01. Nomenclature
COORDINATION COMPOUNDS

274025 The species that has a spin-only magnetic moment of 5.9 BM, is $\left(T_{d}=\right.$ tetrahedral $)$

1 $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ (Square Planar)
2 $\left[\mathrm{NiCl}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
3 $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]\left(\mathrm{T}_{\mathrm{d}}\right)$
4 $\left[\mathrm{MnBr}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
COORDINATION COMPOUNDS

274026 The pair in which both the species have the same magnetic moment (spin only) is

1 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
3 $\left[\mathrm{CO}(\mathrm{OH})_{4}\right]^{2-}$ and $\left[\mathrm{Fe}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{CoCl}_{4}\right]^{2-}$
COORDINATION COMPOUNDS

274029 The correct order of the spin only magnetic moments of the following complexes is
(I) $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Br}_{2}$
(II) $\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
(III) $\mathrm{Na}_{3}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]\left(\Delta_{0}>\mathrm{P}\right)$
(IV) $\left(\mathrm{Et}_{4} \mathrm{~N}\right)_{2}\left[\mathrm{CoCl}_{4}\right]$

1 (II) $\approx$ (I) $>$ (IV) $>$ (III)
2 (I) $>$ (IV) $>$ (III) $>$ (II)
3 (III) $=$ (I) $>$ (IV) $>$ (II)
4 (III) $=$ (I) $>$ (II) $>$ (IV)
COORDINATION COMPOUNDS

274030 The d-electron configurations of $\mathrm{Cr}^{2+}, \mathrm{Mn}^{2+}$, $\mathrm{Fe}^{2+}$ and $\mathrm{Co}^{2+}$ are $d^{4}, d^{5}, d^{6}$ and $d^{7}$ respectively. Which one of the following will exhibit the lowest paramagnetic behavior?
(Atomic no. $\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27$ ).

1 $\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]_{2+}^{2+}$
3 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
COORDINATION COMPOUNDS

274025 The species that has a spin-only magnetic moment of 5.9 BM, is $\left(T_{d}=\right.$ tetrahedral $)$

1 $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ (Square Planar)
2 $\left[\mathrm{NiCl}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
3 $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]\left(\mathrm{T}_{\mathrm{d}}\right)$
4 $\left[\mathrm{MnBr}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
COORDINATION COMPOUNDS

274026 The pair in which both the species have the same magnetic moment (spin only) is

1 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
3 $\left[\mathrm{CO}(\mathrm{OH})_{4}\right]^{2-}$ and $\left[\mathrm{Fe}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{CoCl}_{4}\right]^{2-}$
COORDINATION COMPOUNDS

274029 The correct order of the spin only magnetic moments of the following complexes is
(I) $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Br}_{2}$
(II) $\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
(III) $\mathrm{Na}_{3}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]\left(\Delta_{0}>\mathrm{P}\right)$
(IV) $\left(\mathrm{Et}_{4} \mathrm{~N}\right)_{2}\left[\mathrm{CoCl}_{4}\right]$

1 (II) $\approx$ (I) $>$ (IV) $>$ (III)
2 (I) $>$ (IV) $>$ (III) $>$ (II)
3 (III) $=$ (I) $>$ (IV) $>$ (II)
4 (III) $=$ (I) $>$ (II) $>$ (IV)
COORDINATION COMPOUNDS

274030 The d-electron configurations of $\mathrm{Cr}^{2+}, \mathrm{Mn}^{2+}$, $\mathrm{Fe}^{2+}$ and $\mathrm{Co}^{2+}$ are $d^{4}, d^{5}, d^{6}$ and $d^{7}$ respectively. Which one of the following will exhibit the lowest paramagnetic behavior?
(Atomic no. $\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27$ ).

1 $\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]_{2+}^{2+}$
3 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
COORDINATION COMPOUNDS

274025 The species that has a spin-only magnetic moment of 5.9 BM, is $\left(T_{d}=\right.$ tetrahedral $)$

1 $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ (Square Planar)
2 $\left[\mathrm{NiCl}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
3 $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]\left(\mathrm{T}_{\mathrm{d}}\right)$
4 $\left[\mathrm{MnBr}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
COORDINATION COMPOUNDS

274026 The pair in which both the species have the same magnetic moment (spin only) is

1 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
3 $\left[\mathrm{CO}(\mathrm{OH})_{4}\right]^{2-}$ and $\left[\mathrm{Fe}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{CoCl}_{4}\right]^{2-}$
COORDINATION COMPOUNDS

274029 The correct order of the spin only magnetic moments of the following complexes is
(I) $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Br}_{2}$
(II) $\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
(III) $\mathrm{Na}_{3}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]\left(\Delta_{0}>\mathrm{P}\right)$
(IV) $\left(\mathrm{Et}_{4} \mathrm{~N}\right)_{2}\left[\mathrm{CoCl}_{4}\right]$

1 (II) $\approx$ (I) $>$ (IV) $>$ (III)
2 (I) $>$ (IV) $>$ (III) $>$ (II)
3 (III) $=$ (I) $>$ (IV) $>$ (II)
4 (III) $=$ (I) $>$ (II) $>$ (IV)
COORDINATION COMPOUNDS

274030 The d-electron configurations of $\mathrm{Cr}^{2+}, \mathrm{Mn}^{2+}$, $\mathrm{Fe}^{2+}$ and $\mathrm{Co}^{2+}$ are $d^{4}, d^{5}, d^{6}$ and $d^{7}$ respectively. Which one of the following will exhibit the lowest paramagnetic behavior?
(Atomic no. $\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27$ ).

1 $\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]_{2+}^{2+}$
3 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
COORDINATION COMPOUNDS

274025 The species that has a spin-only magnetic moment of 5.9 BM, is $\left(T_{d}=\right.$ tetrahedral $)$

1 $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ (Square Planar)
2 $\left[\mathrm{NiCl}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
3 $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]\left(\mathrm{T}_{\mathrm{d}}\right)$
4 $\left[\mathrm{MnBr}_{4}\right]^{2-}\left(\mathrm{T}_{\mathrm{d}}\right)$
COORDINATION COMPOUNDS

274026 The pair in which both the species have the same magnetic moment (spin only) is

1 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
3 $\left[\mathrm{CO}(\mathrm{OH})_{4}\right]^{2-}$ and $\left[\mathrm{Fe}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ and $\left[\mathrm{CoCl}_{4}\right]^{2-}$
COORDINATION COMPOUNDS

274029 The correct order of the spin only magnetic moments of the following complexes is
(I) $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Br}_{2}$
(II) $\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
(III) $\mathrm{Na}_{3}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]\left(\Delta_{0}>\mathrm{P}\right)$
(IV) $\left(\mathrm{Et}_{4} \mathrm{~N}\right)_{2}\left[\mathrm{CoCl}_{4}\right]$

1 (II) $\approx$ (I) $>$ (IV) $>$ (III)
2 (I) $>$ (IV) $>$ (III) $>$ (II)
3 (III) $=$ (I) $>$ (IV) $>$ (II)
4 (III) $=$ (I) $>$ (II) $>$ (IV)
COORDINATION COMPOUNDS

274030 The d-electron configurations of $\mathrm{Cr}^{2+}, \mathrm{Mn}^{2+}$, $\mathrm{Fe}^{2+}$ and $\mathrm{Co}^{2+}$ are $d^{4}, d^{5}, d^{6}$ and $d^{7}$ respectively. Which one of the following will exhibit the lowest paramagnetic behavior?
(Atomic no. $\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27$ ).

1 $\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
2 $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]_{2+}^{2+}$
3 $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$
4 $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$