{matrix}$ $\overset{M g / e t h e r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - M g . B r \end{matrix}$ $\overset{C O_{2} / H B r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}$

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28331 Match the column $I$ with column $I I$ to identify the products of oxidation of alkanes and mark the appropriate choiceColumn $I$

Column $I I$

$(A)$
${(C H_{3})}_{3} C H + 2 O_{2} \to_{[O]}^{K M n O_{4}}$
$(i)$
$C H_{3} C O O H + H_{2} O$

$(B)$
$2 C H_{4} + O_{2} \to_{100 a t m}^{C u / 523 K}$
$(i i)$
$(C H_{3})_{3} C O H$

$(C)$
$C H_{4} + O_{2} \to_{Δ}^{M o_{2} O_{3}}$
$(i i i)$
$2 C H_{3} O H$

$(D)$
$C H_{3} - C H_{3} + \frac{3}{2} O_{2} \overset{{(C H_{3} C O O)}_{2} M n}{\to}$
$(i v)$
$H C H O + H_{2} O$

1

(A) \to (i), (B) \to (i i), (C) \to (i i i), (D) \to (i v)

2

(A) \to (i i), (B) \to (i i i), (C) \to (i v), (D) \to (i)

3

(A) \to (i v), (B) \to (i i), (C) \to (i i i), (D) \to (i)

4

(A) \to (i i i), (B) \to (i), (C) \to (i i), (D) \to (i v)

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28332 Which compound on oxidation with acidic $K M n O_{4}$ give Benzoic acid

1

2

3

4 All of these

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28333 Tribasic acid is

1 Succinic acid

2 Tartaric acid

3 Citric acid

4 Adipic acid

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28330 Find product $V$ is $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\to_{H_{3} O^{+}}^{L i A l H_{4}}$ $I \overset{P B r_{3}}{\to} I I \to_{e t h e r}^{M g}$ $I I I \overset{C O_{2}}{\to} I V \overset{H_{2} O^{+} / H^{+}}{\to} V$

1

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} B r \end{matrix}

2

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C - C O O H \\ | \\ B r \end{matrix}

3

\begin{matrix} C H_{3} & O \\ | & | | \\ C H_{3} - C H - C H_{2} - O - & C - H \end{matrix}

4

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}

Explanation:

$\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\overset{L i A l H_{4}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - O H \end{matrix}$ $\overset{P B r_{3}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - B r \end{matrix}$ $\overset{M g / e t h e r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - M g . B r \end{matrix}$ $\overset{C O_{2} / H B r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}$

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28331 Match the column $I$ with column $I I$ to identify the products of oxidation of alkanes and mark the appropriate choiceColumn $I$

Column $I I$

$(A)$
${(C H_{3})}_{3} C H + 2 O_{2} \to_{[O]}^{K M n O_{4}}$
$(i)$
$C H_{3} C O O H + H_{2} O$

$(B)$
$2 C H_{4} + O_{2} \to_{100 a t m}^{C u / 523 K}$
$(i i)$
$(C H_{3})_{3} C O H$

$(C)$
$C H_{4} + O_{2} \to_{Δ}^{M o_{2} O_{3}}$
$(i i i)$
$2 C H_{3} O H$

$(D)$
$C H_{3} - C H_{3} + \frac{3}{2} O_{2} \overset{{(C H_{3} C O O)}_{2} M n}{\to}$
$(i v)$
$H C H O + H_{2} O$

1

(A) \to (i), (B) \to (i i), (C) \to (i i i), (D) \to (i v)

2

(A) \to (i i), (B) \to (i i i), (C) \to (i v), (D) \to (i)

3

(A) \to (i v), (B) \to (i i), (C) \to (i i i), (D) \to (i)

4

(A) \to (i i i), (B) \to (i), (C) \to (i i), (D) \to (i v)

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28332 Which compound on oxidation with acidic $K M n O_{4}$ give Benzoic acid

1

2

3

4 All of these

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28333 Tribasic acid is

1 Succinic acid

2 Tartaric acid

3 Citric acid

4 Adipic acid

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28330 Find product $V$ is $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\to_{H_{3} O^{+}}^{L i A l H_{4}}$ $I \overset{P B r_{3}}{\to} I I \to_{e t h e r}^{M g}$ $I I I \overset{C O_{2}}{\to} I V \overset{H_{2} O^{+} / H^{+}}{\to} V$

1

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} B r \end{matrix}

2

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C - C O O H \\ | \\ B r \end{matrix}

3

\begin{matrix} C H_{3} & O \\ | & | | \\ C H_{3} - C H - C H_{2} - O - & C - H \end{matrix}

4

\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}

Explanation:

$\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C O O H \end{matrix}$ $\overset{L i A l H_{4}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - O H \end{matrix}$ $\overset{P B r_{3}}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - B r \end{matrix}$ $\overset{M g / e t h e r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - M g . B r \end{matrix}$ $\overset{C O_{2} / H B r}{\to}$ $\begin{matrix} C H_{3} \\ | \\ C H_{3} - C H - C H_{2} - C O O H \end{matrix}$

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28331 Match the column $I$ with column $I I$ to identify the products of oxidation of alkanes and mark the appropriate choiceColumn $I$

Column $I I$

$(A)$
${(C H_{3})}_{3} C H + 2 O_{2} \to_{[O]}^{K M n O_{4}}$
$(i)$
$C H_{3} C O O H + H_{2} O$

$(B)$
$2 C H_{4} + O_{2} \to_{100 a t m}^{C u / 523 K}$
$(i i)$
$(C H_{3})_{3} C O H$

$(C)$
$C H_{4} + O_{2} \to_{Δ}^{M o_{2} O_{3}}$
$(i i i)$
$2 C H_{3} O H$

$(D)$
$C H_{3} - C H_{3} + \frac{3}{2} O_{2} \overset{{(C H_{3} C O O)}_{2} M n}{\to}$
$(i v)$
$H C H O + H_{2} O$

1

(A) \to (i), (B) \to (i i), (C) \to (i i i), (D) \to (i v)

2

(A) \to (i i), (B) \to (i i i), (C) \to (i v), (D) \to (i)

3

(A) \to (i v), (B) \to (i i), (C) \to (i i i), (D) \to (i)

4

(A) \to (i i i), (B) \to (i), (C) \to (i i), (D) \to (i v)

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28332 Which compound on oxidation with acidic $K M n O_{4}$ give Benzoic acid

1

2

3

4 All of these

ALDEHYDES, KETONES AND CARBOXYLIC ACID

28333 Tribasic acid is

1 Succinic acid

2 Tartaric acid

3 Citric acid

4 Adipic acid