CARBOXYLIC ACIDS
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28310 The artificial sweetener aspartame \((A)\) is converted to _________ on storage for extended periods of time in aqueous solution :$\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N\limits^ \oplus   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}}\limits_{(A)} $

1 $\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}} $
2 $\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
   {{H}_{2}}N-CH-COH  \\
   |\,\,\,\,\,\,\,\,  \\
   \,\,C{{H}_{2}}\,\,\,  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   \,\,\,\,\,\,\,\,\,C{{O}_{2}}H\,\,\,\,\,\,  \\
\end{matrix}+$ $ \begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_2}NCH - COH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {C{H_2}Ph} 
\end{array} + C{H_3}OH$
3 364-c155
4 no change, remains as \((A)\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28311 Reductive amination of \(A\) forms :\(A\) :

1 364-a156
2 364-b156
3 364-c156
4 364-d156
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28312 The synthetic sweetener aspartame, known commercially as Nutra sweet, is carboxylic acid. In aqueous solution on standing it changes to :

1 364-a157
2 364-b157
3 364-c157
4 no hydrolysis is possible
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28313 Malonic acid from acetic acid can be prepared by use of which combination of chemicals, in proper sequence

1 \(HCN, \,H_3O^+\)
2 \(Br_2-\) Red \(\  P, \,KCN, \,H_3O^+\)
3 \(NaCN, \,H_3O^+\)
4 \(HOCl, \,KCN, \,H_3O^+\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28310 The artificial sweetener aspartame \((A)\) is converted to _________ on storage for extended periods of time in aqueous solution :$\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N\limits^ \oplus   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}}\limits_{(A)} $

1 $\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}} $
2 $\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
   {{H}_{2}}N-CH-COH  \\
   |\,\,\,\,\,\,\,\,  \\
   \,\,C{{H}_{2}}\,\,\,  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   \,\,\,\,\,\,\,\,\,C{{O}_{2}}H\,\,\,\,\,\,  \\
\end{matrix}+$ $ \begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_2}NCH - COH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {C{H_2}Ph} 
\end{array} + C{H_3}OH$
3 364-c155
4 no change, remains as \((A)\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28311 Reductive amination of \(A\) forms :\(A\) :

1 364-a156
2 364-b156
3 364-c156
4 364-d156
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28312 The synthetic sweetener aspartame, known commercially as Nutra sweet, is carboxylic acid. In aqueous solution on standing it changes to :

1 364-a157
2 364-b157
3 364-c157
4 no hydrolysis is possible
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28313 Malonic acid from acetic acid can be prepared by use of which combination of chemicals, in proper sequence

1 \(HCN, \,H_3O^+\)
2 \(Br_2-\) Red \(\  P, \,KCN, \,H_3O^+\)
3 \(NaCN, \,H_3O^+\)
4 \(HOCl, \,KCN, \,H_3O^+\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28310 The artificial sweetener aspartame \((A)\) is converted to _________ on storage for extended periods of time in aqueous solution :$\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N\limits^ \oplus   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}}\limits_{(A)} $

1 $\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}} $
2 $\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
   {{H}_{2}}N-CH-COH  \\
   |\,\,\,\,\,\,\,\,  \\
   \,\,C{{H}_{2}}\,\,\,  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   \,\,\,\,\,\,\,\,\,C{{O}_{2}}H\,\,\,\,\,\,  \\
\end{matrix}+$ $ \begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_2}NCH - COH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {C{H_2}Ph} 
\end{array} + C{H_3}OH$
3 364-c155
4 no change, remains as \((A)\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28311 Reductive amination of \(A\) forms :\(A\) :

1 364-a156
2 364-b156
3 364-c156
4 364-d156
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28312 The synthetic sweetener aspartame, known commercially as Nutra sweet, is carboxylic acid. In aqueous solution on standing it changes to :

1 364-a157
2 364-b157
3 364-c157
4 no hydrolysis is possible
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28313 Malonic acid from acetic acid can be prepared by use of which combination of chemicals, in proper sequence

1 \(HCN, \,H_3O^+\)
2 \(Br_2-\) Red \(\  P, \,KCN, \,H_3O^+\)
3 \(NaCN, \,H_3O^+\)
4 \(HOCl, \,KCN, \,H_3O^+\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28310 The artificial sweetener aspartame \((A)\) is converted to _________ on storage for extended periods of time in aqueous solution :$\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N\limits^ \oplus   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}}\limits_{(A)} $

1 $\mathop {\begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_3}\mathop N   - CH - C - NH - CH - C - OC{H_3}} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{H_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}Ph\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{C{O_2}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
\end{array}} $
2 $\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O  \\
   \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||  \\
   {{H}_{2}}N-CH-COH  \\
   |\,\,\,\,\,\,\,\,  \\
   \,\,C{{H}_{2}}\,\,\,  \\
   |\,\,\,\,\,\,\,\,\,\,  \\
   \,\,\,\,\,\,\,\,\,C{{O}_{2}}H\,\,\,\,\,\,  \\
\end{matrix}+$ $ \begin{array}{*{20}{c}}
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O} \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||} \\ 
  {{H_2}NCH - COH} \\ 
  {|\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
  {C{H_2}Ph} 
\end{array} + C{H_3}OH$
3 364-c155
4 no change, remains as \((A)\)
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28311 Reductive amination of \(A\) forms :\(A\) :

1 364-a156
2 364-b156
3 364-c156
4 364-d156
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28312 The synthetic sweetener aspartame, known commercially as Nutra sweet, is carboxylic acid. In aqueous solution on standing it changes to :

1 364-a157
2 364-b157
3 364-c157
4 no hydrolysis is possible
ALDEHYDES, KETONES AND CARBOXYLIC ACID

28313 Malonic acid from acetic acid can be prepared by use of which combination of chemicals, in proper sequence

1 \(HCN, \,H_3O^+\)
2 \(Br_2-\) Red \(\  P, \,KCN, \,H_3O^+\)
3 \(NaCN, \,H_3O^+\)
4 \(HOCl, \,KCN, \,H_3O^+\)