01. Resonance
GENERAL ORGANIC CHEMISTRY

231711 Identify the correct statement.

1 Reaction mechanisms are studied using isotopic labelling
2 Isolation of reactive intermediates is a method of establish reaction mechanism
3 Both (a) and (b) are correct
4 Neither (a) nor (b) are correct
GENERAL ORGANIC CHEMISTRY

231714 Relative stabilities of the following carbocations will be in the order
\[\begin{align}
& \overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{3}}\,\,\,\,\,\text{C}{{\text{H}}_{3}}\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\,\,\,\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\text{OC}{{\text{H}}_{3}} \\
& (A)\,\,\,\,\,\,\,\,\,\,\,\,\,\,(B)\,\,\,\,\,\,\,\,\,\,\,(C) \\
\end{align}\]

1 C $>$ B $>$ A
2 C $<$ B $<$ A
3 B $>$ C $>$ A
4 C $>$ A $>$ B
GENERAL ORGANIC CHEMISTRY

231719 Which one of the following reactions proceeds through free radical chain mechanism?

1 Addition of $\mathrm{HBr}$ on ethane $\rightarrow$ ionic addition reaction
$\mathrm{CH}_{2}=\mathrm{CH}_{2}+\mathrm{HBr} \rightarrow \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{Br}$
2 Halogenation of benzene in presence of $\mathrm{FeBr}_{3} \rightarrow$ Electrophilic substitution reaction
3 Photochemical chlorination of methane $\rightarrow$ free radical substitution reaction.
4 Hydrolysis with tert-butyl chloride $\rightarrow$ Nucleophic with aqueous $\mathrm{KOH} \quad$ substitution reaction
5 Addition of $\mathrm{NaHSO}_{3}$ on acetone $\rightarrow$ Nucleophic addition reaction
Hence, on the basis of above explanation option (c) is correct
original image
GENERAL ORGANIC CHEMISTRY

231721 The stablest radical among the following is

1 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow$ It has $1^{\circ}$ free radical
2 $\mathrm{CH}_{3}-\mathrm{CH}_{2} \longrightarrow$ It also has $1^{\circ}$ free radical only $3 \alpha$ Hydrogen
3 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \longrightarrow$ It has resonance as well as $3 \alpha$ - Hydrogen
$\mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}_{3} \longrightarrow 6 \alpha$ - Hydrogen $2^{\circ}$ free radical
$\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow 2 \alpha$ - Hydrogen $1^{\circ}$
So, on the basis above explanation (c) is more stable
4 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3}$
5 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}_{2}-\mathrm{CH}_{2}$
GENERAL ORGANIC CHEMISTRY

231722 The least stable free radical is

1 $\mathrm{CH}_{3} \dot{\mathrm{C}} \mathrm{H}_{2}$
2 $\mathrm{CH}_{3} \mathrm{CH}_{2} \dot{\mathrm{C}} \mathrm{H}_{2}$
3 $\left(\mathrm{CH}_{3}\right)_{2} \dot{\mathrm{C}} \mathrm{H}$
4 $\left(\mathrm{CH}_{3}\right)_{3} \dot{\mathrm{C}}$
5 $\dot{\mathrm{C}} \mathrm{H}_{3}$
GENERAL ORGANIC CHEMISTRY

231711 Identify the correct statement.

1 Reaction mechanisms are studied using isotopic labelling
2 Isolation of reactive intermediates is a method of establish reaction mechanism
3 Both (a) and (b) are correct
4 Neither (a) nor (b) are correct
GENERAL ORGANIC CHEMISTRY

231714 Relative stabilities of the following carbocations will be in the order
\[\begin{align}
& \overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{3}}\,\,\,\,\,\text{C}{{\text{H}}_{3}}\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\,\,\,\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\text{OC}{{\text{H}}_{3}} \\
& (A)\,\,\,\,\,\,\,\,\,\,\,\,\,\,(B)\,\,\,\,\,\,\,\,\,\,\,(C) \\
\end{align}\]

1 C $>$ B $>$ A
2 C $<$ B $<$ A
3 B $>$ C $>$ A
4 C $>$ A $>$ B
GENERAL ORGANIC CHEMISTRY

231719 Which one of the following reactions proceeds through free radical chain mechanism?

1 Addition of $\mathrm{HBr}$ on ethane $\rightarrow$ ionic addition reaction
$\mathrm{CH}_{2}=\mathrm{CH}_{2}+\mathrm{HBr} \rightarrow \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{Br}$
2 Halogenation of benzene in presence of $\mathrm{FeBr}_{3} \rightarrow$ Electrophilic substitution reaction
3 Photochemical chlorination of methane $\rightarrow$ free radical substitution reaction.
4 Hydrolysis with tert-butyl chloride $\rightarrow$ Nucleophic with aqueous $\mathrm{KOH} \quad$ substitution reaction
5 Addition of $\mathrm{NaHSO}_{3}$ on acetone $\rightarrow$ Nucleophic addition reaction
Hence, on the basis of above explanation option (c) is correct
original image
GENERAL ORGANIC CHEMISTRY

231721 The stablest radical among the following is

1 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow$ It has $1^{\circ}$ free radical
2 $\mathrm{CH}_{3}-\mathrm{CH}_{2} \longrightarrow$ It also has $1^{\circ}$ free radical only $3 \alpha$ Hydrogen
3 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \longrightarrow$ It has resonance as well as $3 \alpha$ - Hydrogen
$\mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}_{3} \longrightarrow 6 \alpha$ - Hydrogen $2^{\circ}$ free radical
$\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow 2 \alpha$ - Hydrogen $1^{\circ}$
So, on the basis above explanation (c) is more stable
4 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3}$
5 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}_{2}-\mathrm{CH}_{2}$
GENERAL ORGANIC CHEMISTRY

231722 The least stable free radical is

1 $\mathrm{CH}_{3} \dot{\mathrm{C}} \mathrm{H}_{2}$
2 $\mathrm{CH}_{3} \mathrm{CH}_{2} \dot{\mathrm{C}} \mathrm{H}_{2}$
3 $\left(\mathrm{CH}_{3}\right)_{2} \dot{\mathrm{C}} \mathrm{H}$
4 $\left(\mathrm{CH}_{3}\right)_{3} \dot{\mathrm{C}}$
5 $\dot{\mathrm{C}} \mathrm{H}_{3}$
GENERAL ORGANIC CHEMISTRY

231711 Identify the correct statement.

1 Reaction mechanisms are studied using isotopic labelling
2 Isolation of reactive intermediates is a method of establish reaction mechanism
3 Both (a) and (b) are correct
4 Neither (a) nor (b) are correct
GENERAL ORGANIC CHEMISTRY

231714 Relative stabilities of the following carbocations will be in the order
\[\begin{align}
& \overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{3}}\,\,\,\,\,\text{C}{{\text{H}}_{3}}\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\,\,\,\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\text{OC}{{\text{H}}_{3}} \\
& (A)\,\,\,\,\,\,\,\,\,\,\,\,\,\,(B)\,\,\,\,\,\,\,\,\,\,\,(C) \\
\end{align}\]

1 C $>$ B $>$ A
2 C $<$ B $<$ A
3 B $>$ C $>$ A
4 C $>$ A $>$ B
GENERAL ORGANIC CHEMISTRY

231719 Which one of the following reactions proceeds through free radical chain mechanism?

1 Addition of $\mathrm{HBr}$ on ethane $\rightarrow$ ionic addition reaction
$\mathrm{CH}_{2}=\mathrm{CH}_{2}+\mathrm{HBr} \rightarrow \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{Br}$
2 Halogenation of benzene in presence of $\mathrm{FeBr}_{3} \rightarrow$ Electrophilic substitution reaction
3 Photochemical chlorination of methane $\rightarrow$ free radical substitution reaction.
4 Hydrolysis with tert-butyl chloride $\rightarrow$ Nucleophic with aqueous $\mathrm{KOH} \quad$ substitution reaction
5 Addition of $\mathrm{NaHSO}_{3}$ on acetone $\rightarrow$ Nucleophic addition reaction
Hence, on the basis of above explanation option (c) is correct
original image
GENERAL ORGANIC CHEMISTRY

231721 The stablest radical among the following is

1 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow$ It has $1^{\circ}$ free radical
2 $\mathrm{CH}_{3}-\mathrm{CH}_{2} \longrightarrow$ It also has $1^{\circ}$ free radical only $3 \alpha$ Hydrogen
3 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \longrightarrow$ It has resonance as well as $3 \alpha$ - Hydrogen
$\mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}_{3} \longrightarrow 6 \alpha$ - Hydrogen $2^{\circ}$ free radical
$\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow 2 \alpha$ - Hydrogen $1^{\circ}$
So, on the basis above explanation (c) is more stable
4 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3}$
5 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}_{2}-\mathrm{CH}_{2}$
GENERAL ORGANIC CHEMISTRY

231722 The least stable free radical is

1 $\mathrm{CH}_{3} \dot{\mathrm{C}} \mathrm{H}_{2}$
2 $\mathrm{CH}_{3} \mathrm{CH}_{2} \dot{\mathrm{C}} \mathrm{H}_{2}$
3 $\left(\mathrm{CH}_{3}\right)_{2} \dot{\mathrm{C}} \mathrm{H}$
4 $\left(\mathrm{CH}_{3}\right)_{3} \dot{\mathrm{C}}$
5 $\dot{\mathrm{C}} \mathrm{H}_{3}$
GENERAL ORGANIC CHEMISTRY

231711 Identify the correct statement.

1 Reaction mechanisms are studied using isotopic labelling
2 Isolation of reactive intermediates is a method of establish reaction mechanism
3 Both (a) and (b) are correct
4 Neither (a) nor (b) are correct
GENERAL ORGANIC CHEMISTRY

231714 Relative stabilities of the following carbocations will be in the order
\[\begin{align}
& \overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{3}}\,\,\,\,\,\text{C}{{\text{H}}_{3}}\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\,\,\,\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\text{OC}{{\text{H}}_{3}} \\
& (A)\,\,\,\,\,\,\,\,\,\,\,\,\,\,(B)\,\,\,\,\,\,\,\,\,\,\,(C) \\
\end{align}\]

1 C $>$ B $>$ A
2 C $<$ B $<$ A
3 B $>$ C $>$ A
4 C $>$ A $>$ B
GENERAL ORGANIC CHEMISTRY

231719 Which one of the following reactions proceeds through free radical chain mechanism?

1 Addition of $\mathrm{HBr}$ on ethane $\rightarrow$ ionic addition reaction
$\mathrm{CH}_{2}=\mathrm{CH}_{2}+\mathrm{HBr} \rightarrow \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{Br}$
2 Halogenation of benzene in presence of $\mathrm{FeBr}_{3} \rightarrow$ Electrophilic substitution reaction
3 Photochemical chlorination of methane $\rightarrow$ free radical substitution reaction.
4 Hydrolysis with tert-butyl chloride $\rightarrow$ Nucleophic with aqueous $\mathrm{KOH} \quad$ substitution reaction
5 Addition of $\mathrm{NaHSO}_{3}$ on acetone $\rightarrow$ Nucleophic addition reaction
Hence, on the basis of above explanation option (c) is correct
original image
GENERAL ORGANIC CHEMISTRY

231721 The stablest radical among the following is

1 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow$ It has $1^{\circ}$ free radical
2 $\mathrm{CH}_{3}-\mathrm{CH}_{2} \longrightarrow$ It also has $1^{\circ}$ free radical only $3 \alpha$ Hydrogen
3 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \longrightarrow$ It has resonance as well as $3 \alpha$ - Hydrogen
$\mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}_{3} \longrightarrow 6 \alpha$ - Hydrogen $2^{\circ}$ free radical
$\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow 2 \alpha$ - Hydrogen $1^{\circ}$
So, on the basis above explanation (c) is more stable
4 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3}$
5 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}_{2}-\mathrm{CH}_{2}$
GENERAL ORGANIC CHEMISTRY

231722 The least stable free radical is

1 $\mathrm{CH}_{3} \dot{\mathrm{C}} \mathrm{H}_{2}$
2 $\mathrm{CH}_{3} \mathrm{CH}_{2} \dot{\mathrm{C}} \mathrm{H}_{2}$
3 $\left(\mathrm{CH}_{3}\right)_{2} \dot{\mathrm{C}} \mathrm{H}$
4 $\left(\mathrm{CH}_{3}\right)_{3} \dot{\mathrm{C}}$
5 $\dot{\mathrm{C}} \mathrm{H}_{3}$
GENERAL ORGANIC CHEMISTRY

231711 Identify the correct statement.

1 Reaction mechanisms are studied using isotopic labelling
2 Isolation of reactive intermediates is a method of establish reaction mechanism
3 Both (a) and (b) are correct
4 Neither (a) nor (b) are correct
GENERAL ORGANIC CHEMISTRY

231714 Relative stabilities of the following carbocations will be in the order
\[\begin{align}
& \overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{3}}\,\,\,\,\,\text{C}{{\text{H}}_{3}}\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\,\,\,\,\overset{\oplus }{\mathop{\text{C}}}\,{{\text{H}}_{2}}\text{OC}{{\text{H}}_{3}} \\
& (A)\,\,\,\,\,\,\,\,\,\,\,\,\,\,(B)\,\,\,\,\,\,\,\,\,\,\,(C) \\
\end{align}\]

1 C $>$ B $>$ A
2 C $<$ B $<$ A
3 B $>$ C $>$ A
4 C $>$ A $>$ B
GENERAL ORGANIC CHEMISTRY

231719 Which one of the following reactions proceeds through free radical chain mechanism?

1 Addition of $\mathrm{HBr}$ on ethane $\rightarrow$ ionic addition reaction
$\mathrm{CH}_{2}=\mathrm{CH}_{2}+\mathrm{HBr} \rightarrow \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{Br}$
2 Halogenation of benzene in presence of $\mathrm{FeBr}_{3} \rightarrow$ Electrophilic substitution reaction
3 Photochemical chlorination of methane $\rightarrow$ free radical substitution reaction.
4 Hydrolysis with tert-butyl chloride $\rightarrow$ Nucleophic with aqueous $\mathrm{KOH} \quad$ substitution reaction
5 Addition of $\mathrm{NaHSO}_{3}$ on acetone $\rightarrow$ Nucleophic addition reaction
Hence, on the basis of above explanation option (c) is correct
original image
GENERAL ORGANIC CHEMISTRY

231721 The stablest radical among the following is

1 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow$ It has $1^{\circ}$ free radical
2 $\mathrm{CH}_{3}-\mathrm{CH}_{2} \longrightarrow$ It also has $1^{\circ}$ free radical only $3 \alpha$ Hydrogen
3 $\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \longrightarrow$ It has resonance as well as $3 \alpha$ - Hydrogen
$\mathrm{CH}_{3}-\mathrm{CH}-\mathrm{CH}_{3} \longrightarrow 6 \alpha$ - Hydrogen $2^{\circ}$ free radical
$\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \longrightarrow 2 \alpha$ - Hydrogen $1^{\circ}$
So, on the basis above explanation (c) is more stable
4 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3}$
5 $\mathrm{CH}_{3}-\dot{\mathrm{C}} \mathrm{H}_{2}-\mathrm{CH}_{2}$
GENERAL ORGANIC CHEMISTRY

231722 The least stable free radical is

1 $\mathrm{CH}_{3} \dot{\mathrm{C}} \mathrm{H}_{2}$
2 $\mathrm{CH}_{3} \mathrm{CH}_{2} \dot{\mathrm{C}} \mathrm{H}_{2}$
3 $\left(\mathrm{CH}_{3}\right)_{2} \dot{\mathrm{C}} \mathrm{H}$
4 $\left(\mathrm{CH}_{3}\right)_{3} \dot{\mathrm{C}}$
5 $\dot{\mathrm{C}} \mathrm{H}_{3}$