11. ALCOHOLS, PHENOLS AND ETHERS
ALCOHOLS, PHENOLS AND ETHER

15387 When a mixture of ethanol and methanol is heated in the presence of concentrated \({H_2}S{O_4}\) the resulting organic product or products is/are

1 \(C{H_3}O{C_2}{H_5}\)
2 \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
3 \(C{H_3}O{C_2}{H_5}\) and \(C{H_3}OC{H_3}\)
4 \(C{H_3}O{C_2}{H_5},\) \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
ALCOHOLS, PHENOLS AND ETHER

15388 In the following groups\(\begin{array}{*{20}{c}}{ - OAc}\\{\rm{I}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OMe}\\{{\rm{II}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}Me}\\{{\rm{III}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}C{F_3}}\\{{\rm{IV}}}\end{array}\)The order of leaving group ability is

1 \(I > II > III > IV\)
2 \(IV > III > I > II\)
3 \(III > II > I > IV\)
4 \(II > III > IV > I\)
ALCOHOLS, PHENOLS AND ETHER

15389 Epoxides are

1 Cyclic ethers
2 Not ethers
3 Aryl-alkyl ethers
4 Ethers with another functional group
ALCOHOLS, PHENOLS AND ETHER

15390 The reaction of with \(HBr\) gives

1 355-a19
2 355-b19
3 355-c19
4 355-d19
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ALCOHOLS, PHENOLS AND ETHER

15387 When a mixture of ethanol and methanol is heated in the presence of concentrated \({H_2}S{O_4}\) the resulting organic product or products is/are

1 \(C{H_3}O{C_2}{H_5}\)
2 \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
3 \(C{H_3}O{C_2}{H_5}\) and \(C{H_3}OC{H_3}\)
4 \(C{H_3}O{C_2}{H_5},\) \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
ALCOHOLS, PHENOLS AND ETHER

15388 In the following groups\(\begin{array}{*{20}{c}}{ - OAc}\\{\rm{I}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OMe}\\{{\rm{II}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}Me}\\{{\rm{III}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}C{F_3}}\\{{\rm{IV}}}\end{array}\)The order of leaving group ability is

1 \(I > II > III > IV\)
2 \(IV > III > I > II\)
3 \(III > II > I > IV\)
4 \(II > III > IV > I\)
ALCOHOLS, PHENOLS AND ETHER

15389 Epoxides are

1 Cyclic ethers
2 Not ethers
3 Aryl-alkyl ethers
4 Ethers with another functional group
ALCOHOLS, PHENOLS AND ETHER

15390 The reaction of with \(HBr\) gives

1 355-a19
2 355-b19
3 355-c19
4 355-d19
ALCOHOLS, PHENOLS AND ETHER

15387 When a mixture of ethanol and methanol is heated in the presence of concentrated \({H_2}S{O_4}\) the resulting organic product or products is/are

1 \(C{H_3}O{C_2}{H_5}\)
2 \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
3 \(C{H_3}O{C_2}{H_5}\) and \(C{H_3}OC{H_3}\)
4 \(C{H_3}O{C_2}{H_5},\) \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
ALCOHOLS, PHENOLS AND ETHER

15388 In the following groups\(\begin{array}{*{20}{c}}{ - OAc}\\{\rm{I}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OMe}\\{{\rm{II}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}Me}\\{{\rm{III}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}C{F_3}}\\{{\rm{IV}}}\end{array}\)The order of leaving group ability is

1 \(I > II > III > IV\)
2 \(IV > III > I > II\)
3 \(III > II > I > IV\)
4 \(II > III > IV > I\)
ALCOHOLS, PHENOLS AND ETHER

15389 Epoxides are

1 Cyclic ethers
2 Not ethers
3 Aryl-alkyl ethers
4 Ethers with another functional group
ALCOHOLS, PHENOLS AND ETHER

15390 The reaction of with \(HBr\) gives

1 355-a19
2 355-b19
3 355-c19
4 355-d19
ALCOHOLS, PHENOLS AND ETHER

15387 When a mixture of ethanol and methanol is heated in the presence of concentrated \({H_2}S{O_4}\) the resulting organic product or products is/are

1 \(C{H_3}O{C_2}{H_5}\)
2 \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
3 \(C{H_3}O{C_2}{H_5}\) and \(C{H_3}OC{H_3}\)
4 \(C{H_3}O{C_2}{H_5},\) \(C{H_3}OC{H_3}\) and \({C_2}{H_5}O{C_2}{H_5}\)
ALCOHOLS, PHENOLS AND ETHER

15388 In the following groups\(\begin{array}{*{20}{c}}{ - OAc}\\{\rm{I}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OMe}\\{{\rm{II}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}Me}\\{{\rm{III}}}\end{array}\)\(\begin{array}{*{20}{c}}{ - OS{O_2}C{F_3}}\\{{\rm{IV}}}\end{array}\)The order of leaving group ability is

1 \(I > II > III > IV\)
2 \(IV > III > I > II\)
3 \(III > II > I > IV\)
4 \(II > III > IV > I\)
ALCOHOLS, PHENOLS AND ETHER

15389 Epoxides are

1 Cyclic ethers
2 Not ethers
3 Aryl-alkyl ethers
4 Ethers with another functional group
ALCOHOLS, PHENOLS AND ETHER

15390 The reaction of with \(HBr\) gives

1 355-a19
2 355-b19
3 355-c19
4 355-d19